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cryogenic filling: State-of-the-art and perspectives (Linde / Reijerkerk)

cryogenic filling: State-of-the-art and perspectives (Linde / Reijerkerk)

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“Conventional” <strong>cryogenic</strong> LH2<br />

refuelling technology<br />

StorHy , June 3rd 2008, Paris


“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies:<br />

stationary installation<br />

2


“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies:<br />

stationary installation<br />

3


“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies:<br />

stationary installation<br />

4


“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies:<br />

stationary installation<br />

5


“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies:<br />

stationary installation<br />

6


“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies:<br />

relocatable installation<br />

7


“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies:<br />

relocatable installation<br />

8


“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies<br />

<strong>State</strong> <strong>of</strong> <strong>the</strong> Art – Filling Process<br />

Dispenser integrated weight compensation system<br />

Verknüpfung mit Ablauf.lnk<br />

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“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies<br />

<strong>State</strong> <strong>of</strong> <strong>the</strong> Art – Refuelling Interface<br />

Vehicle<br />

Station<br />

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“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies<br />

<strong>State</strong> <strong>of</strong> <strong>the</strong> Art – Filling Process – future challenges<br />

<strong>State</strong> <strong>of</strong> <strong>the</strong> Art<br />

— LH2 Filling process (incl. storage, sub-cooling) has been installed<br />

<strong>and</strong> daily operated at public refueling sites<br />

— System is highly reliable <strong>and</strong> shows repeatable performance<br />

— A sub-cooled refueling rate <strong>of</strong> 50 litres /min* is st<strong>and</strong>ard for<br />

refueling with LH2 transfer pumps<br />

— The refueling process <strong>and</strong> hardware has proven functionality in a<br />

temperature range <strong>of</strong> -40°C to +80°C<br />

— More than 30.000 <strong>filling</strong>s performed (Status Q1 2008)<br />

* Conventional fuels Diesel <strong>and</strong> Gasoline are refueled at 50litres/min at public refuelling sites<br />

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“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies<br />

<strong>State</strong> <strong>of</strong> <strong>the</strong> Art – Filling Process – future challenges<br />

Future Challenges <strong>of</strong> LH2 <strong>filling</strong> process<br />

— Advancement <strong>of</strong> data interface (non-mechanical connection,<br />

dataset)<br />

— Calibratable <strong>cryogenic</strong> LH2 flow measurement<br />

— Minimization <strong>of</strong> H2 “return-gas” during <strong>filling</strong> by<br />

improvements <strong>of</strong> receiving tank (less pressure losses)<br />

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“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies<br />

<strong>State</strong> <strong>of</strong> <strong>the</strong> Art – Filling Process – future challenges<br />

Minimize <strong>of</strong> H2 “return-gas” during <strong>filling</strong><br />

Zero H2-Return gas <strong>filling</strong> with sub-cooled LH2 is proven <strong>and</strong> tested<br />

Necessary precautions to meet <strong>the</strong> technical requirements are:<br />

— Pre-cooling <strong>of</strong> <strong>filling</strong> line at <strong>the</strong> <strong>filling</strong> station to less than 80 K<br />

— Filling line as short as possible<br />

— Minimized pressure losses in valves <strong>and</strong> tubes inside <strong>the</strong> vehicle<br />

tank system (Goal: pressure losses


“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies<br />

Test: Zero <strong>filling</strong> losses due to sub-cooled LH2 (1994)<br />

Filling<br />

volume<br />

(litre)<br />

Filling<br />

losses<br />

Filling time<br />

Storage vessel<br />

Vehicle vessel<br />

Filling-line precooled<br />

Average <strong>filling</strong> flow<br />

Max. <strong>filling</strong> flow<br />

subcooled hydrogen 3,6 barg, about 21,8 K<br />

3 barg, about 26 K, special spraying liquid <strong>filling</strong> line<br />

80 K<br />

2400 ltr/h = 170 kg/h<br />

5000 ltr/h = 354 kg/h<br />

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“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies<br />

Test: Zero <strong>filling</strong> losses due to sub-cooled LH2 (2003)<br />

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Thank you for your attention.<br />

www.linde.com/hydrogen


“Conventional” <strong>cryogenic</strong> <strong>filling</strong> technologies<br />

<strong>State</strong> <strong>of</strong> <strong>the</strong> Art – Filling Process<br />

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