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Program and the Book of Abstracts (PDF) - Mrs-serbia.org.rs

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Tenth Young Researche<strong>rs</strong> Conference – Materials Science <strong>and</strong> Engineering<br />

December 21-23, 2011, Hall 2, SASA, Knez Mihailova 35 & 36, Belgrade, Serbia<br />

X/7<br />

Comparison <strong>of</strong> structural modifications <strong>of</strong> SWCNT thin films<br />

treated by laser <strong>and</strong> <strong>the</strong>rmal irradiation<br />

Dejan P. Kepić 1 , Zoran M. Marković 1 , Ivanka D. Holclajtner Antunović 2 ,<br />

Marko G. Nikolić 1 , Miroslav D. Dramićanin 1 , Biljana M. Todorović Marković 1<br />

1 Vinča Institute <strong>of</strong> Nuclear Sciences, Unive<strong>rs</strong>ity <strong>of</strong> Belgrade, Belgrade, Serbia<br />

2 Faculty <strong>of</strong> Physical Chemistry, Unive<strong>rs</strong>ity <strong>of</strong> Belgrade, Belgrade, Serbia<br />

In present work we compare <strong>the</strong> effects <strong>of</strong> OPO laser <strong>and</strong> heat irradiation upon thin films <strong>of</strong><br />

single wall carbon nanotubes (SWCNTs). Modification <strong>of</strong> carbon nanotube structure was analyzed<br />

both by Raman spectroscopy <strong>and</strong> atomic force microscopy. Results showed that OPO laser<br />

irradiation affects both metallic <strong>and</strong> semiconducting nanotubes, with <strong>the</strong> most ascendant effects at<br />

430 nm wavelength. On <strong>the</strong> o<strong>the</strong>r side, heat irradiation more affects metallic nanotubes, while<br />

semiconducting SWCNTs are more resistant upon it. Decreasing <strong>of</strong> D b<strong>and</strong> in Raman spectra <strong>of</strong><br />

SWCNTs heated in air indicates prominent oxidation <strong>of</strong> carbon impurities, <strong>the</strong>refore this method<br />

can be applied for routine removal <strong>of</strong> those impurities.<br />

43

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