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$Fayek & Kyser 2000 uraninite fractionations.pdf - Queen's University$

Figure 3.2. Simplified geological map of the Beaverlodge area showing the location of the studied uranium deposits. (modified from Macdonald and Slimmon, 1985). The Paleoproterozoic Martin Lake Basin (Fig. 3.2) is a ca. 5000 m-thick, molasse, red-bed succession (Langford, 1981; Mazimhaka and Hendry, 1985; Morelli et al., 2001) 85
of essentially unmetamorphosed arkose, conglomerates and siltstone with mafic flows and sills of alkaline affinity (Morelli et al., 2009). The fault-controlled basin is confined to a broad open syncline centered on Martin Lake (Ramaekers, 1981; Ashton et al., 2001). Locally, extensive suites of east- to southeast striking mafic dikes, dated at 1818±4 Ma, are interpreted as feeders to the Martin Lake Basin mafic flows and sills (Morelli et al., 2009). The Martin Lake Basin formed during a period of active tectonism related to backarc extension (Dieng et al., 2011) following the peak Trans-Hudson Orogeny (Hoffman, 1989, 1990; Corrigan, 2009) and can be therefore classified as a successor basin (Clendenin et al., 1988). Overlying the Martin Lake Basin are outliers of the Paleoproterozoic to Mesoproterozoic Athabasca Formation (Rainbird et al., 2007). These occur south of the Beaverlodge area and consist of generally flat-lying, undeformed quartz sandstone with minor shale, conglomerate, and greywacke (Sibbald, 1983). 3.2.2. Uranium mineralization The Beaverlodge area hosts a multitude of U deposits (Fig. 3.2), which were actively mined between 1953 and 1963 from 284 deposits. Ore grades were generally in the range of 0.15 to 0.25 per cent U but in places, up to 0.4 per cent U (Robinson, 1955; Beck, 1969). About 25,000 t U was mined (Sibbald and Quirt, 1987), which is the equivalent of the Millennium deposit in the Athabasca Basin (Roy et al., 2005). Some previous investigators of the Beaverlodge U deposits reported a single event of U mineralization (Dudar, 1960; Sassano, 1972), but others described two mineralizing events (Turek, 1962). However, Tortosa (1983) identified five stages of U mineralization 86
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FLUID EVOLUTION AND STRUCTURAL CONT
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Abstract Uranium deposits associate
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Co-Authorship This thesis and the m
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Sarah Rice and Jonathan Cloutier, a
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TABLE OF CONTENTS Abstract………
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2.5.2. Temporal relationships of fa
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4.5.3. Isotopic compositions of min
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List of Figures Figure 1.1. General
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Figure 4.16. Distribution of 207 Pb
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Table 4.4. Isotopic data of the U-P
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processes by which these deposits f
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Figure 1.1. Generalized geological
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which is the equivalent of the Mill
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dolostone and carbonaceous shale (L
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Mineral Field (Figure 1.2). Many de
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2005). U mineralization is controll
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Figure 1.4. Schematic representatio
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In particular, the key issues to be
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genetic model for the U mineralizat
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fourth and most significant uranium
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The Beaverlodge area is part of the
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1998; Hartlaub and Ashton, 1998). R
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(D 1 ) produced a regional migmatit
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These previous age models do not ta
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the age when the concentrations of
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Figure 2.3. A: Detailed geologic ma
Page 53 and 54: hornblende-feldspar gneiss showing
Page 55 and 56: east-west striking en-échelon quar
Page 57 and 58: and broken Kfs 1 and Qtz 1 embedded
Page 59 and 60: A Meters LEGEND B Figure 2.6. A: De
Page 62 and 63: Figure 2.7. Microphotograph of vari
Page 64: eplaces Kfs 1 feldspars (Fig. 2.7A)
Page 67 and 68: the Qtz 1 quartz dissolution result
Page 69 and 70: Figure 2.9. Microphotograph of typi
Page 71 and 72: uraninite (Fig. 2.10). The errors o
Page 73 and 74: Figure 2.10. Backscattered Electron
Page 75 and 76: post-mineralization alteration duri
Page 77 and 78: Post-mineralization alteration even
Page 79 and 80: Volcanic-type ±U 5 (Sample 6139, G
Page 81 and 82: 6134 pt8a 2 Gunnar 82.92 2.92 5.30
Page 83 and 84: Regression to zero content of the s
Page 85 and 86: faults (Fig. 2.13C). The breccias w
Page 87 and 88: Figure 2.13. Schematic cross-sectio
Page 89 and 90: Mylonites were then reactivated at
Page 91 and 92: and thrusting during the 1.94-1.92
Page 93 and 94: Beaverlodge area (Morelli et al., 2
Page 95 and 96: dikes (Ernst and Buchan, 2001b) and
Page 97 and 98: Figure 2.15: Distribution of 207 Pb
Page 99 and 100: CHAPTER 3 GENESIS OF MULTIFARIOUS U
Page 101 and 102: eccia-type. The other styles of min
Page 103: The basement consist of Neoarchean
Page 107 and 108: WDX X-ray spectrometers at Carleton
Page 109 and 110: 3.4. Results 3.4.1. Paragenesis of
Page 111 and 112: are derived from their chlorite cry
Page 113 and 114: Figure 3.4. Photomicrographs of typ
Page 115 and 116: 3.4J). Py 6 Pyrite and Cpy 5 chalco
Page 117 and 118: mineralization varies from 25.70 to
Page 119 and 120: 6137APt71 60.67 13.73 4.59 6.48 0.0
Page 121 and 122: Fig. 3.6A). The Ca may result from
Page 123 and 124: Sample ID 1 ± 2 ± 3.a ± 4 ± 5.a
Page 125 and 126: Stable isotopic O and C composition
Page 127 and 128: Sample ID Deposit Mineral Mineral v
Page 129 and 130: equilibrium with a fluid having δ
Page 131 and 132: Syn-ore Chl 8 chlorite sampled from
Page 133 and 134: Figure 3.9. Binary diagrams showing
