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Proposed Title 1: - Queen's University

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in the U-Pb systems are in large part a function of the U age (Chipley et al., 2007); older<br />

uraninite is more likely affected by multiple alteration events so that errors obtained in the<br />

U-Pb system are greater. Analytical results are presented in Table 4.4 and the U-Pb<br />

concordia results summarized in Table 4.5.<br />

4.5.4.1. U-Pb geochronology of U-rich minerals by LA-HR-ICP-MS<br />

U 1 uraninite grains from the syn-ore stage at the Coronation Hill deposit have U-Pb<br />

isotopic compositions that define a discordia line with an upper intercept age of 1823±140<br />

Ma and an oldest 207 Pb/ 206 Pb age of 1719±31 Ma (2σ, MSWD=2.6) (Fig. 4.12A). Two<br />

samples from the El Sherana deposit have upper intercept ages of 1819±150 Ma (2σ,<br />

MSWD=7.8; Fig. 4.12B) and 1616±100 Ma (2σ, MSWD=1.02; Fig. 4.12C) and the oldest<br />

207 Pb/ 206 Pb ages of 1810±15 Ma and 1825±90 Ma, respectively. The upper intercept and<br />

oldest 207 Pb/ 206 Pb ages at Coronation Hill are identical to oldest 207 Pb/ 206 Pb ages at El<br />

Sherana and can therefore be interpreted as the estimate formation age for U 1<br />

mineralization.<br />

The U-Pb system in uraninite from various samples from the Coronation Hill deposit<br />

records various periods of post-mineralization alteration coincident with major tectonic<br />

events that have affected the area. These ages include 1654±170 Ma and 1638±160 Ma<br />

(Figs. 4.12D and 4.12E respectively), 1510±10 Ma (Fig. 4.12F), 1266±68 Ma (Fig. 4.12G),<br />

and 837±130 Ma (Fig. 4.12H). Similar post-formation alteration dates of uraninite have<br />

been reported from unconformity-type deposits in the Athabasca (Kotzer and Kyser 1993;<br />

Fayek and Kyser 1997; Cloutier et al., 2009) and Kombolgie basins (Polito et al., 2004).<br />

167

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