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<strong>1.</strong> <strong>Which</strong> <strong>of</strong> <strong>the</strong> <strong>following</strong> <strong>is</strong> <strong>equal</strong> <strong>for</strong> <strong>the</strong> <strong>for</strong>ward <strong>and</strong> <strong>reverse</strong> reactions at equilibrium<br />

A) concentration<br />

B) rates<br />

C) rate constants<br />

2. All chemical equilibria are _____ in nature.<br />

A) dynamic<br />

B) <strong>equal</strong><br />

C) static<br />

D) kinetic<br />

3. An example <strong>of</strong> a physical equilibrium <strong>is</strong> _____.<br />

A)<br />

B)<br />

C)<br />

D)<br />

4. <strong>Which</strong> <strong>of</strong> <strong>the</strong> <strong>following</strong> <strong>is</strong> not a physical equilibrium<br />

A) melting<br />

B) allotropic trans<strong>for</strong>mation<br />

C) vaporization<br />

D) rusting<br />

5. An example <strong>of</strong> heterogeneous equilibrium <strong>is</strong> _____.<br />

A)<br />

B)<br />

C) Enzyme-catalyzed reactions<br />

6. <strong>Which</strong> <strong>of</strong> <strong>the</strong> <strong>following</strong> statements <strong>is</strong> always correct<br />

A) chemical equilibria are homogeneous<br />

B) physical equilibria are homogeneous<br />

C) physical equilibria are heterogeneous<br />

D) chemical equilibria are heterogeneous<br />

Page 1


7. The expression <strong>for</strong> K p <strong>for</strong> <strong>the</strong> reaction<br />

<strong>is</strong> _____.<br />

A) P CO2<br />

B) P<br />

HO 2<br />

C)<br />

D)<br />

P CO2<br />

P CO2<br />

HO<br />

/ P 2<br />

HO<br />

ท P 2<br />

8. The expression <strong>for</strong> K p <strong>for</strong> <strong>the</strong> reaction<br />

<strong>is</strong> _____.<br />

A) 2P<br />

SO 2 O<br />

+ P 2<br />

B) P<br />

2 SO 2 O<br />

ท P 2<br />

C) P<br />

SO 2 O<br />

+ P 2<br />

D) 2P<br />

SO 2 O<br />

/ P 2<br />

9. The equilibrium constant K p <strong>is</strong> not applicable <strong>for</strong> <strong>the</strong> reaction _____.<br />

A)<br />

B)<br />

C)<br />

D)<br />

10. The equilibrium constant K c <strong>for</strong> <strong>the</strong> reaction<br />

A)<br />

<strong>is</strong> given by _____.<br />

B)<br />

C)<br />

D)<br />

Page 2


1<strong>1.</strong> The equation relating K p <strong>and</strong> K c <strong>is</strong> _____.<br />

A) K p = K c (RT) ∆n<br />

B) K p = K c RT ∆n<br />

C) K c = K p RT ∆n<br />

D) K c = K p (RT) ∆n<br />

12. K p will be <strong>equal</strong> to K c if _____.<br />

A) ∆n = 1<br />

B) ∆n = 0<br />

C) RT = 0<br />

D) ∆n = ∞<br />

13. K p will be less than K p if _____.<br />

A) ∆H = negative<br />

B) ∆n = positive<br />

C) ∆n = negative<br />

D) ∆n = 0<br />

14. The equilibrium constants <strong>for</strong> <strong>the</strong> reactions<br />

<strong>and</strong><br />

are x <strong>and</strong> y, respectively. The equilibrium constant <strong>for</strong> <strong>the</strong> reaction<br />

A)<br />

B) x + y<br />

C) x – y<br />

D) xy<br />

<strong>is</strong> _____.<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 15-16:<br />

The equilibrium constant <strong>for</strong> <strong>the</strong> reaction<br />

<strong>is</strong> x.<br />

Page 3


15. The equilibrium constant <strong>for</strong> <strong>the</strong> reaction<br />

A) –x<br />

B) x<br />

C) 1/x<br />

D) 2x<br />

<strong>is</strong> _____.<br />

16. The equilibrium constant <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> _____.<br />

A) 2x<br />

B) x<br />

C) x/2<br />

D) x 2<br />

17. The equilibrium constant <strong>for</strong> <strong>the</strong> reaction<br />

<strong>is</strong> 4.17 ×<br />

31<br />

A) –4.17 × 10 −<br />

B) 4.17 × 10 31<br />

C) 2.40 × 10 30<br />

D) 2.40× 10 -33<br />

31<br />

10 − . The equilibrium constant <strong>for</strong> <strong>the</strong> reaction<br />

<strong>is</strong><br />

18. The number <strong>of</strong> moles <strong>of</strong> H 2 , S 2 , <strong>and</strong> H 2 S present at <strong>the</strong> equilibrium <strong>for</strong> <strong>the</strong> reaction<br />

are 2.50, <strong>1.</strong>35 × 10 -5 <strong>and</strong> 8.70 moles respectively in a 12 L flask. The equilibrium<br />

constant, K c <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> _____.<br />

A) <strong>1.</strong>08 × 10 7<br />

B) <strong>1.</strong>08 × 10 -7<br />

C) 5.6 × 10 3<br />

D) 7.2 × 10 -5<br />

Page 4


19. Kc <strong>for</strong> <strong>the</strong> reaction<br />

<strong>is</strong> 2.24 × 10 22 at 1273 บC. K p <strong>for</strong> <strong>the</strong> reaction at <strong>the</strong> same temperature <strong>is</strong> _____.<br />

A) 7.16 × 10 -18<br />

B) <strong>1.</strong>76 × 10 20<br />

C) 5.12 × 10 -15<br />

D) 3.12 × 10 19<br />

20. The equilibrium partial pressures <strong>of</strong> N 2 , O 2 <strong>and</strong> NO in <strong>the</strong> reaction<br />

are 0.15, 0.33 <strong>and</strong> 0.050 atm, respectively at 2200ฐC. The value <strong>of</strong> K p <strong>for</strong> <strong>the</strong> reaction <strong>is</strong><br />

