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Hexion Methanol Spill - U.S. National Response Team (NRT)

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Region 4 Regional <strong>Response</strong><br />

<strong>Team</strong> (RRT)<br />

North Carolina<br />

Kenneth Rhame<br />

EPA On Scene Coordinator (OSC)<br />

NC State University<br />

Raleigh NC<br />

919-475<br />

475-73977397 cell<br />

404-562<br />

562-8700 24 hour<br />

800-424<br />

424-8802<br />

<strong>National</strong><strong>Response</strong> Center


NRC Report - <strong>Hexion</strong><br />

Incident Report # 890607<br />

INCIDENT DESCRIPTION<br />

*Report taken by: MST2 JAQUELINE ARSENAULT at 21:01 on 20-NOV-08<br />

Incident Type: FIXED<br />

Incident Cause: EQUIPMENT FAILURE<br />

Affected Area:<br />

Incident was discovered on 20-NOV-08 at 19:30 local incident time.<br />

Affected Medium: SUBSURFACE BELOW GROUND<br />

_______________________________________________________________________<br />

REPORTING PARTY<br />

Name: MICHELLE WEST<br />

Organization: HEXION SPECIALTY CHEMICALS<br />

Address: 1141 INDUSTRIAL DRIVE<br />

FAYETTEVILLE, NC 28301<br />

HEXION SPECIALTY CHEMICALS reported for the responsible party.<br />

PRIMARY Phone: (910)9886139<br />

Type of Organization: PRIVATE ENTERPRISE<br />

_______________________________________________________________________<br />

SUSPECTED RESPONSIBLE PARTY<br />

Name: MICHELLE WEST<br />

Organization: HEXION SPECIALTY CHEMICALS<br />

Address: 1141 INDUSTRIAL DRIVE<br />

FAYETTEVILLE, NC 28301<br />

PRIMARY Phone: (910)9886139<br />

________________________________________________________________________<br />

INCIDENT LOCATION<br />

1141 INDUSTRIAL DRIVE County: CUMBERLAND<br />

City: FAYETTEVILLE State: NC Zip: 28301<br />

_______________________________________________________________________<br />

RELEASED MATERIAL(S)<br />

CHRIS Code: MAL Official Material Name: METHYL ALCOHOL<br />

Also Known As:<br />

Qty Released: 0 UNKNOWN AMOUNT<br />

________________________________________________________________________<br />

DESCRIPTION OF INCIDENT<br />

AN INVENTORY DISCREPANCY INVESTIGATION REVEALED A RELEASE OF<br />

METHANOL FROM A PROCESS LINE. PRESSURE TESTING CONDUCTED ON THE LINE<br />

FAILED. THE QUANTITY OF METHANOL THAT WAS RELEASED IS UNKNOWN.<br />

________________________________________________________________________<br />

INCIDENT DETAILS<br />

Package: NO<br />

Building ID:<br />

Type of Fixed Object: CHEMICAL FACILITY<br />

Power Generating Facility: NO<br />

Generating Capacity:<br />

______________________________________________________________________<br />

IMPACT<br />

Fire Involved: NO Fire Extinguished: UNKNOWN<br />

INJURIES: NO Hospitalized: Empl/Crew: Passenger:<br />

FATALITIES: NO Empl/Crew: Passenger: Occupant:<br />

EVACUATIONS:NO Who Evacuated: Radius/Area:<br />

Damages: NO<br />

Hours Direction of<br />

Closure Type Description of Closure Closed Closure<br />

N<br />

Air:<br />

N Major<br />

Road: Artery:N<br />

N<br />

Waterway:<br />

N<br />

Track:<br />

Environmental Impact: NO<br />

Media Interest: NONE Community Impact due to Material:<br />

______________________________________________________________________<br />

REMEDIAL ACTIONS<br />

INVESTIGATION IS CURRENTLY UNDERWAY; CLEANUP NOT YET BEGUN<br />

Release Secured: YES<br />

Release Rate:<br />

Estimated Release Duration:<br />

______________________________________________________________________<br />

WEATHER<br />

Weather: UNKNOWN, ºF<br />

______________________________________________________________________<br />

ADDITIONAL AGENCIES NOTIFIED<br />

Federal: NONE<br />

State/Local: NONE<br />

State/Local On Scene: NONE<br />

State Agency Number: NONE<br />

_______________________________________________________________________<br />

ADDITIONAL INFORMATION<br />

CALLER STATED THAT THIS RELEASE MAY HAVE BEEN OCCURRING SINCE<br />

SEPTEMBER 2008. CALLER INTENDS TO NOTIFY SERC.


