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Contents
ix
5.7.2 Fullerene-Based Phototransistors and
Electro-Optic Circuits 227
5.8 Summary and Perspectives 230
6 Carbon Nanohorns Chemical Functionalization 239
Georgia Pagona and Nikos Tagmatarchis
6.1 Introduction 240
6.2 Chemical Functionalization of CNHS 243
6.2.1 Covalent Functionalization 243
6.2.1.1 1,3-dipolar cycloaddition of in situ
generated azomethine ylides 243
6.2.1.2 Aryl addition via in situ generated aryl
diazonium salts 246
6.2.1.3 Bingel cyclopropanation reaction 247
6.2.1.4 Anionic polymerization 249
6.2.1.5 Bulk free radical polymerization 250
6.2.1.6 NaNH 2 addition and amination
reactions 250
6.2.1.7 Oxidation 252
6.2.2 Non-Covalent Functionalization 257
6.3 Conclusions and Outlook 262
7 Endohedral Metallofullerene Functionalization 269
Yutaka Maeda, Takeshi Akasaka, and Shigeru Nagase
7.1 Introduction 270
7.2 Reduction and Oxidation 270
7.3 Disilylation 272
7.4 Reaction with Nitrogen Compounds 275
7.5 Prato Reaction 276
7.6 Cycloaddition of Diene and Benzyne 279
7.7 Addition of Carbene 281
7.8 Nucleophilic Addition 284
7.9 Radical Addition 287
7.10 Conclusion 290
8 Quantum Computing with Endohedral Fullerenes 299
Kyriakos Porfyrakis and Simon C. Benjamin
8.1 Introduction 299