_____.<br />

A) 5.1<br />

B) 0.51<br />

C) 51<br />

D) 0.051<br />

2<strong>1.</strong> The equilibrium concentrations <strong>of</strong> NH 3 , N 2 <strong>and</strong> H 2 are 0.25 M, 0.11 M <strong>and</strong> <strong>1.</strong>91 M,<br />

respectively. The equilibrium constant K c <strong>for</strong> <strong>the</strong> reaction<br />

A) 0.082<br />

B) 8.2 × 10 -3<br />

C) 8.2<br />

D) 0.82<br />

<strong>is</strong> _____.<br />

22. The equilibrium constant, K c , <strong>for</strong> <strong>the</strong> reaction<br />

<strong>is</strong> 0.082. What <strong>is</strong> K a <strong>for</strong><br />

A) 0.164<br />

B) 0.041<br />

C) 0.29<br />

D) <strong>1.</strong>64<br />

Page 5


23. The equilibrium constant, K c , <strong>for</strong> <strong>the</strong> reaction<br />

<strong>is</strong> 3.8 × 10 -5 at 727ฐC. The value <strong>of</strong> K p <strong>for</strong> <strong>the</strong> equilibrium<br />

A) 648<br />

B) 320<br />

C) 32.0<br />

D) 6.48<br />

at <strong>the</strong> same temperature <strong>is</strong> _____.<br />

24. The equilibrium pressure <strong>for</strong> <strong>the</strong> reaction<br />

_____.<br />

A) 0.105<br />

B) 0.210<br />

C) <strong>1.</strong>05<br />

D) 10.5<br />

<strong>is</strong> 0.105 atm at 350ฐC. K p <strong>for</strong> <strong>the</strong> reaction <strong>is</strong><br />

25. K p <strong>for</strong> <strong>the</strong> reaction<br />

same temperature <strong>is</strong> _____.<br />

A) 4.21 × 10 3<br />

B) 0.105<br />

C) 3.05 × 10 -4<br />

D) 2.05 × 10 -3<br />

at 350 o C <strong>is</strong> 0.105. K c <strong>for</strong> <strong>the</strong> reaction at <strong>the</strong><br />

26. The equilibrium constant, K p, <strong>for</strong> <strong>the</strong> reaction<br />

<strong>is</strong> <strong>1.</strong>05 at 250ฐC. The reaction <strong>is</strong> started with PCl 5 , PCl 3 <strong>and</strong> Cl 2 at 0.177, 0.223 <strong>and</strong><br />

0.111 atm at 250ฐC. When <strong>the</strong> reaction comes to equilibrium, <strong>the</strong> pressure <strong>of</strong> _____.<br />

A) PCl 3 must have decreased<br />

B) Cl 2 must have decreased<br />

C) PCl 5 must have decreased<br />

D) PCl 5 must have increased<br />

Page 6


27. Starting with only <strong>the</strong> solid, <strong>the</strong> total pressure <strong>of</strong> NH 3 <strong>and</strong> CO 2 was found to 0.363 atm<br />

<strong>for</strong> <strong>the</strong> equilibrium<br />

equilibrium constant, K p <strong>is</strong><br />

A) 7.1 × 10 -3<br />

B) 2.5 × 10 -2<br />

C) 5.3 × 10 -4<br />

D) 3.6 × 10 -6<br />

at 40ฐC. The<br />

28. <strong>1.</strong>05 moles <strong>of</strong> Br 2 in a 0.980 L container undergo <strong>1.</strong>2% d<strong>is</strong>sociation. The equilibrium<br />

constant, K c <strong>for</strong> <strong>the</strong> reaction<br />

A) 2.5 × 10 -5<br />

B) <strong>1.</strong>8 × 10 -3<br />

C) 6.2 × 10 -4<br />

D) 5.9 × 10 -6<br />

<strong>is</strong> _____.<br />

29. K p = K c <strong>for</strong> <strong>the</strong> reaction _____.<br />

A)<br />

B)<br />

C)<br />

D)<br />

30. 3.00 × 10 -2 mol <strong>of</strong> phosgene gas, COCl 2 , was heated in a <strong>1.</strong>50 L container at 800 K. At<br />

equilibrium <strong>the</strong> pressure <strong>of</strong> CO was found to be 0.497 atm. The equilibrium constant, K p<br />

<strong>for</strong> <strong>the</strong> reaction<br />

A) 3.30<br />

B) 9.80<br />

C) 2.75<br />

D) 5.61<br />

<strong>is</strong> _____.<br />

3<strong>1.</strong> The equilibrium constant, K p <strong>for</strong> <strong>the</strong> reaction<br />

at 2200ฐC <strong>is</strong> 0.05<strong>1.</strong> The equilibrium constant, K c <strong>for</strong> <strong>the</strong> same reaction <strong>is</strong> _____.<br />

A) 0.102<br />

B) 0.051<br />

C) 2.5 × 10 -3<br />

D) <strong>1.</strong>02 × 10 4<br />

Page 7


Use <strong>the</strong> <strong>following</strong> to answer questions 32-33:<br />

At equilibrium, nitrosyl bromide in <strong>the</strong> reaction<br />

<strong>is</strong> 34% d<strong>is</strong>sociated at 25ฐC <strong>and</strong> <strong>the</strong> total pressure <strong>is</strong> 0.25 atm.<br />

32. The value <strong>of</strong> K p <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> _____.<br />

A) 9.6 × 10 -3<br />

B) <strong>1.</strong>39 × 10 -5<br />

C) 3.8 × 10 -4<br />

D) 6.7 × 10 -6<br />

33. The value <strong>of</strong> K c <strong>for</strong> <strong>the</strong> above reaction <strong>is</strong> _____.<br />

A) <strong>1.</strong>6 × 10 -6<br />

B) 2.7 × 10 -5<br />

C) 3.9 × 10 -4<br />

D) 4.5 × 10 -7<br />

34. 2.50 mole <strong>of</strong> NOCl was heated in a <strong>1.</strong>50 L vessel at 400ฐC.At equilibrium it was found<br />

that 28.0% <strong>of</strong> <strong>the</strong> NOCl had d<strong>is</strong>sociated. The equilibrium constant, K c <strong>of</strong> <strong>the</strong> reaction<br />