• No quantity indicated<br />

• No conditions of the<br />

spill indicated<br />

• No facility capacity for<br />

methanol although<br />

there were 2-500,0002<br />

gallon AST’s s on-site<br />

that were connected to<br />

the pipeline<br />

• No indication of the<br />

Cape Fear River being<br />

impacted<br />

NRC Report


<strong>Spill</strong> Reporting Issues<br />

• The spill had been<br />

occurring since Sep<br />

2008<br />

• The Reportable Quantity<br />

is 5,000 lbs<br />

• The company thought<br />

the reported losses were<br />

an accounting error<br />

• The Line was pressure<br />

tested within the last<br />

year and passed<br />

• 90% of the line is above<br />

ground and no leaking<br />

was visible


<strong>Spill</strong> Reporting Issues<br />

• The company could not produce<br />

the spill amount until 24 hours<br />

after the spill was reported<br />

• Once the spill quantity was<br />

reported it was 234,000 gallons<br />

spilled over a three month<br />

period.


<strong>Hexion</strong> <strong>Methanol</strong> <strong>Spill</strong>


Cleanup activities<br />

• The RP is using their<br />

contractor for cleanup<br />

who has been<br />

contracted under the NC<br />

voluntary cleanup<br />

program.<br />

• The contractors<br />

excavated the<br />

underground line and<br />

identified the leak.


Cleanup Activities<br />

• Since the spill was reported over the<br />

weekend sampling could not be completed<br />

for several days<br />

• Using specific weight <strong>Hexion</strong>, , EPA, and<br />

contractors were able to determine the<br />

percent methanol in the spill area.<br />

• The ditch area was 5 to 7% methanol in<br />

surface water (40 meters from source)<br />

• The spill area was as high as 93% methanol<br />

in groundwater at the source


Cleanup Activities<br />

• The RP bermed the ditch and collected water at the<br />

ditch to ensure no further methanol reached the Cape<br />

Fear River.<br />

• A bypass was installed to divert rainwater around the<br />

ditch to avoid collection of excessive storm water.


Cleanup Activities<br />

• RP contractors installed 4 recovery wells to extract<br />

groundwater around the spill area.<br />

• To date 43,672 gallons of methanol have been<br />

recovered.<br />

• <strong>Methanol</strong> Concentrations in the ditch are currently<br />

0.92%, the recovery wells are between 11% and 22%.


Conclusion<br />

• Proper investigation of missing methanol<br />

could have prevented thousands of gallons<br />

from reaching the Cape Fear River<br />

• Once the report was made it took a day to<br />

get a actual quantity of released methanol<br />

• The RP is close to a agreement with the<br />

state to put the methanol recovery into<br />

the voluntary cleanup program.


Region 4 Regional <strong>Response</strong><br />

Kenneth Rhame EPA On-<br />

Scene Coordinator (OSC)<br />

NC State University<br />

Raleigh NC<br />

919-475<br />

475-73977397 cell<br />

404-562<br />

562-8700 24 hour<br />

800-424<br />

424-8802 <strong>National</strong><br />

<strong>Response</strong> Center<br />

<strong>Team</strong> (RRT)<br />

North Carolina


INCREASING NUMBER OF<br />

ABANDONED FACILITIES?<br />

A EPA Emergency <strong>Response</strong> or Removal was<br />

conducted at these abandoned Facilities in North<br />

Carolina last year.<br />

• Component Concepts<br />

• Beasley Lumber Company<br />

• Fieldcrest Cannon Plant #7<br />

• Whiten Roberts Plant #2<br />

• Enfield Transformer<br />

• Superior Products<br />

Due to economic hard times, we could see an increased<br />

number of bankrupt facilities.


