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Program and the Book of Abstracts (PDF) - Mrs-serbia.org.rs

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Tenth Young Researche<strong>rs</strong> Conference – Materials Science <strong>and</strong> Engineering<br />

December 21-23, 2011, Hall 2, SASA, Knez Mihailova 35 & 36, Belgrade, Serbia<br />

V/3<br />

Electrodeposition <strong>of</strong> Zn-Mn alloys with high Mn percentage<br />

from chloride electrolyte<br />

Mihael Bučko, J. B. Bajat, B. Jokić<br />

Faculty <strong>of</strong> Technology <strong>and</strong> Metallurgy, Unive<strong>rs</strong>ity <strong>of</strong> Belgrade, Belgrade, Serbia<br />

The manganese addition can significantly improve <strong>the</strong> corrosion resistance <strong>of</strong> sacrificial Zn<br />

coatings. The best properties are obtained with 30 – 40 mass % Mn in Zn-Mn alloys. The scope <strong>of</strong><br />

this work was to employ chloride electrolyte, in electrodeposition <strong>of</strong> Zn-Mn alloys with optimal Mn<br />

content on one side, <strong>and</strong> satisfactory surface appearance <strong>and</strong> morphology on <strong>the</strong> ano<strong>the</strong>r side. The<br />

influence <strong>of</strong> deposition current density <strong>and</strong> manganese concentration in <strong>the</strong> electrolyte was<br />

investigated. The electrochemical reactions <strong>of</strong> interest were investigated by cyclic voltammetry <strong>and</strong><br />

chronoamperommetry. The samples obtained were characterized by scanning electron microscopy<br />

<strong>and</strong> energy dispe<strong>rs</strong>ive X-ray spectrometry.<br />

V/4<br />

Research on local corrosion processes in low-alloyed pipeline steel<br />

S. Belikov, Ksenia Sergeeva<br />

The Ural Federal Unive<strong>rs</strong>ity named after Fi<strong>rs</strong>t President <strong>of</strong> Russia B.N. Yeltsin,<br />

Ekaterinburg, Russia<br />

The main problem pipeline rupture can be defined as corrosion damage local tube parts.<br />

Therefore it is important to recognize <strong>the</strong> effects <strong>of</strong> structure <strong>and</strong> nonmetallic inclusions on<br />

corrosion resistance <strong>and</strong> particularly on pitting corrosion processes. The alloy used in this study had<br />

a composition <strong>of</strong> 0.15C, 0.50Mn, 0.25Si, 0.52Cr, 0.20Cu, 0.13Ni, 0.05V. Optical metallography,<br />

electron microscopy <strong>and</strong> potentiodynamic polarization methods are widely known as very powerful<br />

methods to research microstructure <strong>and</strong> points <strong>of</strong> pitting formation. It was found <strong>the</strong> basic classes <strong>of</strong><br />

inclusions, <strong>the</strong>ir influence on pitting corrosion <strong>and</strong> dependence corrosion damage from<br />

microstructure.<br />

20

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