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(best examples and good practices) on household organic waste ...

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35<br />

Pyrolysis: thermal degradati<strong>on</strong> of <strong>organic</strong> material in the absence of<br />

oxygen<br />

Gasificati<strong>on</strong>: partial oxidati<strong>on</strong><br />

Incinerati<strong>on</strong>: full oxidative combusti<strong>on</strong>.<br />

3.2. Incinerati<strong>on</strong><br />

The incinerati<strong>on</strong> (combusti<strong>on</strong>) of carb<strong>on</strong>-based materials in an oxygen-rich<br />

envir<strong>on</strong>ment (greater than stoichiometric), typically at temperatures higher<br />

than 850o, produces a <strong>waste</strong> gas composed primarily of carb<strong>on</strong> dioxide (CO2)<br />

<str<strong>on</strong>g>and</str<strong>on</strong>g> water (H2O). Other air emissi<strong>on</strong>s are nitrogen oxides, sulphur dioxide, etc.<br />

The in<strong>organic</strong> c<strong>on</strong>tent of the <strong>waste</strong> is c<strong>on</strong>verted to ash. This is the most<br />

comm<strong>on</strong> <str<strong>on</strong>g>and</str<strong>on</strong>g> well-proven thermal process using a wide variety of fuels. During<br />

the full combusti<strong>on</strong> there is oxygen in excess <str<strong>on</strong>g>and</str<strong>on</strong>g>, c<strong>on</strong>sequently, the<br />

stoichiometric coefficient of oxygen in the combusti<strong>on</strong> reacti<strong>on</strong> is higher than<br />

the value “1”. In theory, if the coefficient is equal to “1”, no carb<strong>on</strong> m<strong>on</strong>oxide<br />

(CO) is produced <str<strong>on</strong>g>and</str<strong>on</strong>g> the average gas temperature is 1,200°C. The reacti<strong>on</strong>s that<br />

are then taking place are:<br />

C + O2 → CO2 + 393.77J (1)<br />

CxHy + (x+ y/4) O2 → xCO2 + y/2 H2O (2)<br />

In the case of lack of oxygen, the reacti<strong>on</strong>s are characterized as incomplete<br />

combusti<strong>on</strong> <strong>on</strong>es, where the produced CO2 reacts with C that has not been<br />

c<strong>on</strong>sumed yet <str<strong>on</strong>g>and</str<strong>on</strong>g> is c<strong>on</strong>verted to CO at higher temperatures.<br />

C + CO2 +172.58J → 2CO (3)<br />

The object of this thermal treatment method is the reducti<strong>on</strong> of the volume of<br />

the treated <strong>waste</strong> with simultaneous utilizati<strong>on</strong> of the c<strong>on</strong>tained energy. The<br />

recovered energy could be used for:<br />

• heating<br />

• Steam producti<strong>on</strong><br />

• Electric energy producti<strong>on</strong><br />

The typical amount of net energy that can be produced per t<strong>on</strong> of domestic<br />

<strong>waste</strong> is about 0.7 MWh of electricity <str<strong>on</strong>g>and</str<strong>on</strong>g> 2 MWh of district heating. Thus,<br />

incinerating about 600 t<strong>on</strong>nes of <strong>waste</strong> per day, about 17 MW of electrical

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