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Research Profile - Department of Materials Science and Metallurgy ...

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Harry Bhadeshia FREng FRS FNAE<br />

Tata Steel Pr<strong>of</strong>essor <strong>of</strong> <strong>Metallurgy</strong><br />

BSc City <strong>of</strong> London Polytechnic<br />

PhD University <strong>of</strong> Cambridge<br />

+44 (0) 1223 334301<br />

hkdb@cam.ac.uk<br />

www.msm.cam.ac.uk/phase-trans/index.html<br />

Phase Transformations<br />

There are so many phase changes in iron <strong>and</strong> its alloys<br />

that it is possible to generate a seemingly infinite variety <strong>of</strong><br />

microstructures <strong>and</strong> properties. This complexity makes the<br />

alloys versatile but at the same time difficult to underst<strong>and</strong> <strong>and</strong><br />

design from first principles. Much <strong>of</strong> our energy is devoted to the<br />

development <strong>of</strong> solid-state phase transformation theory, <strong>and</strong> its<br />

experimental validation, in the hope <strong>of</strong> inventing new alloys <strong>and</strong><br />

processes.<br />

Theory <strong>of</strong> transformations<br />

We deal mostly with phase changes which are thermodynamically<br />

<strong>of</strong> first order, i.e. they involve nucleation <strong>and</strong> growth with<br />

well-defined mechanisms <strong>of</strong> transformations <strong>and</strong> particular<br />

constraints to the achievement <strong>of</strong> equilibrium. In fact, most<br />

useful microstructures are far from equilibrium so we build<br />

kinetic theory to determine non-equilibrium states. There are<br />

complications when many different transformations occur<br />

together, complications which have stimulated new theory.<br />

Finally, the microstructure must be related to properties which are<br />

appreciated by technologists.<br />

Mathematical models<br />

We express the theory <strong>and</strong> empirical observations in the form<br />

<strong>of</strong> computer models which can be used to greatly reduce the<br />

vast number <strong>of</strong> parameters that have to be controlled during the<br />

creation <strong>of</strong> new alloys <strong>and</strong> processes. We also produce courses,<br />

books <strong>and</strong> algorithms in addition to research papers to help<br />

spread the word about this thriving science <strong>of</strong> materials.<br />

H Matsuda & HKDH Bhadeshia, “Kinetics <strong>of</strong> the bainite transformation”<br />

Proc. Roy. Soc. (London) A 460, 1710–1722 (2004).<br />

HKDH Bhadeshia, “Large chunks <strong>of</strong> very strong steel” Mater. Sci. Technol.<br />

21, 1293–1302 (2005).<br />

S Yamasaki & HKDH Bhadeshia, “M 4<br />

C 3<br />

precipitation in Fe-C-Mo-V steels<br />

<strong>and</strong> relationship to hydrogen trapping” Proc. Roy. Soc. (London) A 462,<br />

2315–2330 (2006).<br />

S Chatterjee, HS Wang, JR Yang & HKDH Bhadeshia, “Mechanical<br />

stabilisation <strong>of</strong> austenite”, Mater. Sci. Technol. 22, 645–649 (2006).<br />

Bulk nanostructured steel with a scale finer than carbon<br />

nanotubes, now produced in tonnage quantities<br />

<strong>Research</strong> <strong>Pr<strong>of</strong>ile</strong> 7

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