COMPONENT CONCEPTS<br />

North Carolina DENR Division of Waste Referred the Site<br />

to US EPA after several failed attempts of contacting the<br />

responsible parties. The Site is Stridemark, , LLC (d/b/a(<br />

Component Concepts) known locally as Component<br />

Concepts. Component Concepts had entered into a<br />

"voluntary bankruptcy" with Fifth Third Bank and<br />

recently closed operations at its 200 Mason Way facility,<br />

located in Thomasville, NC.


MIXING ROOM<br />

A residential neighborhood was located<br />

within 1500 feet from this facility.


DRUMS BEHIND LOADING<br />

DOCK DOOR


FROZEN-BULGING DRUM


LOADING DOCK -<br />

ICE FORMING


DRUMS IN BOILER ROOM


TOTE ON MAIN FLOOR


BEASLEY LUMBER<br />

COMPANY<br />

• Beasley Lumber Company went bankrupt<br />

20 years ago. Metal scrapping thieves in<br />

an attempt to steal two metal above<br />

ground storage tanks (15,000 gallons<br />

each) released #6 oil to a ditch that is a<br />

tributary to the Roanoke River. Estimated<br />

release was 6,000 gallons.


15,000 Gallon Above Ground Storage Tank<br />

Tree was shoved into the drain hole by local<br />

fire dept to contain the spill.


Absorbent Boom Placed Downstream<br />

Creek flowed behind a bird Sanctuary (Sylvan<br />

Heights).


Oiled Wood Duck<br />

Oiled Creek


Oiled Ditch<br />

Oiled Ditch prior to entering creek.


FIELDCREST CANNON<br />

PLANT #7<br />

• Approximately 15,000 gallons of fuel<br />

oil and 3,000 gallons of pcb tranformer<br />

oil spilled at an abandoned Fieldcrest<br />

Cannon Plant. Release is believed to<br />

have been caused by copper thieves<br />

stealing copper pipe from the<br />

transformer and boiler room. <strong>Spill</strong><br />

impacted a small drainage ditch that is<br />

a tributary to the Yadkin River.


Fieldcrest Cannon Plant #7<br />

Abandoned Facility in Salisbury NC.


Absorbent Boom<br />

Oiled Ditch


Stockpile of pcb Contaminated Soil<br />

3,000 gallons of pcb (1,300 ppm) ) oil was spilled<br />

when thieves stole copper from the transformers.


Unknown Material<br />

Some unknown material was also left behind<br />

when the facility closed.


Bedding<br />

Homeless were accessing the facility for<br />

shelter and potentially exposing themselves to<br />

asbestos.


WHITEN ROBERTS PLANT 2<br />

• EPA, at the request of the NCDER Hazwaste<br />

Section responded to a facility in Sanford,<br />

NC where 35 abandoned drums/containers<br />

were discovered. Several drums were<br />

identified as leaking. Multiple fires have<br />

occurred at the facility believed to have<br />

been caused by metal thieves using torches<br />

to steel metal. Residential neighborhood<br />

located across the street.


Whiten Roberts Plant 2<br />

Bankrupt Facility in Sanford, NC.


Drums of Unknown Waste Left Behind<br />

Various unknowns left behind in leaking<br />

containers.


TOWN OF ENFIELD<br />

TRANSFORMER SPILL<br />

• Copper Thieves caused a release of<br />

approximately 600 gallons of transformer<br />

oil containing 274 parts per million<br />

polychlorinated biphenyls (pcb(<br />

pcb’s).


Superior Products<br />

• Tank Thieves began overturning ASTs<br />

releasing contents (oils, solvents, acids) to<br />

surface soils.<br />

• Creek ran adjacent to the facility<br />

• Thieves claimed that they were the<br />

property owner and signed NOFI and<br />

access agreement.


Superior Products


Approximately 15,000 Gallons of<br />

Various Hazardous Substances and<br />

Oils Released


Current Economic Conditions<br />

• More Bankrupt Facilities<br />

• More <strong>Spill</strong>s Due to Facilities Making Cut-<br />

Backs on Maintenance and Personnel<br />

• Disgruntled Former (Laid-Off) Employees<br />

Vandalizing Former Employer

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