Proposed Title 1: - Queen's University

Proposed Title 1: - Queen's University Proposed Title 1: - Queen's University

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fracture systems created by brittle reactivation of the El Sherana-Palette fault at temperatures near 250°C. Syn-ore mineral crystal chemistry suggests that uranyl-fluoridechloride and -phosphate were dominant ore transporting complexes. Interaction of oxidizing basinal brines with reducing Koolpin Formation sediments led to deposition of the ore metals. Uranium deposits of the South Alligator Valley Mineral Field can therefore, be classified as unconformity-related uranium mineralization associated with the El Sherana successor basin. Post-ore alteration is dominated by secondary uraninite along late fractures, kaolinite and hematite alteration, and chlorite and calcite veins, which formed at temperatures near ca. 100°C. Post-ore alteration occurred during major tectonic events based on U-Pb and Pb-Pb dating of uraninite and was coincident with fluid flow induced by both near and far-field tectonic events that altered much of the primary uraninite into secondary uranium minerals. Our results show that the age of the uranium deposits are older than previously proposed and are also older than the unconformity-related uranium mineralization in the Kombolgie Basin. Unconformity-related uranium mineralization is associated with basinal brines from the Paleoproterozoic successor basin, thereby enhancing the uranium prospectivity of the area. 4.1. Introduction The South Alligator Valley Mineral Field (SAVMF), Northern Territories, Australia, lies within a north-west-trending zone of folded and faulted Paleoproterozoic metasediments (Fig. 4.1) exposed within the South Alligator Valley in the Pine Creek Orogen (Needham et al., 1980, 1987, 1988; Needham and Stuart-Smith, 1985, Valenta, 133

1990, 1991; Wyborn et al., 1990). Historic exploration within the SAVMF resulted in the discovery of several uranium deposits and occurrences. Nevertheless, the SAVMF is the smallest uranium field in the Pine Creek uranium province (Fig. 4.1). Between 1956 and 1964 only 874 t of U 3 O 8 was mined from 14 deposits (Foy, 1975). Since the discovery of unconformity-type uranium deposits in the Kombolgie Basin, research in the Pine Creek Orogen has been focused on the large and higher grade deposits within the Kombolgie Basin, which uncomformably overlies the successor El Sherana Basin (Friedmann and Grotzinger, 1994). The character and formation of unconformity-related uranium deposits associated with the younger Kombolgie Basin (Sweet et al., 1999) have been well documented and a general genetic model proposed (e.g. Gustafson and Curtis, 1983; Polito et al., 2004; 2005; Cuney, 2005). In contrast, uranium mineralization in the successor El Sherana Basin has been less studied, despite several decades of intense exploration and mining activities and the discovery of several uranium and precious metal deposits (e.g. Needham and Stuart-Smith, 1987; Mernagh et al., 1994). Moreover, there is limited information on the role of the successor basin and the key processes by which these deposits formed. The U mineralization occurs in basement rocks beneath, and within, the successor El Sherana Basin (e.g. Ayres et al., 1975; Mernagh et al., 1994) that is stratigraphically older than, but spatially related to, the younger U-rich Kombolgie Basin (e.g. Wilde, 1992; Polito et al., 2005). Whether these deposits are unconformity-related associated with the successor basin or similar to those in the younger Kombolgie Basin is inconclusive. 134

1990, 1991; Wyborn et al., 1990). Historic exploration within the SAVMF resulted in the<br />

discovery of several uranium deposits and occurrences. Nevertheless, the SAVMF is the<br />

smallest uranium field in the Pine Creek uranium province (Fig. 4.1). Between 1956 and<br />

1964 only 874 t of U 3 O 8 was mined from 14 deposits (Foy, 1975). Since the discovery of<br />

unconformity-type uranium deposits in the Kombolgie Basin, research in the Pine Creek<br />

Orogen has been focused on the large and higher grade deposits within the Kombolgie<br />

Basin, which uncomformably overlies the successor El Sherana Basin (Friedmann and<br />

Grotzinger, 1994). The character and formation of unconformity-related uranium deposits<br />

associated with the younger Kombolgie Basin (Sweet et al., 1999) have been well<br />

documented and a general genetic model proposed (e.g. Gustafson and Curtis, 1983; Polito<br />

et al., 2004; 2005; Cuney, 2005). In contrast, uranium mineralization in the successor El<br />

Sherana Basin has been less studied, despite several decades of intense exploration and<br />

mining activities and the discovery of several uranium and precious metal deposits (e.g.<br />

Needham and Stuart-Smith, 1987; Mernagh et al., 1994). Moreover, there is limited<br />

information on the role of the successor basin and the key processes by which these<br />

deposits formed. The U mineralization occurs in basement rocks beneath, and within, the<br />

successor El Sherana Basin (e.g. Ayres et al., 1975; Mernagh et al., 1994) that is<br />

stratigraphically older than, but spatially related to, the younger U-rich Kombolgie Basin<br />

(e.g. Wilde, 1992; Polito et al., 2005). Whether these deposits are unconformity-related<br />

associated with the successor basin or similar to those in the younger Kombolgie Basin is<br />

inconclusive.<br />

134

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