A) 0.0353<br />

B) 3.53 × 10 2<br />

C) 3.53 × 10 -4<br />

D) 3.53<br />

<strong>is</strong> _____.<br />

35. The ionization constants K c' <strong>and</strong> K c” <strong>for</strong><br />

were found to be 9.5 × 10 -8 <strong>and</strong> <strong>1.</strong>0 × 10 -19 respectively. The equilibrium constant <strong>for</strong><br />

<strong>the</strong> reaction<br />

A) 9.5 × 10 -8<br />

B) <strong>1.</strong>0 × 10 -19<br />

C) 9.5 × 10 -27<br />

D) <strong>1.</strong>05 × 10 -12<br />

<strong>is</strong> _____.<br />

Page 8


36. The equilibrium constant, K c = 4.0 ื 10 -6 <strong>for</strong> <strong>the</strong> reaction<br />

.<br />

If <strong>the</strong> equilibrium constant, K c = 6.5 × 10 -2 <strong>for</strong> <strong>the</strong> reaction<br />

<strong>the</strong> equilibrium constant <strong>for</strong><br />

A) 4.0× 10 -6<br />

B) 6.1 × 10 -5<br />

C) <strong>1.</strong>6 × 10 4<br />

D) 6.5 × 10 -2<br />

,<br />

<strong>is</strong> _____.<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 37-38:<br />

The <strong>following</strong> equilibrium constants were measured <strong>for</strong> <strong>the</strong> reactions:<br />

37. The equilibrium constant <strong>for</strong> <strong>the</strong> reaction<br />

A) xy<br />

B) x + y<br />

C) xy 2<br />

D) x + y 2<br />

<strong>is</strong> _____.<br />

38. The equilibrium constants K 1 <strong>and</strong> K 2 <strong>for</strong> <strong>the</strong> reactions above are<br />

<strong>1.</strong>3 × 10 14 <strong>and</strong> 6.0 × 10 -3 , respectively. The equilibrium constant <strong>for</strong> <strong>the</strong> reaction<br />

A) 4.7 × 10 9<br />

B) <strong>1.</strong>0 × 10 14<br />

C) <strong>1.</strong>0 × 10 26<br />

D) 3.6 × 10 18<br />

<strong>is</strong> _____.<br />

Page 9


39. The equilibrium constants K 1 K 2 <strong>and</strong> K 3 <strong>for</strong> <strong>the</strong> reactions below are<br />

K 1 = 4.2 × 10 52<br />

K 2 = x<br />

The value <strong>of</strong> K 2 <strong>is</strong> _____.<br />

A) 9.8 × 10 28<br />

B) 9.8 × 10 128<br />

C) 6.7 × 10 12<br />

D) 2.6 × 10 75<br />

K 3 = 5.6 × 10 23 .<br />

40. The equilibrium constant in terms <strong>of</strong> rate constants <strong>for</strong> <strong>the</strong> <strong>for</strong>ward reaction, k f , <strong>and</strong> <strong>the</strong><br />

<strong>reverse</strong> reaction, k r , <strong>is</strong> given as _____.<br />

A) kr<br />

K = k<br />

B) K = k f + k r<br />

C) k<br />

f<br />

K = k<br />

r<br />

D) K = k f k r<br />

f<br />

4<strong>1.</strong> The concentration <strong>of</strong> H + in pure water at 25ฐC <strong>is</strong> _____.<br />

A) 10 -14 M<br />

B) 10 -7 M<br />

C) 10 -10 M<br />

D) 10 -8 M<br />

42. The equilibrium constant <strong>of</strong> a reaction <strong>is</strong> 12.6. If <strong>the</strong> rate constant <strong>of</strong> <strong>the</strong> <strong>reverse</strong><br />

reaction <strong>is</strong> 5.1 × 10 -2 , <strong>the</strong> rate constant <strong>for</strong> <strong>the</strong> <strong>for</strong>ward reaction <strong>is</strong> _____.<br />

A) 0.32<br />

B) 0.16<br />

C) 0.64<br />

D) 0.08<br />

43. <strong>Which</strong> <strong>of</strong> <strong>the</strong> <strong>following</strong> statements can be correct with respect to reaction quotient, Q<br />

<strong>and</strong> equilibrium constant, K<br />

A) Q < K<br />

B) Q = K<br />

C) Q > K<br />

D) all <strong>the</strong> above<br />

Page 10


44. The value <strong>of</strong> K c <strong>for</strong> <strong>the</strong> equilibrium<br />

<strong>is</strong> 5.6 × 10 4 350ฐC. The initial pressures <strong>of</strong> SO 2 <strong>and</strong> O 2 in a mixture are 0.350 atm <strong>and</strong><br />

0.762 atm. The total pressure at equilibrium will be _____ atm.<br />

A) less than 0.350<br />

B) less than 0.741<br />

C) less than <strong>1.</strong>112<br />

D) <strong>equal</strong> to <strong>1.</strong>112<br />

45. The value <strong>of</strong> Kc <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> <strong>1.</strong>2 . The<br />

reaction <strong>is</strong> started with [H 2 ] 0 = 0.76 M, [N 2 ] 0 = 0.60 M <strong>and</strong> [NH 3 ] 0 = 0.48 M. <strong>Which</strong> <strong>of</strong><br />

<strong>the</strong> <strong>following</strong> <strong>is</strong> correct as <strong>the</strong> reaction comes to equilibrium<br />

A) The concentration <strong>of</strong> N 2 will increase<br />

B) The concentration <strong>of</strong> H 2 will decrease<br />

C) The concentration <strong>of</strong> NH 3 will decrease<br />

D) The concentration <strong>of</strong> both N 2 <strong>and</strong> H 2 will increase<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 46-48:<br />

For <strong>the</strong> reaction<br />

K c = 0.534 at 700ฐC<br />

46. Calculate <strong>the</strong> number <strong>of</strong> moles <strong>of</strong> H 2 present at equilibrium if a mixture <strong>of</strong> 0.300 moles<br />

