Scientific career of Fabrizio Cavani in brief Scientific Interests

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Scientific collaborations with French Scientists During his career, FC has established strong scientific relationships with French scientists, both from industrial companies and public research bodies, that led to several joint publications in international journals. Especially in the field of catalytic selective oxidation, collaborations established allowed the understanding of the interaction between catalysts and reactive substrates, for reactions such as the ammoxidation of propane to acrylonitrile, the oxidation of n-butane to maleic anhydride, the oxidative dehydrogenation of isobutyric acid and the selective oxidation of isobutane to methacrylic acid, and the oxidative dehydrogenation of alkanes to alkenes. Articles jointly published with French scientists: In collaboration with scientists from the Univ. of Lille S. Albonetti, F. Cavani, F. Trifirò, M. Gazzano, M. Koutyrev, F.C. Aissi, A. Aboukais, M. Guelton, "Mechanism of Thermal Decomposition of Potassium/Ammonium Salts of the 12- Molybdophosphoric Acid and Effect on the Catalytic Performance in the Isobutyric Acid Oxidehydrogenation", J. Catal., 146 (1994) 491-502 E. Etienne, F. Cavani, R. Mezzogori, F. Trifirò, G. Calestani, L. Gengembre, M. Guelton, “Chemical-physical characterization of Fe-doped, Keggin-type P/Mo polyoxometalates, catalysts for the selective oxidation of isobutane to methacrylic acid” Special issue: Heteropoly Acids Special Issue - Edited by I. Kiricsi, Appl. Catal., A: General, 256/1-2 (2003) 275-290 N. Ballarini, F.Cavani, E. Degli Esposti, D. De Santi, S. Luciani, F. Trifirò, C. Cortelli, R. Leanza, G. Mazzoni, A. Brückner, E. Bordes-Richard, “The dynamic nature of vanadyl pyrophosphate, catalyst for the selective oxidation of n-butane to maleic anhydride”, In “Catalysis of Organic Reactions “, M.L. Prunier (Ed.), CRC Press, Boca Raton, 2009, p. 485-490. F. Cavani, D. De Santi, S. Luciani, A. Lofberg, E. Bordes-Richard, C. Cortelli, R. Leanza, “Transient reactivity of vanadyl pyrophosphate, the catalyst for n-butane oxidation to maleic anhydride, in response to in-situ treatments”, Appl. Catal. A 376 (2010) 66–75 In collaboration with scientists from CNRS E. Garcin, R. Surantyn, A. Chambosse, A. Foucault, G. Coudurier, J.C. Volta, J.Ph. Nogier, A.M. De Kersabiec, F. Cavani, J. Van Ommen, B. Grzyvbowska, M. Czervenka, K. Malec, A. Andersson, "Chemical characterization of Eurocat Ti-V-O catalysts", Catal. Today, 20 (1994) 23-34 F. Cavani, A. Colombo, F. Trifirò, M.T. Sananes Schulz, J.C. Volta and G.J. Hutchings, "The effect of cobalt and iron dopants on the catalytic behavior of V/P/O catalysts in the selective oxidation of n-pentane to maleic and phthalic anhydrides", Catal. Lett., 43 (1997) 241-247 M. Cimini , J.-M.M. Millet, F. Cavani, “Mechanisms of molybdenum substitution in vanadium antimonate “, J. Solid State Chem., 177 (4-5) (2004) 1045-1052 M. Cimini, J. M. M. Millet, N. Ballarini, F. Cavani, C. Ciardelli and C. Ferrari, “Synthesis, characterization and evaluation as catalysts for propane ammoxidation of VMoSbO systems with rutile-type structure “, Catal. Today, 91-92 (2004) 259-264
N. Ballarini, F. Cavani, M. Cimini, F. Trifirò, J.M.M. Millet, U. Corsaro, R. Catani, “Role of Nb in rutile-type Cr/V/Nb/Sb mixed oxides, catalysts for propane ammoxidation to acrylonitrile”, J. Catal., 241 (2006) 255-267 N. Ballarini, F. Cavani, M. Cimini, G.M. Mascanzoni, F. Trifirò, J.-M- Millet, M. Banares, M.O. Guerriero-Perez, U. Cornaro, R. Catani, “Role of Nb in rutile-type metal antimonates for propane ammoxidation”, Proceedings Fifth Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, luglio 2006 “Sience and Technology in catalysis 2006”, Stud. Surf. Sci. Catal., 172 (2007) 145-149 In collaboration with scientists from Atochem (then TotalFinaElf, then Arkema) F. Cavani, E. Etienne, M. Favaro, A. Galli, F. Trifirò, G. Hecquet, "Enhancement of catalytic activity of the ammonium/potassium salt of 12-molybdophosphoric acid by iron ion addition for the oxidation of isobutane to methacrylic acid", Catal. Lett., 32 (1995) 215-226 F. Cavani, E. Etienne, G. Hecquet, G. Selleri, F. Trifirò, "Multi-Step and Single-Step Gas-Phase Selective Oxidation of Isobutane to Methacrylic Acid as an Alternative Process to the Acetone Cyanohydrin Route", in "Catalysis of Organic Reactions", R.E. Malz (Ed.), Marcel Dekker, New York (1996), p. 107-117, Pubblicato a New York, 1996 F. Cavani, E. Etienne, F. Trifirò, "Application d'un catalyseur supporté à base d'oxyde de chrome à la deshydrogénation oxydante d'hydrocarbures paraffiniques en les monooléfines correspondantes", France Patent 2,748,021 A1 (1997). Assegnato ad Elf Atochem. D. André, A. Belletti, F. Cavani, H. Degrand, J.-L. Dubois, F. Trifirò, “Molybdenum oxide-based systems, prepared starting from Anderson-type polyoxometalates precursors, as catalysts for the oxidation of i-C4 hydrocarbons”, Stud Surf Sci Catal, 155 (2005) 57-66. D. André, F. Cavani, H. Degrand, J.L. Dubois, C. Lucarelli, F. Trifirò, “Isobutene and Isobutane Oxidation over Molybdenum Oxide-Based Catalysts, Prepared Starting from Anderson-type Polyoxometalates Precursors”, Proceedings DGMK Conference “C4/C5-Hydrocarbons: Routes to higher value-added products”, ottobre 2004, Munich, D, DGMK-Tagungsbericht 2004-3, ISBN 3- 936418-23-3, p. 289-296 N. Ballarini, F. Candiracci, F. Cavani, H. Degrand, J.-L. Dubois, G. Lucarelli, M. Margotti, A. Patinet, A. Pigamo and F. Trifirò, “The dispersion of Keggin-type P/Mo polyoxometalates inside silica gel, and the preparation of catalysts for the oxidation of isobutane to methacrolein and methacrylic acid”, Appl. Catal. A, 325 (2007) 263-269. N. Ballarini, F. Cavani, H. Degrand, E. Etienne, A. Pigamo, F. Trifirò, J.L. Dubois, “The oxidation of isobutane to methacrylic acid: an alternative techonology for MMA production”, In “Methods and Reagents for Green chemistry”, P. Tundo, A. Perosa, F. Zecchini, eds. John Wiley and Sons, Hoboken, 2007, p. 265-279 In collaboration with scientists from Rhone Poulenc (then Rhodia)
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Page 3 and 4: Main scientific and technological a
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Scientific career of Fabrizio Cavani in brief Scientific Interests

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