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poster - International Conference of Agricultural Engineering

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y denitrification because <strong>of</strong> lower air temperature during winter. The NO 3 concentration <strong>of</strong><br />

the animal manure origin tended to be always higher in the upper stream, no. 2, than in the<br />

mid stream, no. 9 (Fig. 3A). During flow from the upper stream to the mid stream,<br />

denitrification and/or dilution might attribute to lower NO 3 concentration at no. 9 than that at no.<br />

2.<br />

At no. 9, the NO 3 concentration <strong>of</strong> the chemical fertilizer origin tended to higher than that <strong>of</strong><br />

the animal manure origin whereas at no. 2 that <strong>of</strong> either origin was similar. During summer,<br />

the NO 3 concentration <strong>of</strong> the chemical fertilizer origin tended to be similar at no. 2 and 9.<br />

This might be reflected by the fact that a large amount <strong>of</strong> chemical fertilizer was used from the<br />

upper stream to the mid stream.<br />

NO 3 -N concentration (mg/L)<br />

0.9<br />

0.8<br />

0.7<br />

0.6<br />

0.5<br />

0.4<br />

0.3<br />

0.2<br />

(A)<br />

Animal manure origin<br />

No 2<br />

No 9<br />

NO 3 -N concentration (mg/L)<br />

0.9<br />

0.8<br />

0.7<br />

0.6<br />

0.5<br />

0.4<br />

0.3<br />

0.2<br />

(B)<br />

Chemical fertilizer origin<br />

No 2<br />

No 9<br />

0.1<br />

0.1<br />

0<br />

Dec-03 Jun-04 Dec-04 Jun-05 Dec-05 Jun-06 Dec-06<br />

Measuring date<br />

0<br />

Dec-03 Jun-04 Dec-04 Jun-05 Dec-05 Jun-06 Dec-06<br />

Measuring date<br />

FIGURE 3: Temporal changes in estimated NO 3 concentrations at no. 2 and 9: (A) for<br />

the animal manure origin with Eq. 7, and (B) for the chemical fertilizer origin with Eq. 6<br />

4. Conclusions<br />

The mixing model described by Eqs. 1-3 successfully estimated NO 3 concentration or δ 15 N<br />

values <strong>of</strong> the main stream based on those values obtained at tributaries only when there was<br />

no major denitrification. Discrepancies between modeled and measured values implied that<br />

N <strong>of</strong> either the chemical fertilizer or the animal manure origin merged the main stream. We<br />

examined to distinguish the origin <strong>of</strong> N using the mixing model. Because <strong>of</strong> large temporal<br />

variations in NO 3 concentrations and δ 15 N values, it was quite difficult to specify the NO 3 <strong>of</strong> the<br />

animal manure origin along the river.<br />

To monitor NO 3 concentration originated by animal manure or chemical fertilizer, more<br />

monitoring sites and more frequent sampling periods will be needed. It would be possible to<br />

improve the accuracy <strong>of</strong> the mixing model with the information on the quantities <strong>of</strong> flow in<br />

each sub-watershed.<br />

Acknowledgments<br />

This research was partly supported by the River Environment Management Foundation<br />

(project #1211). We are grateful to Ms. A. Nakano, and Mr. M. Yoshida <strong>of</strong> Iwate <strong>Agricultural</strong><br />

Research Center for their technical assistance.

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