<strong>of</strong> CO <strong>and</strong> 0.300 moles <strong>of</strong> H 2 O <strong>is</strong> heated to 700ฐC in a 10.0 L container.<br />

A) 0.432 mol<br />

B) 0.273 mol<br />

C) 0.577 mol<br />

D) 0.173 mol<br />

47. <strong>Which</strong> statement <strong>is</strong> correct with respect to <strong>the</strong> above equilibrium when 0.30 moles <strong>of</strong><br />

CO <strong>and</strong> 0.30 moles <strong>of</strong> H 2 O are heated to 700ฐC <strong>and</strong> allowed to reach equilibrium.<br />

A) [H 2 O] = [CO 2 ]<br />

B) [CO 2 ] = [CO]<br />

C) [H 2 O] = [CO]<br />

D) [H 2 O] = [H 2 ]<br />

Page 11


48. <strong>Which</strong> <strong>of</strong> <strong>the</strong> <strong>following</strong> statements <strong>is</strong> correct<br />

A) All concentrations are <strong>equal</strong><br />

B) K p = K c<br />

C) K p < K c<br />

D) K p > K c<br />

49. K p <strong>is</strong> 158 <strong>for</strong> <strong>the</strong> equilibrium<br />

Starting with NO 2 (g) only, <strong>the</strong> partial pressure <strong>of</strong> O 2 at equilibrium <strong>is</strong> 0.25 atm.<br />

Calculate <strong>the</strong> partial pressure <strong>of</strong> NO 2 at equilibrium.<br />

A) 0.020 atm<br />

B) 0.20 atm<br />

C) 3.1 atm<br />

D) 0.035atm<br />

50. The partial pressure <strong>of</strong> NO in <strong>the</strong> above equilibrium <strong>is</strong> _____ atm.<br />

A) 0.125<br />

B) 0.50<br />

C) 0.25<br />

D) 0.02<br />

5<strong>1.</strong> The equilibrium constant Kc <strong>for</strong> <strong>the</strong> reaction <strong>is</strong><br />

2.18 × 10 6 . Starting with 3.20 moles <strong>of</strong> HBr in a 12.0L container, <strong>the</strong> concentration <strong>of</strong><br />

HBr at equilibrium <strong>is</strong> _____.<br />

A) 0.167 M<br />

B) 0.0267 M<br />

C) <strong>1.</strong>6 M<br />

D) 0.267 M<br />

52.<br />

Kc <strong>is</strong> 3.8 × 10 -5 at 1000K <strong>for</strong> <strong>the</strong> equilibrium<br />

Starting with 0.0456 moles <strong>of</strong> I 2 in a 2.30 L flask, at 1000 K, <strong>the</strong> equilibrium<br />

concentration <strong>of</strong> I 2 at <strong>is</strong>:<br />

A) <strong>1.</strong>94 M<br />

B) 0.0194 M<br />

C) 0.12 M<br />

D) 0.012 M<br />

Page 12


Use <strong>the</strong> <strong>following</strong> to answer questions 53-54:<br />

K c <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> 4.63 × 10 -3 at 527ฐC .<br />

53. Starting with pure phosgene, COCl 2 , at 0.760 atm, <strong>the</strong> equilibrium partial pressure <strong>of</strong><br />

CO <strong>is</strong> _____.<br />

A) 0.352 atm<br />

B) 0.0416 atm<br />

C) 0.0352 atm<br />

D) 0.416 atm<br />

54. Starting with pure phosgene, COCl 2 , at 0.760 atm, <strong>the</strong> equilibrium partial pressure <strong>of</strong><br />

COCl 2 <strong>is</strong> _____.<br />

A) 0.173 atm<br />

B) 0.204 atm<br />

C) 0.302 atm<br />

D) 0.408 atm<br />

55. What <strong>is</strong> <strong>the</strong> value <strong>of</strong> K c <strong>for</strong> <strong>the</strong> reaction<br />

when <strong>the</strong> equilibrium concentrations <strong>of</strong><br />

CO, H 2 , CO 2 <strong>and</strong> H 2 O are 0.050 M, 0.045 M, 0.086 M <strong>and</strong> 0.040 M respectively<br />

A) 0.074<br />

B) 0.52<br />

C) 0.063<br />

D) 0.24<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 56-57:<br />

The equilibrium constant K p <strong>for</strong> <strong>the</strong> reaction<br />

total pressure at equilibrium <strong>is</strong> 4.50 atm.<br />

<strong>is</strong> <strong>1.</strong>52 <strong>and</strong> <strong>the</strong><br />

56. The equilibrium partial pressure <strong>of</strong> CO <strong>is</strong> _____ atm.<br />

A) 0.86<br />

B) <strong>1.</strong>62<br />

C) <strong>1.</strong>96<br />

D) <strong>1.</strong>31<br />

Page 13


57. The equilibrium partial pressure <strong>of</strong> CO 2 <strong>is</strong> _____ atm.<br />

A) 2.54 atm<br />

B) 0.98 atm<br />

C) <strong>1.</strong>27 atm<br />

D) 0.72 atm<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 58-60:<br />

The equilibrium constant, K c <strong>for</strong> <strong>the</strong> reaction<br />

4.2. Initially 0.80 mole <strong>of</strong> H 2 <strong>and</strong> 0.80 mole CO 2 are placed in a 5.0 L flask.<br />

<strong>is</strong><br />

58. The concentration <strong>of</strong> H 2 at equilibrium <strong>is</strong> _____.<br />

A) 0.054 M<br />

B) 0.025 M<br />

C) 0.15 M<br />

D) 0.029 M<br />

59. At equilibrium, <strong>the</strong> concentration <strong>of</strong> H 2 <strong>is</strong> <strong>equal</strong> to <strong>the</strong> concentration <strong>of</strong> _____.<br />

