- Page 1 and 2: Dearomatising Addition of Organolit
- Page 3 and 4: 2.3 Synthetic Scope 64 2.3.1 Organo
- Page 5 and 6: Abstract Dearomatising Addition of
- Page 7 and 8: The Author The Author graduated fro
- Page 9 and 10: Abbreviations & Conventions Ac acet
- Page 11: RDS rate determining step R f RC rt
- Page 15 and 16: 1.2 - Electrophilic dearomatisation
- Page 17 and 18: 1.2 - Electrophilic dearomatisation
- Page 19 and 20: 1.3 - Nucleophilic dearomatisation
- Page 21 and 22: 1.3 - Nucleophilic dearomatisation
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- Page 41 and 42: 1.4 - Metal complexation has a very
- Page 43 and 44: 1.4 - Metal complexation R R R O N
- Page 45 and 46: 1.4 - Metal complexation LiAlH 4 R
- Page 47 and 48: 1.4 - Metal complexation Ph O O N O
- Page 49 and 50: 1.5 Summary of Methods In their rec
- Page 51 and 52: 2.1 - A new reaction Ph OMe No DMPU
- Page 53 and 54: 2.1 - A new reaction anticipated th
- Page 55 and 56: 2.1 - A new reaction The next secti
- Page 57 and 58: 2.2 - Reaction optimisation % Compo
- Page 59 and 60: 2.2 - Reaction optimisation 2.2.2 D
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2.3 - Synthetic scope 2.3 Synthetic
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2.3 - Synthetic scope generally fol
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2.3 - Synthetic scope their electro
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2.3 - Synthetic scope The presence
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2.3 - Synthetic scope Ph O Ph NLi R
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2.4 - Mechanistic discussion chelat
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2.4 - Mechanistic discussion orbita
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2.4 - Mechanistic discussion Whilst
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2.4 - Mechanistic discussion centre
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2.4 - Mechanistic discussion Subjec
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2.4 - Mechanistic discussion The te
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2.4 - Mechanistic discussion Yamata
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2.4 - Mechanistic discussion Gringa
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2.4 - Mechanistic discussion phenyl
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2.5 Summary & Future Work It is uns
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 3 - Oxazoline synthesis & r
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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Chapter 4 - Synthesis of carbasugar
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References References for Chapters
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References (73) Betson, M. S.; Clay
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References (139) Yoon, Y.-J.; Joo,
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References (202) Meyers, A. I.; Tem
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Experimental section Chapter 5 - Ex
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Experimental section was triturated
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Experimental for chapter 2 5.2 Expe
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Experimental for chapter 2 Synthesi
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Experimental for chapter 2 Synthesi
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Experimental for chapter 2 103c R f
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Experimental for chapter 2 102j R f
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Experimental for chapter 2 105 R f
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Experimental for chapter 2 5.55 (dd
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Experimental for chapter 3.1 5.3 Ex
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Experimental for chapter 3.1 ν max
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Experimental for chapter 3.1 CHOH),
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Experimental for chapter 3.1 over c
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Experimental for chapter 3.1 R f :
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Experimental for chapter 3.1 Synthe
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Experimental for chapter 3.1 101b d
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Experimental for chapter 3.1 (d, 1H
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Experimental for chapter 3.1 R f :
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Experimental for chapter 3.1 101j R
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Experimental for chapter 3.1 Synthe
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Experimental for chapter 3.1 R f :
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Experimental for chapter 3.2 5.4 Ex
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Experimental for chapter 3.2 324.19
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Experimental for chapter 3.2 Synthe
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Experimental for chapter 3.2 5.56 (
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Experimental for chapter 3.2 Synthe
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Experimental for chapter 3.2 10.0,
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Experimental for chapter 4.1 5.5 Ex
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Experimental for chapter 4.1 Ph), 7
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Experimental for chapter 4.1 Synthe
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Experimental for chapter 4.1 Synthe
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Experimental for chapter 4.1 Synthe
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Experimental for chapter 4.1 2.30 (
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Experimental for chapter 4.1 Synthe
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Experimental for chapter 4.1 ¹³C-
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Experimental for chapter 4.2 5.6 Ex
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Experimental for chapter 4.2 Synthe
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Experimental for chapter 4.2 Synthe
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Experimental for chapter 4.2 Synthe
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Experimental for chapter 4.2 (d, 3H
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Experimental for chapter 4.2 Data f
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Appendix A: Selected NMR Spectra 27
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277
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279
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281
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283
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Appendix B - Crystallographic Infor
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_audit_creation_method SHELXL-97 _c
- Page 288 and 289:
_refine_ls_shift/su_mean 0.000 loop
- Page 290 and 291:
C7 0.0311(13) 0.0244(13) 0.0347(13)
- Page 292 and 293:
O1 C4 C5 111.68(17) . . ? C6 C5 C4
- Page 294 and 295:
C21 C22 C23 C24 0.4(3) . . . . ? C2
- Page 296 and 297:
The structure was solved by the dir
- Page 298 and 299:
_refine_ls_extinction_coef ? _refin
- Page 300 and 301:
_atom_site_aniso_U_12 O1 0.0253(7)
- Page 302 and 303:
C21 C3 H3 109.7 . . ? C2 C3 H3 109.
- Page 304 and 305:
C17 C18 C19 C20 -0.8(3) . . . . ? C
- Page 306 and 307:
Final R indices [I>2sigma(I)] R1 =
- Page 308 and 309:
_diffrn_reflns_limit_k_min -11 _dif
- Page 310 and 311:
H8 H 0.9757 -0.1848 0.2244 0.024 Ui
- Page 312 and 313:
C43 C 0.4196(12) 0.2863(7) 0.6783(6
- Page 314 and 315:
C42 0.072(7) 0.028(5) 0.057(6) 0.01
- Page 316 and 317:
C29 C35 1.548(8) . ? C29 C30 1.554(
- Page 318 and 319:
C20 C21 H21 119.7 . . ? C21 C22 C23
- Page 320 and 321:
C1 C4 C5 C11 64.4(7) . . . . ? C11
- Page 322 and 323:
d. Compound 278 HO OH HO OH 278 OH
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_exptl_crystal_description plate _e
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_refine_ls_restrained_S_all 1.154 _
- Page 328 and 329:
C18 C 0.4218(4) 0.5303(6) 0.6578(3)
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loop_ _geom_bond_atom_site_label_1
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C2 C9 H9 106.9 . . ? C9 C10 H10A 10
- Page 334:
O9 C16 C17 C12 -179.9(4) . . . . ?