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EC safety data sheet - Doriot Dent (Ro)

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<strong>EC</strong> <strong>safety</strong> <strong>data</strong> <strong>sheet</strong><br />

Trade name: Wirosil (component A)<br />

Product no.: 51995/52001<br />

Current version : 1.0.1, issued: 08.05.2012 Replaced version: 1.0.1, issued: 09.03.2012 Region: GB<br />

S<strong>EC</strong>TION 1: Identification of the substance/mixture and of the company/undertaking<br />

1.1 Product identifier<br />

Trade name<br />

Wirosil (component A)<br />

1.2 Relevant identified uses of the substance or mixture and uses advised against<br />

Relevant identified uses of the substance or mixture<br />

Manufacturing of dental prosthesis in a dental laboratory<br />

1.3 Details of the supplier of the <strong>safety</strong> <strong>data</strong> <strong>sheet</strong><br />

Address<br />

BEGO Bremer Goldschlägerei<br />

Wilh. Herbst GmbH & Co. KG<br />

Wilhelm-Herbst-Str. 1<br />

28359 Bremen<br />

Telephone no. +49/ 421/ 2028 – 0<br />

Fax no. +49/ 421/ 2028 – 115<br />

Information provided by / telephone<br />

Research & Development Department - Materials, alloys and ceramics; +49/ 421/ 2028 – 130 (Chief Development<br />

Officer alloys)<br />

Advice on Safety Data Sheet<br />

msds@bego.com<br />

1.4 Emergency telephone number<br />

For medical advice (in German and English):<br />

+49/ 551/ 192 40 (Giftinformationszentrum Nord)<br />

S<strong>EC</strong>TION 2: Hazards identification<br />

2.1 Classification of the substance or mixture<br />

Classification information<br />

This product does not meet the classification and labelling criteria given in the Dangerous Preparations Directive<br />

(1999/45/<strong>EC</strong>; DPD)<br />

2.2 Label elements<br />

Not relevant<br />

2.3 Other hazards<br />

PBT assessment<br />

No <strong>data</strong> available.<br />

vPvB assessment<br />

No <strong>data</strong> available.<br />

S<strong>EC</strong>TION 3: Composition/information on ingredients<br />

3.1 Substances<br />

Not applicable. The product is not a substance.<br />

3.2 Mixtures<br />

Chemical characterization<br />

polymethylvinylsiloxane and silicon (silicic acid) based mixture<br />

Hazardous ingredients<br />

This product does not contain substances to be mentioned according to EU Regulation No 1907/2006 (REACH),<br />

annex II.<br />

Page 1 of 7


<strong>EC</strong> <strong>safety</strong> <strong>data</strong> <strong>sheet</strong><br />

Trade name: Wirosil (component A)<br />

Product no.: 51995/52001<br />

Current version : 1.0.1, issued: 08.05.2012 Replaced version: 1.0.1, issued: 09.03.2012 Region: GB<br />

S<strong>EC</strong>TION 4: First aid measures<br />

4.1 Description of first aid measures<br />

General information<br />

In case of persisting adverse effects, consult a physician. Remove contaminated clothing and shoes immediately, and<br />

launder thoroughly before reusing.<br />

After inhalation<br />

Ensure supply of fresh air. Remove affected person from the immediate area.<br />

After skin contact<br />

Wash off immediately with soap and water.<br />

After eye contact<br />

Remove contact lenses, irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart and<br />

seek medical advice.<br />

After ingestion<br />

Do not induce vomiting. Rinse mouth thoroughly with water. Never give anything by mouth to an unconscious person.<br />

Let plenty of water be drunk in small gulps. Summon a doctor immediately.<br />

4.2 Most important symptoms and effects, both acute and delayed<br />

No <strong>data</strong> available.<br />

4.3 Indication of any immediate medical attention and special treatment needed<br />

No <strong>data</strong> available.<br />

S<strong>EC</strong>TION 5: Firefighting measures<br />

5.1 Extinguishing media<br />

Suitable extinguishing media<br />

Water spray jet; Foam; Carbon dioxide; extinguishing powder<br />

Unsuitable extinguishing media<br />

Full water jet<br />

5.2 Special hazards arising from the substance or mixture<br />

In the event of fire, the following can be released: Carbon monoxide and carbon dioxide; amorphous silicic acid<br />

