Environmental Technologies and Eco-innovation in the Czech ...
Environmental Technologies and Eco-innovation in the Czech ...
Environmental Technologies and Eco-innovation in the Czech ...
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cooperation with <strong>the</strong> Faculty of Electrical Eng<strong>in</strong>eer<strong>in</strong>g <strong>and</strong> Information Technology of<br />
<strong>the</strong> Technical University <strong>in</strong> Brno, <strong>the</strong> Faculty of Electrical Eng<strong>in</strong>eer<strong>in</strong>g of CTU <strong>in</strong> Prague<br />
<strong>and</strong> <strong>the</strong> Institute of Scientific Instruments <strong>in</strong> Brno.<br />
5.1.2 | Th<strong>in</strong>-film structures <strong>and</strong> semiconductor materials<br />
The most widely spread technology <strong>in</strong> this field is structures based on amorphous<br />
hydrogenated silica <strong>and</strong> microcrystall<strong>in</strong>e silica. Long-term research <strong>and</strong> development<br />
is be<strong>in</strong>g conducted at <strong>the</strong> Institute of Physics of <strong>the</strong> Academy of Sciences on <strong>the</strong> <strong>Czech</strong><br />
Republic <strong>in</strong> Prague. The ma<strong>in</strong> aim of <strong>the</strong> research is to study <strong>the</strong> optoelectronic<br />
properties 1 of non-crystall<strong>in</strong>e forms of silica <strong>and</strong> produce optic models of solar cell<br />
structures. At <strong>the</strong> Institute, methods were implemented to analyse <strong>the</strong> magnitude<br />
of defects <strong>in</strong> amorphous <strong>and</strong> crystall<strong>in</strong>e silica. Fur<strong>the</strong>rmore, a workplace has been<br />
established for produc<strong>in</strong>g th<strong>in</strong> films with <strong>the</strong> possibility of <strong>in</strong>-situ characterisation of<br />
topography as well as <strong>the</strong> morphology of layered surfaces.<br />
The Research Centre for New <strong>Technologies</strong> at <strong>the</strong> University of West Bohemia <strong>in</strong> Plzeň<br />
also deals with th<strong>in</strong> films. The research is aimed at deposit<strong>in</strong>g <strong>and</strong> characteris<strong>in</strong>g<br />
<strong>the</strong> physical properties of transparent conductive oxides, amorphous hydrogenated<br />
silica, microcrystall<strong>in</strong>e silica <strong>and</strong> recrystallised polycrystall<strong>in</strong>e silica. Significant<br />
results have been obta<strong>in</strong>ed <strong>in</strong> <strong>the</strong> stabilisation of layers of amorphous hydrogenated<br />
silica aga<strong>in</strong>st degradation as a consequence of <strong>the</strong> long-term actuation of light. This<br />
has been also verified <strong>in</strong> <strong>the</strong> structure of a photovoltaic cell.<br />
Organic <strong>and</strong> polymeric 2 semi-conductor materials are <strong>the</strong> youngest technological<br />
branch that has a huge development potential because of <strong>the</strong>ir significantly lower<br />
costs. They are currently <strong>in</strong> <strong>the</strong> <strong>in</strong>itial research phase. Although it is <strong>the</strong> youngest<br />
branch of photovoltaics, <strong>the</strong> volume of research activities exceeds that of o<strong>the</strong>r<br />
branches <strong>in</strong> <strong>the</strong> <strong>Czech</strong> Republic. Syn<strong>the</strong>sis<strong>in</strong>g <strong>and</strong> study<strong>in</strong>g properties of organic<br />
<strong>and</strong> polymeric materials for photovoltaics are <strong>the</strong> subject of <strong>the</strong> research be<strong>in</strong>g<br />
simultaneously conducted at several workplaces. The most significant <strong>in</strong> this field is <strong>the</strong><br />
Institute of Macromolecular Chemistry of <strong>the</strong> Academy of Sciences of <strong>the</strong> <strong>Czech</strong> Republic<br />
<strong>in</strong> Prague where complex research <strong>and</strong> development of new polymeric materials<br />
<strong>and</strong> systems is be<strong>in</strong>g conducted for <strong>the</strong> application <strong>in</strong> photovoltaics <strong>in</strong>clud<strong>in</strong>g <strong>the</strong><br />
1 optoelectronic properties – <strong>the</strong> summary of optical <strong>and</strong> electronic properties of semiconductor materials reflect<strong>in</strong>g <strong>the</strong>ir<br />
electronic structure (<strong>the</strong> density of electron states, valence <strong>and</strong> conduction b<strong>and</strong>, <strong>the</strong> magnitude <strong>and</strong> power distribution of<br />
defects, spectral dependence of absorption coefficient, etc.)<br />
2 polymeric semi-conductor materials – new types of organic semiconductors that replace costly cells that are mostly made of<br />
silica<br />
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