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Proposed Title 1: - Queen's University

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Sample ID Deposit Mineral<br />

Mineral values Temperatures Fluid values<br />

δ 18 O<br />

V-SMOW<br />

per mil<br />

δ 13 C<br />

V-PDB<br />

per mil<br />

o C<br />

δ 18 O fluid<br />

V-SMOW<br />

per mil<br />

δ 13 C fluid<br />

V-PDB<br />

per mil<br />

C-27-319D Cinch Lake MG-Calcite 11.4 -2.6 320 6.3 -4.7<br />

C-37-28 Cinch Lake Calcite 12.7 -1.7 320 7.5 -3.8<br />

C-42-180 Cinch Lake Calcite 12.8 -2.1 320 7.6 -4.2<br />

C-42-180D Cinch Lake Calcite 12.6 -1.9 320 7.5 -4.1<br />

C-42-244-1 Cinch Lake Calcite 10.5 -1.9 320 5.4 -4.1<br />

Athabasca-type U 6 mineralization<br />

3705 Ace-Fay Dolomite 11.2 -1 235 3.3 -1.9<br />

3705-D Ace-Fay Dolomite 11.2 -0.9 235 3.3 -1.9<br />

Late calcite veins<br />

C-09-181 Cinch Lake Calcite 14.6 -2.5 140 1.2 -0.5<br />

C-16-220 Cinch Lake Calcite 12.8 -2.8 140 -0.6 -0.8<br />

C-42-244 Cinch Lake Calcite 13.4 -6.4 140 0.02 -4.5<br />

C-42-244D Cinch Lake Calcite 13.3 -6.5 140 -0.1 -4.6<br />

Table 3.5. Measured δ 18 O and δ 13 C for calcite and calculated δ 18 O fluid and δ 13 C fluid values for<br />

fluids in equilibrium with carbonate minerals for different generations of U mineralization in<br />

the Beaverlodge area. Paragenesis of all phases analyzed is shown in Figures 3.3 and 3.4 and<br />

data are plotted in Figure 3.8 (see the text for more details).<br />

Syn-ore Cal 8 calcite in the major breccia-type U 4 yields a wide range of δ 18 O values<br />

between 7.6 per mil and 22.2 per mil and δ 13 C values between -5.8 per mil and -1.6 per<br />

mil (Table 3.5). These values are similar to O and C isotopic compositions of calcite<br />

matrix from mineralized breccia reported by Tortosa (1983) at the Cenex deposit and to<br />

values reported by Sassano (1972) for the type-C calcite in the Ace-Fay deposit that he<br />

interpreted as syn-ore calcite-filling breccia. A formation temperature of 330°C was used<br />

to calculate δ 18 O fluid and δ 13 C fluid values, which range from 2.8 per mil to 17.4 per mil and<br />

-8.3 per mil to -4 per mil, respectively (Fig. 3.7; Table 3.5). The lowest δ 13 C fluid values<br />

(Fig. 3.7) likely reflect the influence of a reduced C source probably originating from the<br />

country rock with which the fluid has interacted (Fig. 3.7).<br />

Syn-ore Cal 9 calcite sampled from the volcanic-type U 5 mineralization has δ 18 O<br />

values ranging from 9.8 per mil to 20.8 per mil and δ 13 C values between -2.7 per mil and -<br />

1.1 per mil (Table 3.5). Using a formation temperature of 320°C (Table 3.3), the<br />

108

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