5.3 Advice for firefighters<br />

Adapt extinguisher and fire-fighting measures to fire in the environment. Use self-contained breathing apparatus. Wear<br />

protective clothing.<br />

S<strong>EC</strong>TION 6: Accidental release measures<br />

6.1 Personal precautions, protective equipment and emergency procedures<br />

For non-emergency personnel<br />

Ensure adequate ventilation. Refer to protective measures listed in sections 7 and 8.<br />

For emergency responders<br />

No <strong>data</strong> available. Personal protective equipment (PPE) - see Section 8.<br />

6.2 Environmental precautions<br />

Collect contaminated water / firefighting water separately. Do not discharge into the drains/surface<br />

waters/groundwater.<br />

6.3 Methods and material for containment and cleaning up<br />

Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). When picked up, treat<br />

material as prescribed under heading "Disposal considerations".<br />

6.4 Reference to other sections<br />

No <strong>data</strong> available.<br />

Page 2 of 7


279 Lk.8014132<br />

20<br />

<strong>EC</strong> <strong>safety</strong> <strong>data</strong> <strong>sheet</strong><br />

Trade name: Wirosil (component A)<br />

Product no.: 51995/52001<br />

Current version : 1.0.1, issued: 08.05.2012 Replaced version: 1.0.1, issued: 09.03.2012 Region: GB<br />

S<strong>EC</strong>TION 7: Handling and storage<br />

7.1 Precautions for safe handling<br />

Advice on safe handling<br />

No special measures necessary if stored and handled as prescribed.<br />

General protective and hygiene measures<br />

Wash hands before breaks and after work. Do not eat, drink or smoke during work time. Remove soiled or soaked<br />

clothing immediately. Keep away from foodstuffs and beverages. Provide eye wash fountain in work area.<br />

Advice on protection against fire and explosion<br />

No special measures necessary.<br />

7.2 Conditions for safe storage, including any incompatibilities<br />

Technical measures and storage conditions<br />

Keep container tightly closed and dry in a cool, well-ventilated place.<br />

Requirements for storage rooms and vessels<br />

Keep only in the original container. Containers which are opened must be carefully resealed and kept upright to<br />

prevent leakage.<br />

Appropriate Material<br />

steel; plastic<br />

Advice on storage assembly<br />

Do not store together with: explosive substances; strong oxidizing agents<br />

7.3 Specific end use(s)<br />

No <strong>data</strong> available.<br />

S<strong>EC</strong>TION 8: Exposure controls/personal protection<br />

8.1 Control parameters<br />

No parameters available for monitoring.<br />

8.2 Exposure controls<br />

Appropriate engineering controls<br />

No <strong>data</strong> available.<br />

Personal protective equipment<br />

Respiratory protection<br />

Not necessary.<br />

Eye / face protection<br />

Safety glasses (EN 166)<br />

Hand protection<br />

In case of intensive contact, wear protective gloves (EN 374). Before use, the protective gloves should be tested in<br />

any case for its specific work-station suitability (i.e. mechanical resistance, product compatibility and antistatic<br />

properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and<br />

replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn.<br />

Design operations thus to avoid permanent use of protective gloves.<br />

Other<br />

Normal chemical work clothing.<br />

Environmental exposure controls<br />

No <strong>data</strong> available.<br />

S<strong>EC</strong>TION 9: Physical and chemical properties<br />

9.1 Information on basic physical and chemical properties<br />

Form/Colour<br />

liquid, viscous<br />

white<br />

Odour<br />

odourless<br />

Page 3 of 7


3 200<br />

3 200<br />

3 400<br />

2 0,01<br />

10 4<br />

<strong>EC</strong> <strong>safety</strong> <strong>data</strong> <strong>sheet</strong><br />

Trade name: Wirosil (component A)<br />

Product no.: 51995/52001<br />

Current version : 1.0.1, issued: 08.05.2012 Replaced version: 1.0.1, issued: 09.03.2012 Region: GB<br />