Page 135 and 136: Figure 3.10. Chondrite-normalized R
Page 137 and 138: Retrograde metamorphism Early vein
Page 139 and 140: contents in syn-ore Chl 4 chlorite
Page 141 and 142: decompression and hydration reactio
Page 143 and 144: mineralizations, which upgraded the
Page 145 and 146: metamorphic origin of the main U 4
Page 147 and 148: y the abundance of Ap 1 apatite and
Page 149 and 150: of late fluid events that have affe
Page 151 and 152: CHAPTER 4 FLUID EVOLUTION AND GENES
Page 153 and 154: 1990, 1991; Wyborn et al., 1990). H
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stable isotope geochemistry, U-Pb g
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coincident with the initiation of s
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plasma mass spectrometry (LA-HR-ICP
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The Coronation Hill deposit occupie
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arsenides, nickel selenide and copp
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No corrections were made to the 238
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which was interpreted as being asso
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porphyry and coated by Chl 1 formin
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Mineralized breccias showing quartz
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SOUTH ALLIGATOR RIVER GROUP EL SHER
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A Carbonaceous Shale B Src 1 Qtz 1
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A Granite Qtz 0 fragments Qtz 0 B M
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chemical composition as a result of
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Sample I.D SiO 2 CaO FeO ThO 2 MnO
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site occupancy (Cathelineau, 1988).
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Mineral values Temperature Fluid va
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Corrected ratios Apparent ages ( ±
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G H Figure 4.12. U-Pb concordia dia
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Figure 4.13. Pb-Pb isochron diagram
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and 4.12B), and to 207 Pb/ 206 Pb a
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160 o C at Coronation Hill. The tem
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Figure 4.15. Conceptual genetic mod
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of the Koolpin Formation, while dep
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at ca. 1820 Ma, approximately 40 My
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culminating with the formation of R
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deposits is related to fluids deriv
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CHAPTER 5 GENERAL DISCUSSION 5.1. I
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ed-bed strata and associated volcan
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character of the fluid that formed
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5.2.1.2. Metamorphic-related uraniu
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during brecciation or reduction as
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ca. 1820 Ma that triggered reactiva
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Plutons Event at 1.4 Ga (Barinek et
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Kolari-Kittila Province Kuusamo Pro
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The uranium deposits in various pro
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Fig. 5.6. Distribution of the Rorai
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Roraima Basin, similar to what is o
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etween ca. 2.3 Ga and 1.9 Ga. Later
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REFERENCES Adams, J., 1989. Postgla
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Ashton, K.E., 2010. The Gunnar Mine
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Bowles, J.F.W., 1990. Age dating of
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Cuney, M.L., 2005. World-class unco
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deposits in the Athabasca Basin, Sa
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Hartlaub, R.P., Heaman, L.M., Chack
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Saskatchewan Geological Survey, Sas
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Kyser, K., and Cuney, M., 2008. Geo
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two-sided oblique-slip collisional
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Creek Geosyncline: in ‘The minera
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Piper, J.D.A., 2004. Discussion on
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99.Sheppard SMF and Gilg HA 1996. S
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Proceedings Darwin Conference 1984
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Wingate, M.T.D, Pisarevsky SA, Evan
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Sample Deposit 207 Pb/ 206 Pb ±2σ
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APPENDIX B REE contents of various
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Sample Y Zr Cs Ba Th La Ce Pr Nd Sm
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Sample ΣREE TLREE THREE LREE/HREE
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SAMPLE ID. SiO 2 TiO 2 AL 2O 3 CR 2
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SAMPLE ID. SiO 2 TiO 2 AL 2O 3 CR 2
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APPENDIX E Electron microprobe data
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SAMPLE Si 4+ AL 4+ Total AL 6+ Ti 4
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SAMPLE Si 4+ AL 4+ Total AL 6+ Ti 4
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Sample ID. Deposit UO 2 SiO 2 CaO F
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Sample ID. Deposit UO 2 SiO 2 CaO F
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Sample ID. Al 2O 3 CaO FeO K2O MgO
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Sample ID. Al 2O 3 CaO FeO K2O MgO
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250 85 330 40 145 70 25 65 30 30 27
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Mineralized veins Quartz veins 276
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