sd15016 - fermitac kleber GB

DR 

Safety Data Sheet 

according to 1907/2006/EC, Article 31 

Page 1/7 

Printing date 06.03.2009 Revision: 05.03.2009 

1 Identification of substance 

· Product details: 

· Trade name: Fermitac Kleber 

· Application of the substance / the preparation Adhesives 

· Manufacturer/Supplier: 

Fermit GmbH 

Zur Heide 4, 

D- 53560 Vettelschoß 

www.fermit.de 

· Informing department: 

Tel.: +49 (0) 2645-2207 

Fax: +49 (0) 2645-3113 

Email: info@fermit.de 

· Emergency information: Tel.: +49 (0) 2645-2207 

2 Hazards identification 

· Hazard designation: 

Xi Irritant 

F Highly flammable 

· Information pertaining to particular dangers for man and environment 

The product has to be labelled due to the calculation procedure of the "General Classification 

guideline for preparations of the EU" in the latest valid version. 

Has a narcotizing effect. 

R 11 Highly flammable. 

R 36 Irritating to eyes. 

R 67 Vapours may cause drowsiness and dizziness. 

· Classification system 

The classification is in line with current EC lists. It is expanded, however, by information from 

technical literature and by information furnished by supplier companies. 

3 Composition/information on ingredients 

· Chemical characterization 

· Description: Mix of the substances listed below including additives not requiring identification. 

· Dangerous components: 

CAS: 78-93-3 

EINECS: 201-159-0 

butanone Xi, F; R 11-36-66-67 50-100% 

CAS: 108-94-1 

EINECS: 203-631-1 

cyclohexanone Xn; R 10-20 10-25% 

CAS: 1330-20-7 

EINECS: 215-535-7 

xylene, mixed isomers, pure Xn, Xi; R 10-20/21-38 2.5-10% 

· Additional information For the wording of the listed risk phrases refer to section 16. 

4 First aid measures 

· After inhalation 

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if 

symptoms persist. 

(Contd. on page 2) 

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Trade name: Fermitac Kleber 

(Contd. from page 1) 

In case of unconsciousness bring patient into stable side position for transport. 

· After skin contact 

Remove contaminated clothing. 

Wash intensively with water and soap. Use protective skin ointment. 

· After eye contact 

Keep eye lids open and rinse them amply with clean running water for at least 15 minutes. 

Seek medical treatment. 

· After swallowing Avoid vomiting. Don't give anything to drink. Immediately consult physician. 

5 Fire fighting measures 

· Suitable extinguishing agents CO2, sand, extinguishing powder. Do not use water. 

· For safety reasons unsuitable extinguishing agents Water with a full water jet. 

· Protective equipment: Wear self-contained breathing apparatus. 

6 Accidental release measures 

· Person-related safety precautions: 

Wear protective equipment. Keep unprotected persons away. 

Keep away from sources of ignition and care for sufficient vventilation due to the fraction of organic 

solvents . 

Do not inhale vapours. 

· Measures for environmental protection: 

Do not allow to enter drainage system, surface or ground water. 

Prevent material from reaching sewage system, holes and cellars. 

Inform respective authorities in case product reaches water or sewage system. 

· Measures for cleaning/collecting: 

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders). 

Dispose of contaminated material as waste according to item 13. 

Ensure adequate ventilation. 

Do not flush with water or aqueous cleansing agents 

7 Handling and storage 

· Handling 

· Information for safe handling: 

Ensure good ventilation/exhaustion at the workplace. 

Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air). 

Prevent formation of aerosols. 

· Information about protection against explosions and fires: 

Keep ignition sources away - Do not smoke. 

Protect against electrostatic charges. 

Use explosion-proof apparatus / fittings and spark-proof tools. 

Vapours are heavier than air and may travel long distances along ground, ignite and flash back to 

source. 

· Storage 

· Requirements to be met by storerooms and containers: 

Store cool and dry in well sealealed containers. 

Ensure sufficient ventilation. 

· Information about storage in one common storage facility: 

Keep away from food, drink and animal feeding stuffs. 


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· Further information about storage conditions: 

Store in cool, dry conditions in well sealed containers. 

8 Exposure controls and personal protection 


· Components with limit values that require monitoring at the workplace: 

78-93-3 butanone 

WEL Short-term value: 899 mg/m³, 300 ppm 

Long-term value: 600 mg/m³, 200 ppm 

Sk 

108-94-1 cyclohexanone 

WEL Short-term value: 20 ppm 

Long-term value: 10 ppm 

Sk 

1330-20-7 xylene, mixed isomers, pure 

WEL Short-term value: 441 mg/m³, 100 ppm 

Long-term value: 220 mg/m³, 50 ppm 

Sk; BMGV 

· Additional information: The lists that were valid during the compilation were used as basis. 

· Personal protective equipment 

· General protective and hygienic measures 

Keep away from foodstuffs, beverages and food. 

