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Proposed Title 1: - Queen's University

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Syn-ore Chl 7 chlorite in breccia-type U 4 mineralization yields the relatively highest<br />

Fe contents of 25.78 weight percent (Table 3.3; Fig. 3.6C) and high Fe/(Fe+Mg) ratios of<br />

0.53, indicating that the U-bearing fluid was Fe-rich. The average Fe/(Mg+Fe) ratio is<br />

similar to values reported by Tortosa (1983) for Fe-chlorite associated with the<br />

mineralized zone at the Cenex mine. Chl 7 chlorite has a composition typical for chamosite<br />

corresponding to formation temperatures near 330°C (Table 3.3). Cal 8 calcite and U 4<br />

uraninite intergrowths with Chl 7 chlorite in conjunction with high F contents in Chl 7<br />

chlorite, suggest that the U-bearing fluid contained Ca and F (Table 3.3; Figs..3.6A and<br />

3.6B). Electron microprobe and backscattered images show that Chl 7 chlorite was<br />

subsequently altered by fluids that were Mg-rich. These altered chlorites have average<br />

formation temperatures near 195 o C (Table 3.4).<br />

Syn-ore Chl 8 chlorite in volcanic-type U 5 mineralization is an Mg-Fe-chlorite with a<br />

formation temperature of ca. 320°C (Table 3.3). Chl 8 chlorite has the highest Mn and Ti<br />

contents (Table 3.3; Figs. 3.6A and 3.6B), although the presence of Ti and Ca reflects Ttn 3<br />

titanite and Ap 1 apatite grains respectively, intergrown with Chl 8 chlorite and U 5 uraninite<br />

(Fig. 3.4I). Chl 8 chlorites were subsequently altered by later Mg-rich fluids, resulting in<br />

altered chlorites with formation temperatures near 210 o C (Table 3.4). Chl 9<br />

chlorite<br />

associated with the Athabasca-type U 6 mineralization has high Mg and Fe contents (15.43<br />

wt.% and 26.01 wt.%, respectively) and is typically F-Cl-rich (Table 3.3; Figs. 3.6A and<br />

3.6B), with formation temperatures of ca. 235°C (Table 3.3). The Fe/(Fe+Mg) ratio of<br />

Chl 9 chlorite ranges from 0.56 to 0.67 and indicates that the U-mineralizing fluid was<br />

likely Mg-rich.<br />

103

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