Safety Data Sheet - N. Bucher AG

DR 

Safety Data Sheet 

according to 1907/2006/EC, Article 31 

Page 1/6 

Printing date 14.01.2010 Revision: 14.01.2010 

1 Identification of substance: 

· Product details: 

· Trade name: VALTRON® AD1339-A 

· Application of the substance / the preparation: Epoxy resin adhesive 

· Manufacturer / Supplier: 

N. Bucher AG Tel.: ++41-56 418 19 90 

Pfadackerstraße 9 Fax: ++41-56 418 19 99 

CH-8957 Spreitenbach 

Switzerland 

· E-mail address of the competent person responsible for the Safety Data Sheet: info@nbucherag.com 

· Informing department: Sales 

· Emergency information: As above or next toxicological information centre 

2 Hazards identification 

· Hazard designation: 

Xi Irritant 

N Dangerous for the environment 

· Information pertaining to particular dangers for man and environment 

R 36/38 Irritating to eyes and skin. 

R 43 May cause sensitisation by skin contact. 

R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 

Contains epoxy constituents. See information supplied by the manufacturer. 

· Classification system 

The product has to be labelled due to the calculation procedure of the "General Classification guideline for 

preparations of the EU" in the latest valid version. 

3 Composition/information on ingredients 

· Chemical characterization 

· Description: Mixture of the substances listed below with nonhazardous additions. 

· Dangerous components: 

CAS: 25068-38-6 

NLP: 500-033-5 

Index number: 603-074-00-8 

Reaction product: Bisphenol-A-(Epichlorhydrine) Epoxy resin 

(number average molecular weight ≤ 700) 

Xi, N; R 36/38-43-51/53 

25-50% 

CAS: 13463-67-7 

Titanium(IV)-oxide 2.5-10% 

EINECS: 236-675-5 

· Additional information For the wording of the listed risk phrases refer to section 16. 

4 First aid measures 

· General information: Immediately remove any clothing contaminated by the product. 

· After inhalation: 

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms 

persist. 

(Contd. on page 2) 

GB

DR 



Page 2/6 


Trade name: VALTRON® AD1339-A 

· After skin contact: 

Instantly wash with water and soap and rinse thoroughly. 

Seek medical treatment. 

· After eye contact: Rinse opened eye for several minutes under running water. Then consult doctor. 

· After swallowing: 

Drink copious amounts of water and provide fresh air. Instantly call for doctor. 

Do not induce vomiting; instantly call for medical help. 

(Contd. of page 1) 

5 Fire fighting measures 

· Suitable extinguishing agents 

Carbon dioxide (CO₂), extinguishing powder or water spray/fog. Fight larger fires with water spray/fog or 

alcohol-resistant foam. 

· For safety reasons unsuitable extinguishing agents Water with a full water jet. 

· Special hazards caused by the material, its products of combustion or flue gases: 

Formation of toxic gases is possible during heating or in case of fire. 

Carbon monoxide (CO) and Carbon dioxide (CO₂) 

· Protective equipment: Wear self-contained breathing apparatus. 

· Additional information Collect contaminated fire fighting water separately. It must not enter drains. 

6 Accidental release measures 

· Person-related safety precautions: 

Ensure adequate ventilation. 

Wear protective equipment. Keep unprotected persons away. 

Avoid skin and eye contact. 

· Measures for environmental protection: 

Do not allow to enter drainage system, surface or ground water. 

Inform respective authorities in case product reaches water or sewage system. 

· Measures for cleaning/collecting: 

Ensure adequate ventilation. 

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). 

Dispose of the material collected according to regulations. 

7 Handling and storage 

· Handling 

· Information for safe handling: 

Ensure good ventilation/exhaustion at the workplace. 

Do not breathe dust. 

Avoid skin and eye contact. 

· Information about protection against explosions and fires: No special measures required. 

· Storage 

· Requirements to be met by storerooms and containers: 

Observe all local and national regulations for storage of water polluting products. 

· Information about storage in one common storage facility: 

Do not store together with oxidizing and acidic materials. 

Do not store together with alkalis (caustic solutions). 

· Further information about storage conditions: 

Store in cool, dry conditions in well sealed containers. 

Store container in a well ventilated position. 

GB 

(Contd. on page 3)

DR 



Page 3/6 




* 8 Exposure controls and personal protection 

· Additional information about design of technical systems: No further data; see item 7. 

· Components with critical values that require monitoring at the workplace: 

Respirable dusts may only be liberated after drying , but not from the product as delivered. 

13463-67-7 Titanium(IV)-oxide 

WEL (Great Britain) Long-term value: 10* 4** mg/m³ 

*total inhalable **respirable 

· Additional information: The lists that were valid during the compilation were used as basis. 

· Personal protective equipment 

· General protective and hygienic measures 

Keep away from foodstuffs, beverages and food. 

Instantly remove any contaminated garments. 

Do not breathe dust. 

Avoid contact with the eyes and skin. 

Wash hands during breaks and at the end of the work. 

· Breathing equipment: Use breathing protection in case of dust formation. 

· Protection of hands: 

Protective gloves 

To avoid skin problems reduce the wearing of gloves to the required minimum. 

Check the permeability prior to each renewed use of the glove. 

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. 

For the permanent contact no recommendation for a suitable glove material can be given. 

Selection of the glove material on consideration of the penetration times, rates of diffusion and the 

degradation. 

· Material of gloves 

Neoprene gloves 

Nitrile rubber - NBR 

Gloves made of these materials are suitable only as protection from splashes. 

Product can penetrate gloves. 