A) H 2 O<br />

B) CO<br />

C) CO 2<br />

D) H 2 O + CO 2<br />

60. The concentration <strong>of</strong> CO at equilibrium <strong>is</strong> _____.<br />

A) 0.22M<br />

B) 0.056M<br />

C) 0.021M<br />

D) 0.11M<br />

6<strong>1.</strong> Le Chโtelier's principle can help to predict how to maximize _____.<br />

A) Reaction yield<br />

B) Equilibrium constant<br />

C) Temperature<br />

D) Rate constant<br />

Page 14


62. <strong>Which</strong> can alter <strong>the</strong> value <strong>of</strong> <strong>the</strong> equilibrium constant<br />

A) Catalyst<br />

B) Concentration<br />

C) Pressure<br />

D) Temperature<br />

63. The equilibrium position <strong>of</strong> <strong>the</strong> reaction<br />

by _____.<br />

A) Removing SO 2<br />

B) Adding Cl 2<br />

C) Removing Cl 2<br />

D) Removing SO 2 <strong>and</strong> Cl 2<br />

can be shifted in <strong>the</strong> <strong>for</strong>ward direction<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 64-65:<br />

The equilibrium constant K c <strong>for</strong> <strong>the</strong> equilibrium<br />

<strong>is</strong> x.<br />

64. The equilibrium constant <strong>for</strong> <strong>the</strong> reaction<br />

A) x/2<br />

B) x 1/2<br />

C) x 2<br />

D) 2x<br />

<strong>is</strong> _____.<br />

65. The equilibrium constant <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> _____.<br />

A) x 2<br />

B)<br />

C) x –2<br />

D) –2x<br />

Page 15


66. <strong>Which</strong> <strong>of</strong> <strong>the</strong> <strong>following</strong> equilibria <strong>is</strong> not affected by pressure<br />

A)<br />

B)<br />

C)<br />

D)<br />

67. The equilibrium<br />

<strong>for</strong>mation by _____. ∆H = 92.5 kJ.<br />

A) Increasing temperature<br />

B) Increasing pressure<br />

C) Decreasing temperature<br />

D) Increasing <strong>the</strong> concentration PCl 3<br />

, can be shifted toward more product<br />

68. The equilibrium<br />

can shifted to <strong>the</strong> reactant side by _____. ∆H = –<br />

198.2 kJ<br />

A) Decreasing temperature<br />

B) Decreasing volume<br />

C) Decreasing pressure<br />

D) Increasing <strong>the</strong> concentration <strong>of</strong> SO 2<br />

69. The equilibrium pressure <strong>of</strong> NO2 in <strong>the</strong> equilibrium <strong>is</strong> <strong>1.</strong>56<br />

atm. Its pressure on <strong>the</strong> addition <strong>of</strong> a catalyst will be _____.<br />

A) <strong>1.</strong>06 atm<br />

B) 0.75 atm<br />

C) <strong>1.</strong>56 atm<br />

D) 2.71 atm<br />

70. The position <strong>of</strong> <strong>the</strong> equilibrium can be shifted<br />

to <strong>the</strong> left by <strong>the</strong> addition <strong>of</strong> _____ at constant pressure.<br />

A) CO<br />

B) He<br />

C) O 2<br />

D) KCl<br />

Page 16


7<strong>1.</strong> The addition <strong>of</strong> He to <strong>the</strong> equilibrium at<br />

constant volume _____.<br />

A) Shifts <strong>the</strong> equilibrium to <strong>the</strong> left<br />

B) Increases K c<br />

C) Shifts <strong>the</strong> equilibrium to <strong>the</strong> right<br />

D) Has no effect<br />

72. <strong>Which</strong> <strong>of</strong> <strong>the</strong> <strong>following</strong> will shift <strong>the</strong> equilibrium<br />

A) Decrease <strong>of</strong> temperature<br />

B) Addition <strong>of</strong> KCl<br />

C) Addition <strong>of</strong> CO 2<br />

D) Addition <strong>of</strong> NaOH solution<br />

to <strong>the</strong> right<br />

73.<br />

The equilibrium<br />

by _____.<br />

A) increasing temperature<br />

B) decreasing pressure<br />

C) removing some CO 2<br />

D) all <strong>of</strong> <strong>the</strong> above<br />

can be shifted to <strong>the</strong> right<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 74-76:<br />

Pure NOCl gas was heated to 240 ฐC in a <strong>1.</strong>00-L container. At equilibrium <strong>the</strong> total pressure was<br />

<strong>1.</strong>00 atm <strong>and</strong> <strong>the</strong> NOCl pressure was 0.64 atm.<br />

74. The partial pressure <strong>of</strong> NO at equilibrium in <strong>the</strong> reaction<br />

A) 0.24<br />

B) 0.12<br />

C) 0.34<br />

D) 0.17<br />

<strong>is</strong> _____ atm.<br />

Page 17


75. The partial pressure <strong>of</strong> Cl 2 in <strong>the</strong> equilibrium<br />

A) 0.36<br />

B) 0.09<br />

C) 0.12<br />

D) 0.18<br />

<strong>is</strong> _____ atm.<br />

76. K p <strong>for</strong> <strong>the</strong> equilibrium<br />

A) <strong>1.</strong>7<br />

B) 0.12<br />

C) 0.17<br />

D) 0.017<br />

<strong>is</strong> _____.<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 77-78:<br />

K p <strong>is</strong> 2.9 × 10 -11 at 530ฐC <strong>for</strong> <strong>the</strong> reaction<br />

.<br />

77. What <strong>is</strong> <strong>the</strong> partial pressure <strong>of</strong> NO at equilibrium when <strong>the</strong> equilibrium partial pressures<br />

<strong>of</strong> N 2 <strong>and</strong> O 2 are 3.0 atm <strong>and</strong> 0.012 atm, respectively<br />

A) <strong>1.</strong>0 × 10 –6 atm<br />

B) <strong>1.</strong>6 × 10 –3 atm<br />

C) <strong>1.</strong>6 × 10 –2 atm<br />

D) 0.16 atm<br />

78. What <strong>is</strong> <strong>the</strong> partial pressure <strong>of</strong> NO at equilibrium under atmospheric conditions where<br />