Odour threshold<br />

No <strong>data</strong> available<br />

pH value<br />

No <strong>data</strong> available<br />

Boiling point / boiling range<br />

No <strong>data</strong> available<br />

Melting point / melting range<br />

No <strong>data</strong> available<br />

Decomposition point / decomposition range<br />

Value > 200 °C<br />

Flash point<br />

Value > 200 °C<br />

Method ASTM D 56<br />

Ignition temperature<br />

Value > 400 °C<br />

Auto-ignition temperature<br />

No <strong>data</strong> available<br />

Oxidising properties<br />

No <strong>data</strong> available<br />

Explosive properties<br />

No <strong>data</strong> available<br />

Flammability (solid, gas)<br />

No <strong>data</strong> available<br />

Lower flammability or explosive limits<br />

No <strong>data</strong> available<br />

Upper flammability or explosive limits<br />

No <strong>data</strong> available<br />

Vapour pressure<br />

Value < 0,01 kPa<br />

Reference temperature 20 °C<br />

Vapour density<br />

No <strong>data</strong> available<br />

Evaporation rate<br />

No <strong>data</strong> available<br />

Relative density<br />

No <strong>data</strong> available<br />

1,05<br />

Density<br />

Value 1,05 g/cm³<br />

Reference temperature 25 °C<br />

Solubility in water<br />

Remarks<br />

Solubility(ies)<br />

Remarks<br />

Partition coefficient: n-octanol/water<br />

No <strong>data</strong> available<br />

insoluble<br />

Partially soluble in organic solvents.<br />

Viscosity<br />

Value appr. 5000 mPa*s<br />

Type<br />

dynamic<br />

Page 4 of 7


914<br />

<strong>EC</strong> <strong>safety</strong> <strong>data</strong> <strong>sheet</strong><br />

Trade name: Wirosil (component A)<br />

Product no.: 51995/52001<br />

Current version : 1.0.1, issued: 08.05.2012 Replaced version: 1.0.1, issued: 09.03.2012 Region: GB<br />

9.2 Other information<br />

Other information<br />

No <strong>data</strong> available.<br />

S<strong>EC</strong>TION 10: Stability and reactivity<br />

10.1 Reactivity<br />

No <strong>data</strong> available.<br />

10.2 Chemical stability<br />

No <strong>data</strong> available.<br />

10.3 Possibility of hazardous reactions<br />

No <strong>data</strong> available.<br />

10.4 Conditions to avoid<br />

None, if handled according to order.<br />

10.5 Incompatible materials<br />

strong oxidizing agents<br />

10.6 Hazardous decomposition products<br />

In case of fire the following can be released: amorphous silicic acid<br />

S<strong>EC</strong>TION 11: Toxicological information<br />

11.1 Information on toxicological effects<br />

Acute oral toxicity<br />

No <strong>data</strong> available<br />

Acute dermal toxicity<br />

No <strong>data</strong> available<br />

Acute inhalational toxicity<br />

No <strong>data</strong> available<br />

Skin corrosion/irritation<br />

No <strong>data</strong> available<br />

Serious eye damage/irritation<br />

No <strong>data</strong> available<br />

Respiratory or skin sensitisation<br />

No <strong>data</strong> available<br />

Germ cell mutagenicity<br />

No <strong>data</strong> available<br />

Reproduction toxicity<br />

No <strong>data</strong> available<br />

Carcinogenicity<br />

No <strong>data</strong> available<br />

STOT-single exposure<br />

No <strong>data</strong> available<br />

STOT-repeated exposure<br />

No <strong>data</strong> available<br />

Aspiration hazard<br />

No <strong>data</strong> available<br />

Delayed and immediate effects as well as chronic effects from short and long-term exposure<br />

Contact with the skin and eyes may cause mechanical irritation.<br />

Page 5 of 7


Lk.2377<br />

710<br />

Lk.2386<br />

<strong>EC</strong> <strong>safety</strong> <strong>data</strong> <strong>sheet</strong><br />

Trade name: Wirosil (component A)<br />

Product no.: 51995/52001<br />

Current version : 1.0.1, issued: 08.05.2012 Replaced version: 1.0.1, issued: 09.03.2012 Region: GB<br />

