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Proposed Title 1: - Queen's University

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sandstone. (E) Pervasive Kln 1 alteration in the sandstone filling well-developed secondary<br />

porosity between detrital Qtz 0 grains. (F) Late Src 2 alteration replacing Kln 1 in sandstone.<br />

The uranium mineralization was not observed in the overlying Coronation sandstone.<br />

Ayres et al. (1975) observed minor uranium mineralization occurring within the Coronation<br />

sandstone, close to the unconformity with the underlying mineralized Koolpin Formation.<br />

4.5.1.2.4. Post-Ore alteration<br />

Post-ore alteration in the basement rock is characterized by the occurrence of thin<br />

veinlets of Chl 3 chlorite cutting through the syn-ore alteration assemblage. Late Kln 2<br />

kaolinite alteration obliterates the pre-ore and syn-ore mineral assemblage (Fig. 4.9F).<br />

Backscattered electron images indicate that U 1 uraninite is coarsely mottled and areas of<br />

apparently pristine uraninite coexist with finely pitted altered U 2<br />

uraninite. Post-ore<br />

alteration in the Coronation sandstone is reflected also by the presence of minor Src 2<br />

sericite that locally replaces Kln 1 kaolinite (Fig. 4.10F). Extensive secondary uranium<br />

mineralization has been previously described associated with the overlying Coronation<br />

sandstone (e.g. Valenta, 1991) (Fig. 4.3).<br />

4.5.2. Crystal chemistry of the alteration minerals<br />

4.5.2.1. Coronation Hill uranium deposit<br />

4.5.2.1.1. Uraninite Crystal Chemistry<br />

Electron microprobe analysis and backscatter images indicate that U 1 and U 2<br />

uraninites have been variably altered to different forms of uranyl-silicates and have variable<br />

U, Pb, Fe, Mg, Mn, and Ca contents (Table 4.1). These uraninites show considerable<br />

variation in reflectance (Figs. 4.6E and 4.6F), suggesting significant heterogeneity in their<br />

159

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