A numerical study on the thermal expansion coefficients of fiber

A numerical study on the thermal expansion coefficients of fiber A numerical study on the thermal expansion coefficients of fiber

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25 a Figure 2.10 Chemical structure of aramid fiber (a), knotted Kevlar aramid fiber (b) (Chawla, 1998). b They have been in use for a long time to improve wear resistance of plastic parts. Aramid fiber is superior to other wear resistant additives due to its easier dispersion and minimal effect on mechanical properties of filled materials. Incorporation of fibers increases the impact strength of composites. Further improvements in mechanical properties can be obtained by modification of the surface with OH and COOH groups. The presence of these groups was found to increase adhesion to many polymers. The degree of modification should be carefully controlled because the mechanical strength of the fiber and the performance of its composite may be adversely affected (Wypych, 2000). The high moisture absorption of aramid fibers is their biggest disadvantage. It was reported in the literature that moisture absorption by epoxy laminates degrades their mechanical properties. Hygroscopic fibers provide an easy route for moisture ingress. The addition of aramid fibers to epoxy and phenolic composites slightly improves their flame resistance and decreases smoke formation. This fiber also has a high resistance to shock loading and a low density, these two factors combined promote its use in bulletproof clothing. 2.2.2.6 Whiskers

26 Whiskers are monocrystalline short fibers with extremely high strength. This high strength is because of the absence of crystalline imperfections such as dislocations and having no grain boundaries. Typically whiskers have a diameter of a few µm and a length of a few mm (Figure 2.11). thus their aspect ratio (length/diameter) can vary from 50 to 10000. Whiskers do not have uniform dimensions or properties. This is perhaps their greatest disadvantage. Handling and alignment of whiskers in a matrix to produce a composite is another problem. Figure 2.11 Scanning electron micrograph of SiC whiskers (Chawla, 1998).

26<br />

Whiskers are m<strong>on</strong>ocrystalline short <strong>fiber</strong>s with extremely high strength. This high<br />

strength is because <strong>of</strong> <strong>the</strong> absence <strong>of</strong> crystalline imperfecti<strong>on</strong>s such as dislocati<strong>on</strong>s<br />

and having no grain boundaries. Typically whiskers have a diameter <strong>of</strong> a few µm and<br />

a length <strong>of</strong> a few mm (Figure 2.11). thus <strong>the</strong>ir aspect ratio (length/diameter) can vary<br />

from 50 to 10000. Whiskers do not have uniform dimensi<strong>on</strong>s or properties. This is<br />

perhaps <strong>the</strong>ir greatest disadvantage. Handling and alignment <strong>of</strong> whiskers in a matrix<br />

to produce a composite is ano<strong>the</strong>r problem.<br />

Figure 2.11 Scanning electr<strong>on</strong> micrograph <strong>of</strong> SiC whiskers (Chawla, 1998).

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