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Proposed Title 1: - Queen's University

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Volcanic-type ±U 5 (Sample 6139, Gunnar deposit). F: Athabasca-related ±U 6 (Sample 2202,<br />

Martin Lake deposit). G: Altered metasomatic-type U 3 (Sample GN-42, Gunnar deposit). H:<br />

Altered breccia-type U 4 at Gunnar (Sample VR, Gunnar deposit). I: Altered breccia-type U 4<br />

(Sample C23-116, Cinch Lake deposit). J: Altered metasomatic-type U 3 (Sample 6134,<br />

Gunnar deposit). K: Altered Athabasca-related ±U 6 (Sample EA3011, Eagle-Ace). L: Altered<br />

volcanic-type ±U 5 (Sample AE3010, Eagle-Ace deposit). M: Altered metasomatic-type U 3<br />

(Sample VR69190, Gunnar deposit). Note: Data-point error ellipses are 2σ. Plots were<br />

constructed using ISOPLOT ver. 3.2 (Ludwig 2000) from the isotope ratios and their<br />

respective errors are presented in Table 2.1. 207 Pb/ 206 Pb ages are reported along discordia line,<br />

the oldest 207 Pb/ 206 Pb age is shown in bold character for concordia of the primary U<br />

mineralization.<br />

2.4.4.2. Chemical Pb age of the uranium mineralization<br />

Regression of the sum SiO 2 , Fe 2 O 3 , CaO and MnO contents to zero in the early veintype<br />

±U 2<br />

uraninite corresponds to 2290 Ma (Fig. 2.12A), which is identical to the<br />

207 Pb/ 206 Pb formation age of 2293±17 Ma (Fig. 2.11B). Chemical Pb ages show alteration<br />

events at ca. 1800 Ma, 1600 Ma, 1200 Ma, and 170 Ma (Table 2.3).<br />

Chemical Pb ages derived from the composition of the breccia-type U 4 uraninite vary<br />

from 1315 Ma to 557 Ma. The intercept at zero content of elements other than uraninite<br />

gives an age of 1830 Ma (Fig. 2.12B), which is close to the 207 Pb/ 206 Pb formation age of<br />

1848±5 Ma (Fig. 2.11D).<br />

The zero intercept of the Chemical Pb age of the volcanic-type ±U 5<br />

uraninite<br />

corresponds to 1827 Ma (Fig. 2.12C), which overlaps the 207 Pb/ 206 Pb ages of 1812±15 Ma<br />

and 1800±37 Ma (Figs. 11D and 11E, respectively). The concordance of these ages is<br />

interpreted as the crystallization age of ±U 5 uraninite. Chemical Pb ages display alteration<br />

events at ca. 1800-1700 Ma, 1500-1400 Ma, and 1300-1200 Ma (Table 2.3).<br />

60

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