S<strong>EC</strong>TION 12: Ecological information<br />

12.1 Toxicity<br />

Fish toxicity<br />

No <strong>data</strong> available<br />

Daphnia toxicity<br />

No <strong>data</strong> available<br />

Algae toxicity<br />

No <strong>data</strong> available<br />

Bacteria toxicity<br />

No <strong>data</strong> available<br />

12.2 Persistence and degradability<br />

No <strong>data</strong> available.<br />

12.3 Bioaccumulative potential<br />

No <strong>data</strong> available.<br />

12.4 Mobility in soil<br />

No <strong>data</strong> available.<br />

12.5 Results of PBT and vPvB assessment<br />

Results of PBT and vPvB assessment<br />

PBT assessment<br />

vPvB assessment<br />

No <strong>data</strong> available.<br />

No <strong>data</strong> available.<br />

12.6 Other adverse effects<br />

No <strong>data</strong> available.<br />

12.7 Other information<br />

Other information<br />

Do not discharge product unmonitored into the environment.<br />

S<strong>EC</strong>TION 13: Disposal considerations<br />

13.1 Waste treatment methods<br />

Product<br />

Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement<br />

with the regional waste disposal company.<br />

Packaging<br />

Residuals must be removed from packaging and when emptied completely disposed of in accordance with the<br />

regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified<br />

by the regional disposer.<br />

Page 6 of 7


<strong>EC</strong> <strong>safety</strong> <strong>data</strong> <strong>sheet</strong><br />

Trade name: Wirosil (component A)<br />

Product no.: 51995/52001<br />

Current version : 1.0.1, issued: 08.05.2012 Replaced version: 1.0.1, issued: 09.03.2012 Region: GB<br />

S<strong>EC</strong>TION 14: Transport information<br />

14.1 Transport ADR/RID/ADN<br />

The product is not subject to ADR/RID/ADN regulations.<br />

14.2 Transport IMDG<br />

The product is not subject to IMDG regulations.<br />

14.3 Transport ICAO-TI / IATA<br />

The product is not subject to ICAO-TI / IATA regulations.<br />

14.4 Other information<br />

No <strong>data</strong> available.<br />

14.6 Special precautions for user<br />

No <strong>data</strong> available.<br />

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code<br />

Not relevant<br />

S<strong>EC</strong>TION 15: Regulatory information<br />

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture<br />

EU regulations<br />

Restriction of occupation<br />

Adhere to the national sanitary and occupational <strong>safety</strong> regulations when using this product.<br />

Council Directive 96/82/<strong>EC</strong> on the control of major-accident hazards involving dangerous substances<br />

Remarks<br />

Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate<br />

decomposition products see Chapter 10.<br />

15.2 Chemical <strong>safety</strong> assessment<br />

No <strong>data</strong> available.<br />

S<strong>EC</strong>TION 16: Other information<br />

Sources of key <strong>data</strong> used to compile the <strong>data</strong> <strong>sheet</strong>:<br />

<strong>EC</strong> Directive 67/548/<strong>EC</strong> resp. 99/45/<strong>EC</strong> as amended in each case.<br />

Regulation (<strong>EC</strong>) No 1907/2006 (REACH), 1272/2008 (CLP) as amended in each case.<br />

<strong>EC</strong> Directives 2000/39/<strong>EC</strong>, 2006/15/<strong>EC</strong>, 2009/161/<strong>EC</strong><br />

National Threshold Limit Values of the corresponding countries as amended in each case.<br />

Transport regulations according to ADR, RID, IMDG, IATA as amended in each case.<br />

The <strong>data</strong> sources used to determine physical, toxic and ecotoxic <strong>data</strong>, are indicated directly in the corresponding<br />

chapter.<br />

Department issuing <strong>safety</strong> <strong>data</strong> <strong>sheet</strong><br />

UMCO Umwelt Consult GmbH - D-21107 Hamburg, Georg-Wilhelm-Strasse 183, Tel.: +49(40)79 02 36 300, Fax:<br />

+49(40)79 02 36 357, e-mail: umco@umco.de<br />

This information is based on our present state of knowledge. However, it should not constitute a guarantee for any<br />

specific product properties and shall not establish a legally valid relationship.<br />

Page 7 of 7

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