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EXAFS as a tool for catalyst characterization: a review of the ... - INT

EXAFS as a tool for catalyst characterization: a review of the ... - INT

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Rj distance from <strong>the</strong> central absorbing atom to atoms in <strong>the</strong><br />

j th coordination shell<br />

s standard deviation<br />

x thickness <strong>of</strong> <strong>the</strong> sample<br />

X 2 chi-square function<br />

W window <strong>of</strong> <strong>the</strong> Fourier trans<strong>for</strong>m<br />

W’ window <strong>of</strong> <strong>the</strong> Fourier backtrans<strong>for</strong>m<br />

Greek letters<br />

κ photoelectron wavevector<br />

λ mean free path <strong>of</strong> <strong>the</strong> ejected photoelectron from <strong>the</strong> absorber<br />

atom absorption coefficient<br />

µ 1 absorption coefficient <strong>of</strong> <strong>the</strong> isolated atom<br />

µ 0 absorption coefficient be<strong>for</strong>e <strong>the</strong> edge<br />

σ Debye-Waller factor due to static disorder and <strong>the</strong>rmal vibrations<br />

φ ph<strong>as</strong>e shift between <strong>the</strong> incident and backscattering wave<br />

χ <strong>EXAFS</strong> function<br />

Super/subscripts<br />

e experimental<br />

c calculated<br />

exp experimental<br />

<strong>the</strong> <strong>the</strong>oretical<br />

REFERENCES

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