Proposed Title 1: - Queen's University
Proposed Title 1: - Queen's University Proposed Title 1: - Queen's University
fracture systems created by brittle reactivation of the El Sherana-Palette fault at temperatures near 250°C. Syn-ore mineral crystal chemistry suggests that uranyl-fluoridechloride and -phosphate were dominant ore transporting complexes. Interaction of oxidizing basinal brines with reducing Koolpin Formation sediments led to deposition of the ore metals. Uranium deposits of the South Alligator Valley Mineral Field can therefore, be classified as unconformity-related uranium mineralization associated with the El Sherana successor basin. Post-ore alteration is dominated by secondary uraninite along late fractures, kaolinite and hematite alteration, and chlorite and calcite veins, which formed at temperatures near ca. 100°C. Post-ore alteration occurred during major tectonic events based on U-Pb and Pb-Pb dating of uraninite and was coincident with fluid flow induced by both near and far-field tectonic events that altered much of the primary uraninite into secondary uranium minerals. Our results show that the age of the uranium deposits are older than previously proposed and are also older than the unconformity-related uranium mineralization in the Kombolgie Basin. Unconformity-related uranium mineralization is associated with basinal brines from the Paleoproterozoic successor basin, thereby enhancing the uranium prospectivity of the area. 4.1. Introduction The South Alligator Valley Mineral Field (SAVMF), Northern Territories, Australia, lies within a north-west-trending zone of folded and faulted Paleoproterozoic metasediments (Fig. 4.1) exposed within the South Alligator Valley in the Pine Creek Orogen (Needham et al., 1980, 1987, 1988; Needham and Stuart-Smith, 1985, Valenta, 133
1990, 1991; Wyborn et al., 1990). Historic exploration within the SAVMF resulted in the discovery of several uranium deposits and occurrences. Nevertheless, the SAVMF is the smallest uranium field in the Pine Creek uranium province (Fig. 4.1). Between 1956 and 1964 only 874 t of U 3 O 8 was mined from 14 deposits (Foy, 1975). Since the discovery of unconformity-type uranium deposits in the Kombolgie Basin, research in the Pine Creek Orogen has been focused on the large and higher grade deposits within the Kombolgie Basin, which uncomformably overlies the successor El Sherana Basin (Friedmann and Grotzinger, 1994). The character and formation of unconformity-related uranium deposits associated with the younger Kombolgie Basin (Sweet et al., 1999) have been well documented and a general genetic model proposed (e.g. Gustafson and Curtis, 1983; Polito et al., 2004; 2005; Cuney, 2005). In contrast, uranium mineralization in the successor El Sherana Basin has been less studied, despite several decades of intense exploration and mining activities and the discovery of several uranium and precious metal deposits (e.g. Needham and Stuart-Smith, 1987; Mernagh et al., 1994). Moreover, there is limited information on the role of the successor basin and the key processes by which these deposits formed. The U mineralization occurs in basement rocks beneath, and within, the successor El Sherana Basin (e.g. Ayres et al., 1975; Mernagh et al., 1994) that is stratigraphically older than, but spatially related to, the younger U-rich Kombolgie Basin (e.g. Wilde, 1992; Polito et al., 2005). Whether these deposits are unconformity-related associated with the successor basin or similar to those in the younger Kombolgie Basin is inconclusive. 134
- Page 101 and 102: eccia-type. The other styles of min
- Page 103 and 104: The basement consist of Neoarchean
- Page 105 and 106: of essentially unmetamorphosed arko
- Page 107 and 108: WDX X-ray spectrometers at Carleton
- Page 109 and 110: 3.4. Results 3.4.1. Paragenesis of
- Page 111 and 112: are derived from their chlorite cry
- Page 113 and 114: Figure 3.4. Photomicrographs of typ
- Page 115 and 116: 3.4J). Py 6 Pyrite and Cpy 5 chalco
- Page 117 and 118: mineralization varies from 25.70 to
- Page 119 and 120: 6137APt71 60.67 13.73 4.59 6.48 0.0