<strong>the</strong> partial pressures <strong>of</strong> N 2 <strong>and</strong> O 2 are 0.78 atm <strong>and</strong> 0.21 atm at 25ฐC K p <strong>for</strong> <strong>the</strong> reaction<br />

<strong>is</strong> 4.0× 10 -31 at 25 ฐC.<br />

A) <strong>1.</strong>12 × 10 -12 atm<br />

B) 2.6 × 10 -16 atm<br />

C) <strong>1.</strong>3 × 10 -8 atm<br />

D) <strong>1.</strong>45 × 10 -4 atm<br />

Page 18


79. The <strong>the</strong>rmal decomposition <strong>of</strong> NaHCO 3 (s) <strong>is</strong> favored by _____.<br />

A) decreasing temperature<br />

B) increasing temperature<br />

C) increasing pressure<br />

D) adding CO 2<br />

80. K p < K c at 25 ฐC <strong>for</strong> which <strong>of</strong> <strong>the</strong> reactions below<br />

A)<br />

B)<br />

C)<br />

D)<br />

8<strong>1.</strong> The condition <strong>for</strong> maximum yield <strong>of</strong> NOCl 2 in <strong>the</strong> reaction<br />

0<br />

<strong>is</strong> _______. (<br />

∆H f<br />

0<br />

∆H f<br />

<strong>of</strong> NO = 90.4kJ/mol.)<br />

A) high pressure, high temperature<br />

B) low pressure, low temperature<br />

C) low pressure, high temperature<br />

D) high pressure, low temperature<br />

<strong>of</strong> NOCl = 5<strong>1.</strong>7 kJ/mol,<br />

82. For <strong>the</strong> reaction<br />

P A = 0.60 atm <strong>and</strong> P B = 0.60 atm at equilibrium at some temperature. K p <strong>for</strong> <strong>the</strong> reaction<br />

<strong>is</strong> _____.<br />

A) 1<br />

B) 0.5<br />

C) <strong>1.</strong>7<br />

D) 0.6<br />

83. For <strong>the</strong> reaction<br />

at equilibrium, <strong>the</strong> P A =0.60 atm <strong>and</strong> P B =0.60 atm <strong>and</strong> <strong>the</strong> total pressure <strong>is</strong> <strong>1.</strong>2 atm. What<br />

<strong>is</strong> <strong>the</strong> P A when <strong>the</strong> total pressure <strong>is</strong> increased to <strong>1.</strong>5 atm<br />

A) 0.69 atm<br />

B) 0.81 atm<br />

C) 0.75 atm<br />

D) 0.91 atm<br />

Page 19


84. The equilibrium mixture in <strong>the</strong> reaction<br />

cons<strong>is</strong>ts <strong>of</strong> 0.020 mole O 2 , 0.040 mole NO <strong>and</strong> 0.96 mole NO 2 . What <strong>is</strong> K p <strong>for</strong> <strong>the</strong><br />

reaction at 430ฐC <strong>and</strong> at a total pressure <strong>of</strong> 0.20 atm<br />

A) <strong>1.</strong>5 × 10 5<br />

B) 7.2 × 10 4<br />

C) 8.1 × 10 –3<br />

D) 5.6 × 10 –6<br />

85. Ammonium carbamate decomposes at a certain temperature .The equilibrium pressure<br />

<strong>of</strong> <strong>the</strong> reaction<br />

<strong>is</strong> 0.318 atm. K p <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> _____.<br />

A) 5.92 × 10 -5<br />

B) <strong>1.</strong>26 × 10 -4<br />

C) 3.12 × 10 -6<br />

D) 4.76 × 10 -3<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 86-88:<br />

A mixture <strong>of</strong> 0.47 moles <strong>of</strong> H 2 <strong>and</strong> 3.59 moles <strong>of</strong> HCl <strong>is</strong> heated to 2800ฐC <strong>and</strong> allowed to reach<br />

equilibrium. The total pressure at equilibrium <strong>is</strong> 2.00 atm.<br />

K p = 193 at 2800ฐC.<br />

86. The equilibrium pressure <strong>of</strong> H 2 <strong>is</strong> _____ atm.<br />

A) 0.56 atm<br />

B) 0.28 atm<br />

C) 0.049 atm<br />

D) <strong>1.</strong>67 atm<br />

87. The partial pressure <strong>of</strong> Cl 2 in <strong>the</strong> above equilibrium <strong>is</strong> _____ atm.<br />

A) 0.28 atm<br />

B) 0.049 atm<br />

C) 0.56 atm<br />

D) 0.49 atm<br />

Page 20


88. The partial pressure <strong>of</strong> HCl in <strong>the</strong> above equilibrium <strong>is</strong> _____ atm.<br />

A) <strong>1.</strong>28 atm<br />

B) <strong>1.</strong>01 atm<br />

C) 2.06 atm<br />

D) <strong>1.</strong>67 atm<br />

89. Initially 1 mole <strong>of</strong> N 2 O 4 <strong>is</strong> placed in a vessel <strong>and</strong> allowed to reach equilibrium. The<br />

relation between <strong>the</strong> degree <strong>of</strong> d<strong>is</strong>sociation α, total pressure P <strong>and</strong> K p <strong>for</strong> <strong>the</strong> reaction<br />

A)<br />

2<br />

4α<br />

Kp = ⋅P<br />

2<br />

1−<br />

α<br />

B)<br />

2<br />

4α<br />

Kp = ⋅P<br />

2<br />

(1 − α)<br />

C)<br />

2<br />

α<br />

Kp = ⋅P<br />

2<br />

1−<br />

α<br />

D)<br />

2<br />

2α<br />

Kp = ⋅P<br />

2<br />

1−α<br />

( )<br />

<strong>is</strong> _____.<br />

90. One mole <strong>of</strong> N 2 <strong>and</strong> three moles <strong>of</strong> H 2 are placed in a flask <strong>and</strong> allowed to reach<br />

equilibrium. T = 375 บC. The mole fraction <strong>of</strong> NH 3 at equilibrium <strong>is</strong> found to be 0.2<strong>1.</strong><br />

