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Research Profile - Department of Materials Science and Metallurgy ...

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Caterina Ducati<br />

Royal Society University <strong>Research</strong> Fellow<br />

Laurea Università Statale di Milano<br />

PhD University <strong>of</strong> Cambridge<br />

+44 (0) 1223 334566<br />

cd251@cam.ac.uk<br />

www-hrem.msm.cam.ac.uk/people/ducati<br />

High-Resolution Electron Microscopy <strong>of</strong> Nanomaterials<br />

My main research interest is nanomaterials, <strong>and</strong> in particular the<br />

relationships between their morphology, their crystallographic<br />

phase <strong>and</strong> their electronic properties, for applications in<br />

photocatalysis <strong>and</strong> electronics. Since the beginning <strong>of</strong> my PhD, I<br />

have been working on the characterization <strong>of</strong> carbon nanotubes<br />

<strong>and</strong> semiconductor nanowires, aiming for a better underst<strong>and</strong>ing<br />

<strong>of</strong> their growth mechanisms. As a member <strong>of</strong> the High-Resolution<br />

Electron Microscopy Group, I have access to a range <strong>of</strong><br />

advanced tools for the analysis <strong>of</strong> materials at the nanoscale.<br />

Nanostructured metal oxides<br />

In collaboration with a group in Milan, we are studying<br />

nanostructured transition-metal (Ti, Pd, W, Sn) oxides produced<br />

by supersonic-beam deposition. We are interested in determining<br />

their phase equilibria <strong>and</strong> the evolution <strong>of</strong> their crystal structure<br />

during thermal treatment, for application in resistive sensors for<br />

toxic gases.<br />

Carbon nanotube <strong>and</strong> inorganic nanowire growth<br />

High-aspect-ratio nanostructures such as nanotubes, nanowires<br />

<strong>and</strong> nanorods have attracted a keen interest, both in fundamental<br />

research <strong>and</strong> for advanced applications. Although the synthesis<br />

<strong>of</strong> these nanostructures has been achieved through many<br />

different strategies, the exact mechanisms that lead to their<br />

formation are not clear <strong>and</strong> need to be elucidated to control the<br />

properties <strong>and</strong> reliability <strong>of</strong> these nanoscale “building blocks”.<br />

We are investigating the growth <strong>of</strong> nanotubes <strong>and</strong> nanowires,<br />

focusing on the rôle <strong>of</strong> the metal catalyst that assists the<br />

synthesis.<br />

C Ducati, K Koziol, TJV Yates, S Friedrichs, MS Shaffer, PA Midgley & AH<br />

Windle, “Crystallographic order in multiwall carbon nanotubes synthesized<br />

in the presence <strong>of</strong> nitrogen” Small 2, 774–784 (2006).<br />

C Ducati, E Barborini, G Bongiorno, S Vinati, P Milani & PA Midgley,<br />

“Titanium fullerenoid oxides” Appl. Phys. Lett. 87, 201906 (2005).<br />

C Ducati, DH Dawson, JR Saffell & PA Midgley, “Ruthenium-coated<br />

ruthenium oxide nanorods” Appl. Phys. Lett. 85, 5385–5387 (2004).<br />

C Ducati, I Alex<strong>and</strong>rou, M Chhowalla, J Robertson & GAJ Amaratunga,<br />

“The role <strong>of</strong> the catalytic particle in the growth <strong>of</strong> carbon nanotubes<br />

by plasma enhanced chemical vapor deposition” J. Appl. Phys. 95,<br />

6387–6391 (2004).<br />

High-resolution TEM image <strong>of</strong> a crystalline ruthenium oxide<br />

nanorod synthesized in solution<br />

<strong>Research</strong> <strong>Pr<strong>of</strong>ile</strong> 17

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