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Prediction of batch heat transfer coefficients for pseudoplastic fluids ...

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.37<br />

2: a in in <strong>heat</strong> cQ@tent <strong>of</strong> the vessel.<br />

A second method <strong>of</strong> calculating the qtta....'1ti ty <strong>of</strong> <strong>heat</strong><br />

<strong>transfer</strong>I'ed is to calculate the change in enthalpy <strong>of</strong> the<br />

<strong>batch</strong>.<br />

There are three corrections 1lrhich must be taken<br />

into account ..<br />

1. The <strong>heat</strong> losses from the sUT'face <strong>of</strong> the<br />

fluid.<br />

2. The mechanical energy input from the ar;itator.<br />

3. The gain in <strong>heat</strong> content <strong>of</strong> the impeller and<br />

shaft.<br />

There is usually at least 20 percent vapor space during a<br />

<strong>heat</strong> <strong>transfer</strong> experiment and the vessel is covered Hith an<br />

insulated lid. If the temperature <strong>of</strong> the <strong>batch</strong> does not<br />

approach the boilinl; point the <strong>heat</strong> losses from the surface<br />

are negligible. The mechanical energy input to the system can<br />

be calculated if DOHer measurements are made (they llsually<br />

are). ROHever, the mechanical energy input is significant<br />

only if very viscous <strong>fluids</strong> are being aGitated.<br />

The gain<br />

in <strong>heat</strong> content <strong>of</strong> the impeller 8illd shaft is also neglicible<br />

because <strong>of</strong> their small ilJeic;ht and <strong>heat</strong> capacity in<br />

comparison v'Ii th that <strong>of</strong> the <strong>batch</strong> fluid.<br />

The temperature<br />

change <strong>of</strong> the <strong>batch</strong> can be chosen large enough so that<br />

errors in measurinrz it are small.<br />

It is this author's<br />

opinion that this second method is the most accurate means<br />

<strong>of</strong> determining the <strong>heat</strong> <strong>transfer</strong> rate.

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