What <strong>is</strong> <strong>the</strong> total pressure <strong>of</strong> <strong>the</strong> system at equilibrium<br />

A) 50 atm<br />

B) 5 atm<br />

C) 500 atm<br />

D) 0.5 atm<br />

9<strong>1.</strong> What <strong>is</strong> [S 2 ] at equilibrium in <strong>the</strong> <strong>following</strong> reaction if [H 2 S] = 4.84 × 10 -3 M <strong>and</strong> [H 2 ] =<br />

<strong>1.</strong>50 × 10 -3 M at equilibrium<br />

A) 2.34 × 10 -2<br />

B) 0.234 M<br />

C) 2.34 × 10 -3 M<br />

D) 2.34 × 10 -4 M<br />

K c = 2.25 × 10 -4<br />

Page 21


92. 6.75 g <strong>of</strong> SO 2 Cl 2 was placed in a 2.00L flask. At 648 K 0.0345 moles <strong>of</strong> SO 2 was<br />

present. K c <strong>for</strong> <strong>the</strong> reaction<br />

A) 3.83 × 10 -2<br />

B) 4.71 × 10 -3<br />

C) <strong>1.</strong>12 × 10 -2<br />

D) 6.12 × 10 -4<br />

<strong>is</strong> _____.<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 93-95:<br />

K p <strong>for</strong> <strong>the</strong> reaction<br />

at 375ฐC <strong>is</strong> 4.31 × 10 -4 . The reaction<br />

<strong>is</strong> started with 0.373 atm <strong>of</strong> H 2 <strong>and</strong> 0.862 atm <strong>of</strong> N 2 in a constant volume vessel.<br />

93. The partial pressure <strong>of</strong> N 2 at equilibrium <strong>is</strong> _____ atm.<br />

A) 0.260<br />

B) 0.760<br />

C) 0.860<br />

D) 0.960<br />

94. The partial pressure <strong>of</strong> H 2 at equilibrium <strong>is</strong> _____ atm.<br />

A) 0.366<br />

B) 0.166<br />

C) 0.266<br />

D) 0.566<br />

95. The partial pressure <strong>of</strong> NH 3 at equilibrium <strong>is</strong> _____ atm.<br />

A) 4.40 × 10 -3<br />

B) <strong>1.</strong>12 × 10 -2<br />

C) 7.20 × 10 -4<br />

D) 2.70 × 10 -5<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 96-97:<br />

A 0.244 M fructose solution was prepared <strong>and</strong> it was found that at equilibrium <strong>the</strong> fructose<br />

concentration had decreased to 0.113 M.<br />

Page 22


96. The equilibrium constant <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> _____.<br />

A) 2.06<br />

B) 5.16<br />

C) 4.27<br />

D) <strong>1.</strong>16<br />

97. The percentage <strong>of</strong> fructose converted into glucose in <strong>the</strong> equilibria<br />

A) 53.7%<br />

B) 83.1%<br />

C) 2<strong>1.</strong>7%<br />

D) 63.2%<br />

<strong>is</strong> _____.<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 98-99:<br />

The equilibrium pressure <strong>of</strong> oxygen <strong>for</strong> <strong>the</strong> reaction<br />

0.49 atm .<br />

<strong>is</strong><br />

98. K p <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> _____.<br />

A) 0.49<br />

B) 2.5 × 10 -3<br />

C) 0.98<br />

D) 4.9<br />

99. The fraction <strong>of</strong> CuO that will decompose if 0.16 mole <strong>of</strong> CuO <strong>is</strong> placed in a 2.0 L vessel<br />

at 1024ฐC <strong>is</strong> _____.<br />

A) 0.15<br />

B) 0.71<br />

C) 0.23<br />

D) 0.47<br />

100. 3.9 moles <strong>of</strong> NO <strong>and</strong> 0.88 moles <strong>of</strong> CO 2 are allowed to react as<br />

At equilibrium 0.11 moles <strong>of</strong> CO 2 was present. K c <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> _____.<br />

A) 0.27<br />

B) <strong>1.</strong>7<br />

C) 3.14<br />

D) 6.03<br />

Page 23


Use <strong>the</strong> <strong>following</strong> to answer questions 101-102:<br />

For <strong>the</strong> reaction at 430ฐC, K c = 54.3.<br />

Initially 0.714 moles <strong>of</strong> H 2 <strong>and</strong> 0.984 moles <strong>of</strong> I 2 <strong>and</strong> 0.886 moles <strong>of</strong> HI are placed in a 2.40 L<br />

vessel.<br />

10<strong>1.</strong> The equilibrium concentration <strong>of</strong> H 2 <strong>is</strong> _____.<br />

A) 0.070 M<br />

B) 0.182 M<br />

C) 0.152 M<br />

D) 0.012 M<br />

102. The equilibrium concentration <strong>of</strong> I 2 <strong>is</strong> _____.<br />

A) 0.112<br />

B) 0.082<br />

C) 0.182<br />

D) 0.116<br />

103.<br />

A gaseous compound, A, d<strong>is</strong>sociates as follows:<br />

. A was<br />

heated until equilibrium was reached. The pressure <strong>of</strong> A at equilibrium was 0.14P,where<br />

P <strong>is</strong> <strong>the</strong> total pressure. K p <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> _____.<br />

A) 0.13P<br />

B) <strong>1.</strong>3P<br />

C) 0.013P<br />

D) 13P<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 104-106:<br />

For <strong>the</strong> reaction<br />

K c = <strong>1.</strong>2 at 375ฐC.<br />

104. K p <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> _____.<br />

A) 4.2 × 10 -2<br />

B) <strong>1.</strong>2× 10 2<br />

C) 3.1 × 10 -3<br />

D) 4.2 × 10 -4<br />

Page 24


105. Kc <strong>for</strong> <strong>the</strong> reaction <strong>is</strong> _____.<br />

A) –<strong>1.</strong>2<br />

B) 0.83<br />

C) 0.38<br />

D) 0.012<br />

106. K c <strong>for</strong> <strong>the</strong> <strong>for</strong>mation <strong>of</strong> one mole <strong>of</strong> NH 3 from H 2 <strong>and</strong> N 2 <strong>is</strong> _____.<br />