- Page 121 and 122: Fig. 3.6A). The Ca may result from
- Page 123 and 124: Sample ID 1 ± 2 ± 3.a ± 4 ± 5.a
- Page 125 and 126: Stable isotopic O and C composition
- Page 127 and 128: Sample ID Deposit Mineral Mineral v
- Page 129 and 130: equilibrium with a fluid having δ
- Page 131 and 132: Syn-ore Chl 8 chlorite sampled from
- Page 133 and 134: Figure 3.9. Binary diagrams showing
- Page 135 and 136: Figure 3.10. Chondrite-normalized R
- Page 137 and 138: Retrograde metamorphism Early vein
- Page 139 and 140: contents in syn-ore Chl 4 chlorite
- Page 141 and 142: decompression and hydration reactio
- Page 143 and 144: mineralizations, which upgraded the
- Page 145 and 146: metamorphic origin of the main U 4
- Page 147 and 148: y the abundance of Ap 1 apatite and
- Page 149 and 150: of late fluid events that have affe
- Page 151: CHAPTER 4 FLUID EVOLUTION AND GENES
- Page 155 and 156: stable isotope geochemistry, U-Pb g
- Page 157 and 158: coincident with the initiation of s
- Page 159 and 160: plasma mass spectrometry (LA-HR-ICP
- Page 161 and 162: The Coronation Hill deposit occupie
- Page 163 and 164: arsenides, nickel selenide and copp
- Page 165 and 166: No corrections were made to the 238
- Page 167 and 168: which was interpreted as being asso
- Page 169 and 170: porphyry and coated by Chl 1 formin
- Page 171 and 172: Mineralized breccias showing quartz
- Page 173 and 174: SOUTH ALLIGATOR RIVER GROUP EL SHER
- Page 175 and 176: A Carbonaceous Shale B Src 1 Qtz 1
- Page 177 and 178: A Granite Qtz 0 fragments Qtz 0 B M
- Page 179 and 180: chemical composition as a result of
- Page 181 and 182: Sample I.D SiO 2 CaO FeO ThO 2 MnO
- Page 183 and 184: site occupancy (Cathelineau, 1988).
- Page 185 and 186: Mineral values Temperature Fluid va
- Page 187 and 188: Corrected ratios Apparent ages ( ±
- Page 189 and 190: G H Figure 4.12. U-Pb concordia dia
- Page 191 and 192: Figure 4.13. Pb-Pb isochron diagram
- Page 193 and 194: and 4.12B), and to 207 Pb/ 206 Pb a
- Page 195 and 196: 160 o C at Coronation Hill. The tem
- Page 197 and 198: Figure 4.15. Conceptual genetic mod
- Page 199 and 200: of the Koolpin Formation, while dep
- Page 201 and 202: at ca. 1820 Ma, approximately 40 My
1990, 1991; Wyborn et al., 1990). Historic exploration within the SAVMF resulted in the<br />
discovery of several uranium deposits and occurrences. Nevertheless, the SAVMF is the<br />
smallest uranium field in the Pine Creek uranium province (Fig. 4.1). Between 1956 and<br />
1964 only 874 t of U 3 O 8 was mined from 14 deposits (Foy, 1975). Since the discovery of<br />
unconformity-type uranium deposits in the Kombolgie Basin, research in the Pine Creek<br />
Orogen has been focused on the large and higher grade deposits within the Kombolgie<br />
Basin, which uncomformably overlies the successor El Sherana Basin (Friedmann and<br />
Grotzinger, 1994). The character and formation of unconformity-related uranium deposits<br />
associated with the younger Kombolgie Basin (Sweet et al., 1999) have been well<br />
documented and a general genetic model proposed (e.g. Gustafson and Curtis, 1983; Polito<br />
et al., 2004; 2005; Cuney, 2005). In contrast, uranium mineralization in the successor El<br />
Sherana Basin has been less studied, despite several decades of intense exploration and<br />
mining activities and the discovery of several uranium and precious metal deposits (e.g.<br />
Needham and Stuart-Smith, 1987; Mernagh et al., 1994). Moreover, there is limited<br />
information on the role of the successor basin and the key processes by which these<br />
deposits formed. The U mineralization occurs in basement rocks beneath, and within, the<br />
successor El Sherana Basin (e.g. Ayres et al., 1975; Mernagh et al., 1994) that is<br />
stratigraphically older than, but spatially related to, the younger U-rich Kombolgie Basin<br />
(e.g. Wilde, 1992; Polito et al., 2005). Whether these deposits are unconformity-related<br />
associated with the successor basin or similar to those in the younger Kombolgie Basin is<br />
inconclusive.<br />
134