Supramolecular Chemistry for Nanosciences
Supramolecular Chemistry for Nanosciences Supramolecular Chemistry for Nanosciences
Bottom-up Fabrication design + synthesis Molecular Components self-assembly, self-organization FUNCTION Shape, size, properties (chemical, photochemical, redox, …) Supramolecular System Integration into device / connexion to macroscopic world... Nanomaterial 04/03/2008 M1-Nanosciences 6
design + synthesis What kind of molecules ? Molecular Components Fe N N O O O O O O N N HS R "Building blocks": - Complexing molecules - Redox units - Photosensitive molecules - Conjugated or saturated molecules - Carbon nanotubes, fullerenes… - Molecules that can be attached onto a surface - … From very simple to very complex… Only limited by imagination and… organic synthesis!!! 04/03/2008 M1-Nanosciences 7
- Page 1 and 2: Supramolecular Chemistry for Nanosc
- Page 3 and 4: Fundamentals of Supramolecular chem
- Page 5: Fundaments of Supramolecular chemis
- Page 9 and 10: Self-assembly of molecular componen
- Page 11 and 12: Self-Assembly onto surfaces R HS Or
- Page 13 and 14: Molecular Switches and Motors Stimu
- Page 15 and 16: Photochemical Molecular switches h
design +<br />
synthesis<br />
What kind of molecules ?<br />
Molecular<br />
Components<br />
Fe<br />
N N<br />
O<br />
O<br />
O<br />
O<br />
O<br />
O<br />
N<br />
N<br />
HS<br />
R<br />
"Building blocks":<br />
- Complexing molecules<br />
- Redox units<br />
- Photosensitive molecules<br />
- Conjugated or saturated molecules<br />
- Carbon nanotubes, fullerenes…<br />
- Molecules that can be attached onto a surface<br />
- …<br />
From very simple to very complex…<br />
Only limited by imagination and… organic synthesis!!!<br />
04/03/2008 M1-<strong>Nanosciences</strong><br />
7
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