A) 0.6<br />

B) <strong>1.</strong>1<br />

C) <strong>1.</strong>2<br />

D) 2.2<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 107-108:<br />

The vapor pressure <strong>of</strong> water at 20ฐC <strong>is</strong> 0.0231 atm.<br />

107.<br />

Kp <strong>for</strong> <strong>the</strong> process <strong>is</strong> _____.<br />

A) 0.0231<br />

B) 2.31 × 10 -6<br />

C) 2.31<br />

D) 100<br />

108. K c <strong>for</strong> vaporization <strong>of</strong> water <strong>is</strong>_____.<br />

A) <strong>1.</strong>8 × 10 -2<br />

B) 2.3 × 10 -5<br />

C) 9.6 × 10 -4<br />

D) 3.6 × 10 -3<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 109-110:<br />

The density <strong>of</strong> a mixture <strong>of</strong> <strong>the</strong> gases, NO 2 <strong>and</strong> N 2 O 4 , <strong>is</strong> 2.3 g/L at 74ฐC <strong>and</strong> <strong>1.</strong>3 atm.<br />

109. The partial pressure <strong>of</strong> NO 2 in <strong>the</strong> mixture <strong>is</strong> _____ atm.<br />

A) <strong>1.</strong>2<br />

B) 0.12<br />

C) 0.012<br />

D) 0.24<br />

Page 25


110. The partial pressure <strong>of</strong> N 2 O 4 <strong>the</strong> mixture <strong>is</strong> _____ atm.<br />

A) 0.62<br />

B) 0.12<br />

C) 0.062<br />

D) 0.63<br />

11<strong>1.</strong> What <strong>is</strong> Kp <strong>for</strong> <strong>the</strong> reaction when <strong>the</strong> total pressure at<br />

equilibrium <strong>is</strong> 2.2 atm<br />

A) <strong>1.</strong>1<br />

B) <strong>1.</strong>2<br />

C) 2.2<br />

D) 2.1<br />

Use <strong>the</strong> <strong>following</strong> to answer questions 112-114:<br />

For <strong>the</strong> equilibrium , <strong>the</strong> equilibrium partial pressures <strong>of</strong> NO 2 <strong>and</strong> N 2 O 4<br />

are 0.15 <strong>and</strong> 0.20 atm at 25ฐC.<br />

112. What <strong>is</strong> <strong>the</strong> equilibrium partial pressure <strong>of</strong> NO 2 when <strong>the</strong> volume <strong>is</strong> doubled<br />

A) <strong>1.</strong>0atm<br />

B) 0.10atm<br />

C) 10atm<br />

D) 0.01atm<br />

113. The equilibrium partial pressure <strong>of</strong> N 2 O 4 when <strong>the</strong> volume <strong>is</strong> doubled will be _____<br />

atm.<br />

A) 0.88<br />

B) 0.44<br />

C) 0.044<br />

D) 0.088<br />

114. Kp <strong>for</strong> <strong>the</strong> equilibrium at 25ฐC <strong>is</strong> _____.<br />

A) <strong>1.</strong>13<br />

B) 0.113<br />

C) 1<strong>1.</strong>3<br />

D) <strong>1.</strong>13 × 10 4<br />

Page 26


115. The vapor pressure <strong>of</strong> mercury <strong>is</strong> 0.0020 mmHg at 26ฐC. K c <strong>for</strong> <strong>the</strong> process<br />

A) <strong>1.</strong>1 × 10 -7<br />

B) 2.2 × 10 4<br />

C) <strong>1.</strong>1 × 10 -3<br />

D) 4.4 × 10 -2<br />

, <strong>is</strong> _____.<br />

Page 27


Answer Key<br />

<strong>1.</strong> B<br />

2. A<br />

3. C<br />

4. D<br />

5. A<br />

6. C<br />

7. D<br />

8. B<br />

9. B<br />

10. C<br />

1<strong>1.</strong> A<br />

12. B<br />

13. C<br />

14. D<br />

15. C<br />

16. D<br />

17. C<br />

18. A<br />

19. B<br />

20. D<br />

2<strong>1.</strong> A<br />

22. C<br />

23. B<br />

24. A<br />

25. D<br />

26. C<br />

27. A<br />

28. C<br />

29. D<br />

30. A<br />

3<strong>1.</strong> B<br />

32. A<br />

33. C<br />

34. A<br />

35. C<br />

36. B<br />

37. C<br />

38. A<br />

39. B<br />

40. C<br />

4<strong>1.</strong> B<br />

42. C<br />

43. D<br />

44. C<br />

Page 28


45. B<br />

46. D<br />

47. C<br />

48. B<br />

49. A<br />

50. B<br />

5<strong>1.</strong> D<br />

52. B<br />

53. A<br />

54. D<br />

55. B<br />

56. C<br />

57. A<br />

58. A<br />

59. C<br />

60. D<br />

6<strong>1.</strong> A<br />

62. D<br />

63. B<br />

64. B<br />

65. C<br />

66. A<br />

67. A<br />

68. C<br />

69. C<br />

70. B<br />

7<strong>1.</strong> D<br />

72. D<br />

73. D<br />

74. A<br />

75. C<br />

76. D<br />

77. A<br />

78. B<br />

79. B<br />

80. A<br />

8<strong>1.</strong> D<br />

82. C<br />

83. A<br />

84. A<br />

85. D<br />

86. B<br />

87. B<br />

88. D<br />

89. A<br />

90. A<br />

Page 29


9<strong>1.</strong> C<br />

92. A<br />

93. C<br />

94. A<br />

95. A<br />

96. D<br />

97. A<br />

98. A<br />

99. C<br />

100. B<br />

10<strong>1.</strong> A<br />

102. C<br />

103. B<br />

104. D<br />

105. B<br />

106. B<br />

107. A<br />

108. C<br />

109. A<br />

110. B<br />

11<strong>1.</strong> B<br />

112. B<br />

113. D<br />

114. B<br />

115. A<br />

Page 30

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