Immediately remove any gloves contaminated by the product. 

· Penetration time of glove material 

The exact break through time has to be found out by the manufacturer of the protective gloves and has to be 

observed. 

· As protection from splashes gloves made of the following materials are suitable: 

Neoprene gloves 

Nitrile rubber - NBR 

· Eye protection: Tightly sealed safety glasses 

· Body protection: Protective work clothing 

* 9 Physical and chemical properties: 

· General Information 

Form: 

Colour: 

Smell: 

pasty 

white 

weak/faint 

· Change in condition 

Melting point/Melting range: not determined 

Boiling point/Boiling range: not determined 

· Flash point: > 154°C 

· Self-inflammability: Product is not selfigniting. 


GB

DR 



Page 4/6 



· Danger of explosion: Product is not explosive. 

· Vapour pressure at 20°C: < 0.13 hPa 

· Density at 20°C 1.60 g/cm³ 

· Solubility in / Miscibility with 

Water: 

Not miscible or difficult to mix 


10 Stability and reactivity 

· Thermal decomposition / conditions to be avoided: 

No decomposition if used and stored according to specifications. 

· Materials to be avoided: 

Strong oxidizing agents 

Alkaline materials 

Strong acids 

· Dangerous reactions Reacts with acids, alkalis and oxidizing agents. 

· Dangerous products of decomposition: 

Carbon monoxide (CO) and Carbon dioxide (CO₂) 

Poisonous gases/vapours 

11 Toxicological information 

· Acute toxicity: 

· Primary irritant effect: 

· on the skin: Irritant for skin and mucous membranes. 

· on the eye: Irritant effect 

· Sensitization: Sensitization possible by skin contact. 

· Additional toxicological information: 

The product shows the following dangers according to the calculation method of the General EC 

Classification Guidelines for Preparations as issued in the latest version: 

Irritant 

Sensitising 

· Sensitisation May cause sensitisation by skin contact. 

12 Ecological information: 

· General notes: 

Water hazard class 2 (Self-assessment): hazardous for water 

Toxic for aquatic organisms 

13 Disposal considerations 

· Product: 

· Recommendation 

Must not be disposed of together with household garbage. Do not allow product to reach sewage system. 

Disposal must be made according to official regulations. 

· European waste catalogue: 

Waste disposal key numbers from EWC have to be assigned depending on origin and processing. 


GB

DR 



Page 5/6 



· Uncleaned packagings: 

· Recommendation: Disposal must be made according to official regulations. 


* 14 Transport information 

· Land transport ADR/RID (cross-border): 

· ADR/RID Class: 9 (M7) Miscellaneous dangerous substances and articles. 

· Kemler Number: 90 

· UN-Number: 3077 

· Packaging group: III 

· Label: 9 

· Special marking: Symbol (fish and tree) 

· Designation of goods: UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. 

(Reaction product: Bisphenol-A-(Epichlorhydrine) Epoxy resin (number average 

molecular weight ≤ 700)) 

· Limited quantities (LQ): LQ7 

· Transport category: 3 

· Tunnel restriction code: E 

· Maritime transport IMDG-Code: 

· IMDG Class: 9 

· UN Number: 3077 

· Label: 9 


· EMS Number: F-A,S-F 

· Correct technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Reaction 

product: Bisphenol-A-(Epichlorhydrine) Epoxy resin (number average molecular 

weight ≤ 700)) 

· Air transport ICAO-TI and IATA-DGR: 

· ICAO/IATA Class: 9 

· UN/ID Number: 3077 

· Label: 9 

· Special marking: Symbol (fish and tree) 


· Correct technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Reaction 

product: Bisphenol-A-(Epichlorhydrine) Epoxy resin (number average molecular 

weight ≤ 700)) 

· Transport/Additional information: Transport by post may be prohibited or restricted. 

GB 

(Contd. on page 6)

DR 



Page 6/6 




15 Regulatory information 

· Designation according to EC guidelines: 

The product has been classified/labelled in accordance with EC Directives / relevant national laws. 

· Code letter and hazard designation of product: 

Xi Irritant 

N Dangerous for the environment 

· Hazard-determining components of labelling: 

Reaction product: Bisphenol-A-(Epichlorhydrine) Epoxy resin (number average molecular weight ≤ 700) 

· Risk phrases: 

36/38 Irritating to eyes and skin. 

43 May cause sensitisation by skin contact. 

51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 

· Safety phrases: 

24 Avoid contact with skin. 

28 After contact with skin, wash immediately with plenty of soap and water. 

37/39 Wear suitable gloves and eye/face protection. 

61 Avoid release to the environment. Refer to special instructions/safety data sheets. 

· Special designation of certain preparations: 

Contains epoxy constituents. See information supplied by the manufacturer. 

· National regulations 

· Information about limitation of use: Employment restrictions concerning young persons must be observed. 

· Decree to be applied in case of technical fault: 

Quantity limits according to "EC Seveso directive" should be observed. 

· Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water 

16 Other information: 

These data are based on our present knowledge. However, they shall not constitute a guarantee for any 

specific product features and shall not establish a legally valid contractual relationship. 

· Relevant R-phrases: 

36/38 Irritating to eyes and skin. 

43 May cause sensitisation by skin contact. 

51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 

· Department issuing MSDS: 

C.S.B. GmbH Phone: +49 - 2151 - 652086-0 

Parkstraße 29 Fax: +49 - 2151 - 652086-9 

D-47829 Krefeld 

Germany 

· * Data compared to the previous version altered. 

GB

Safety Data Sheet - N. Bucher AG

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?