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Environmental Technologies and Eco-innovation in the Czech ...

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pressure, it complies with <strong>the</strong> strictest requirements for many liquid filtration<br />

facilities. Nano-fibres may <strong>the</strong>refore help to resolve <strong>the</strong> global lack of dr<strong>in</strong>k<strong>in</strong>g water,<br />

may help to make sea water desal<strong>in</strong>isation easier <strong>and</strong> more efficient.<br />

Fur<strong>the</strong>rmore, nano-fibres may be used <strong>in</strong> produc<strong>in</strong>g energy from renewable<br />

resources. Nano-fibres can replace both classical silica cells <strong>and</strong> <strong>the</strong> new generation<br />

of cells with nano-composites 10 . They also enable operation <strong>in</strong> aggravated light<br />

conditions (no sunsh<strong>in</strong>e) <strong>and</strong> <strong>the</strong> use of mobile power sources (<strong>the</strong> comb<strong>in</strong>ation of<br />

solar cells with batteries for nano-fibres).<br />

5.3 | Absorption materials based on natural m<strong>in</strong>erals<br />

Natural materials that may be used as absorbents for water contam<strong>in</strong>ants or waste<br />

gases <strong>in</strong>clude m<strong>in</strong>erals such as montmorillonite, bentonite, kaol<strong>in</strong>ite, halloysite,<br />

etc. However, natural m<strong>in</strong>erals are hydrophilic 11 <strong>and</strong> are unsuitable for absorb<strong>in</strong>g<br />

organic pollutants. They feature layered structures with a layer thickness of ca 1 nm.<br />

The space between <strong>in</strong>dividual layers, <strong>the</strong> <strong>in</strong>terlayer, is filled with <strong>in</strong>organic cations<br />

which compensate for <strong>the</strong> negative charge <strong>in</strong> <strong>in</strong>ner layers of a m<strong>in</strong>eral. Replac<strong>in</strong>g<br />

<strong>in</strong>organic cations <strong>in</strong> <strong>in</strong>terlayers by organic cations causes changes to <strong>the</strong> m<strong>in</strong>eral’s<br />

properties <strong>and</strong> <strong>the</strong>refore becomes organophilic 12 <strong>and</strong> enables <strong>the</strong> absorption of<br />

organic pollutants. The properties of absorbents are given by organic cations used.<br />

For clay m<strong>in</strong>erals, m<strong>in</strong>erals based on smectites are <strong>the</strong> most frequently used for <strong>the</strong>se<br />

modifications to environmental technologies. For waste water treatment technologies,<br />

organically modified clays may be used separately as absorption materials for treat<strong>in</strong>g<br />

waste water contam<strong>in</strong>ated by organic compounds, e.g. crude oil hydrocarbons, or <strong>in</strong><br />

comb<strong>in</strong>ation with active coal. They can form a part of <strong>the</strong> clay barriers <strong>and</strong> absorbents<br />

of organic substances <strong>in</strong> dumps.<br />

Ano<strong>the</strong>r suitable natural material seems to be vermiculite, whose use is currently<br />

be<strong>in</strong>g analysed at <strong>the</strong> University of M<strong>in</strong><strong>in</strong>g – <strong>the</strong> Technical University of Ostrava. The<br />

research is ma<strong>in</strong>ly aimed at prepar<strong>in</strong>g <strong>and</strong> test<strong>in</strong>g organically modified vermiculite for<br />

absorption of organic substances from waste water <strong>and</strong> gases. Organically modified clay<br />

has been made from vermiculite m<strong>in</strong>ed <strong>in</strong> <strong>the</strong> <strong>Czech</strong> deposit of Letovice <strong>and</strong> efficiently<br />

absorbs organic substances found <strong>in</strong> waste water.<br />

10 nano-composites – materials consist<strong>in</strong>g of two or more different components where one of <strong>the</strong>m is up to tens of nanometers;<br />

<strong>the</strong>se are mostly nano-particles of active substances<br />

11 hydrophilic – able to absorb water or be diluted <strong>in</strong> water<br />

12 organophilic – able to bound organic substances or dilute <strong>in</strong> organic solvents

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