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poster - International Conference of Agricultural Engineering

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R<br />

f<br />

C<br />

t<br />

D<br />

L<br />

2<br />

C<br />

V<br />

2<br />

x<br />

w<br />

C<br />

x<br />

(9)<br />

where<br />

C : concentration <strong>of</strong> the dissolved chemical species (contaminant)<br />

R : retardation factor ( ( K / ) )<br />

f<br />

1<br />

d e<br />

: bulk density <strong>of</strong> the soil, <br />

e<br />

: effective porosity <strong>of</strong> the soil<br />

K : distribution coefficient <strong>of</strong> the soil ( K )<br />

d<br />

oc<br />

foc<br />

K<br />

oc<br />

: organic carbon partition coefficient,<br />

oc<br />

*<br />

D : longitudinal dispersion coefficient ( V D / )<br />

L<br />

<br />

L<br />

: longitudinal dispersivity,<br />

c<br />

w<br />

f<br />

L<br />

V V / R ,<br />

f : fraction <strong>of</strong> organic carbon content<br />

c<br />

e<br />

*<br />

D : diffusion coefficient<br />

V<br />

w<br />

: pore water velocity in the x-direction ( ( K / e<br />

) /( dh / dx)<br />

)<br />

K : hydraulic conductivity, dh / dx : hydraulic gradient<br />

Analytical solution to the governing equation can be written as:<br />

x V t V x x V t <br />

c<br />

c<br />

c<br />

C x t C erfc<br />

<br />

erfc<br />

<br />

( , ) 0.5<br />

<br />

<br />

0<br />

exp<br />

t T<br />

<br />

D t<br />

<br />

D<br />

<br />

, 0 (10)<br />

L L DLt<br />

4 <br />

4 <br />

where and T is a period <strong>of</strong> injection. In this paper, Benzene is considered as contaminant.<br />

Model parameters <strong>of</strong> contaminant Benzene are given in Table 1 and 2.<br />

TABLE 1: The deterministic parameters <strong>of</strong> Benzene<br />

C<br />

0<br />

Chemical<br />

<br />

*<br />

dh / dx D<br />

<br />

L<br />

species (mg/L) (g/cm 3 ) (m/m) (m 2 /s) (%) (%) (m)<br />

Benzene 100 1.8 -0.008 0 1.6 25 5.0<br />

f<br />

oc<br />

<br />

e<br />

Chemical<br />

species<br />

TABLE 2: The uncertainty parameters <strong>of</strong> Benzene<br />

K<br />

Mean (cm/s)<br />

Standard<br />

Mean (cm 3 /g)<br />

deviation<br />

Benzene 0.001 0.0002 58.9 5.0<br />

K<br />

oc<br />

Standard<br />

deviation<br />

4. Results and Discussions<br />

The 50 samples <strong>of</strong> random variables are generated by combining <strong>of</strong> three different<br />

distributions (Normal, Log-Normal and Uniform). If sample size <strong>of</strong> a random variable is small,<br />

it is impossible to estimate the exact PDF. In order to compare results from using probability<br />

distributions by Hermite polynomials and results from using estimated well-known PDF, Chisquare<br />

goodness-<strong>of</strong>-fit test is performed for generated samples <strong>of</strong> K and K . The results<br />

oc

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