Take off immediately all contaminated clothing 

Wash hands during breaks and at the end of the work. 

Avoid contact with the eyes and skin. 

· Breathing equipment: 

In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or 

longer exposure use breathing apparatus that is independent of circulating air. 

· Protection of hands: 

The glove material has to be impermeable and resistant to the product/ the substance/ the 

preparation. 

Due to missing tests no recommendation to the glove material can be given for the product/ the 

preparation/ the chemical mixture. 

Selection of the glove material on consideration of the penetration times, rates of diffusion and the 

degradation 

There is no suitable material for protective gloves for this substance. The recommended protective 

glove has to be replaced often 

· Material of gloves 

The selection of the suitable gloves does not only depend on the material, but also on further marks 

of quality and varies from manufacturer to manufacturer. As the product is a preparation of several 

substances, the resistance of the glove material can not be calculated in advance and has therefore 

to be checked prior to the application. 

· Penetration time of glove material 

The exact break trough time has to be found out by the manufacturer of the protective gloves and 

has to be observed. 

Value for the permeation: Level ≥ 2 

· For the permanent contact gloves made of the following materials are suitable: 

Butyl rubber, BR 

· Eye protection: Tightly sealed safety glasses. 

GB 

(Contd. on page 4)

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9 Physical and chemical properties 

· General Information 

Form: Pasty 

Colour: According to product specification 

Odour: Characteristic 

· Change in condition 

Melting point/Melting range: Not determined 

Boiling point/Boiling range: 79°C 

· Flash point: -4°C 

· Ignition temperature: 420°C 

· Self-inflammability: Product is not selfigniting. 


· Danger of explosion: Product is not explosive. However, formation of explosive air/ 

steam mixtures is possible. 

· Critical values for explosion: 

Lower: 1.3 Vol % 

Upper: 11.5 Vol % 

· Vapour pressure at 20°C: 110-175 kPa 

· Density at 20°C

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12 Ecological information 

· General notes: 

Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water. 

Do not allow product to reach ground water, water bodies or sewage system. 

Danger to drinking water if even small quantities leak into soil. 

13 Disposal considerations 


· Product: 

· Recommendation 

Must not be disposed of together with household garbage. Do not allow product to reach sewage 

system. 

The waste code numbers mentioned are recommendations based on the probable use of the 

product. 

· European waste catalogue 

08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) 

OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, 

SEALANTS AND PRINTING INKS 

08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products) 

08 04 09 waste adhesives and sealants containing organic solvents or other dangerous 

substances 

· Uncleaned packagings: 

· Recommendation: Disposal must be made according to official regulations. 

14 Transport information 

· Land transport ADR/RID (cross-border) 

· ADR/RID-GGVSE Class: 3 (F1) Flammable liquids. 

· Kemler Number: 33 

· UN-Number: 1133 

· Packaging group: III 

· Label 3 

· Designation of goods: 1133 ADHESIVES, special provision 640H 

· Maritime transport IMDG: 

· IMDG Class: 3 

· UN Number: 1133 

· Label 3 


· EMS Number: F-E,S-D 

· Marine pollutant: No 


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· Correct technical name: ADHESIVES 

· Air transport ICAO-TI and IATA-DGR: 

· ICAO/IATA Class: 3 

· UN/ID Number: 1133 

· Label 3 


· Correct technical name: ADHESIVES 

15 Regulatory information 


· Designation according to EC guidelines: 

The product has been classified and labelled in accordance with EC Directives / Ordinance on 

Hazardous Materials (GefStoffV) 

· Code letter and hazard designation of product: 

Xi Irritant 

F Highly flammable 

· Risk phrases: 

11 Highly flammable. 

36 Irritating to eyes. 

67 Vapours may cause drowsiness and dizziness. 

· Safety phrases: 

2 Keep out of the reach of children. 

9 Keep container in a well-ventilated place. 

16 Keep away from sources of ignition - No smoking. 

26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 

33 Take precautionary measures against static discharges. 

46 If swallowed, seek medical advice immediately and show this container or label. 

· National regulations 

· Technical instructions (air): 

Class Share in % 

NK 50-100 

· Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. 

16 Other information 

These data are based on our present knowledge. However, they shall not constitute a guarantee for 

any specific product features and shall not establish a legally valid contractual relationship. 

· Relevant R-phrases 

10 Flammable. 

11 Highly flammable. 

20 Harmful by inhalation. 

20/21 Harmful by inhalation and in contact with skin. 

36 Irritating to eyes. 

38 Irritating to skin. 


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66 Repeated exposure may cause skin dryness or cracking. 

67 Vapours may cause drowsiness and dizziness. 

· Department issuing data specification sheet: 

This Material Safety Data Sheet has been drawn up in cooperation with: 

DEKRA Umwelt GmbH, Hanomagstr. 12, D-30449 Hannover, 

Tel.: +49.511.42079-311. 


GB

sd15016 - fermitac kleber GB

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