2009 Market Slurries and Particles in CMP & a Bit ... - Techcet Group

2009 Market Slurries and Particles in CMP & a Bit ... - Techcet Group 2009 Market Slurries and Particles in CMP & a Bit ... - Techcet Group

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• Silica Comes in 3 Types Silica for CMP • “Fumed”: flame vapor-phase hydrolysis of SiCl 4 or the like … 3 major suppliers • “Colloidal”: precipitated from sodium silicate & H 2 SO 4 ... >8 suppliers • “Sol”: Stöber process condensation of silicon alkoxide (TEOS, TMOS) w/ ammonia & water, at least 2 major suppliers • Abrasives and Applications • Oxide/ILD ≤65nm use less aggressive particles: fumed to colloidal or milled fumed • Copper “Step 1” predominately uses Colloidal • Copper Barrier (and Dielectric Cap) uses Colloidal or Sol • Tungsten fumed and colloidal KHolland@Techcet.com AVS CMP-UG 07/2009 4

Annual Revenue (M$USD) IC CMP Slurry Growth ? 1,200 1,000 800 600 400 200 Cu Barrier Cu Step 1 Tungsten Oxide ☺ ? 0 S-STI 2006 2007 2008 2009 2010 2011 2012 KHolland@Techcet.com AVS CMP-UG 07/2009 5

• Silica Comes <strong>in</strong> 3 Types<br />

Silica for <strong>CMP</strong><br />

• “Fumed”: flame vapor-phase hydrolysis of SiCl 4 or the<br />

like … 3 major suppliers<br />

• “Colloidal”: precipitated from sodium silicate & H 2 SO 4 ...<br />

>8 suppliers<br />

• “Sol”: Stöber process condensation of silicon alkoxide<br />

(TEOS, TMOS) w/ ammonia & water, at least 2 major<br />

suppliers<br />

• Abrasives <strong>and</strong> Applications<br />

• Oxide/ILD ≤65nm use less aggressive particles: fumed<br />

to colloidal or milled fumed<br />

• Copper “Step 1” predom<strong>in</strong>ately uses Colloidal<br />

• Copper Barrier (<strong>and</strong> Dielectric Cap) uses Colloidal or Sol<br />

• Tungsten fumed <strong>and</strong> colloidal<br />

KHoll<strong>and</strong>@<strong>Techcet</strong>.com AVS <strong>CMP</strong>-UG 07/<strong>2009</strong> 4

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