Extraction Technologies for Medicinal and Aromatic ... - Capacity4Dev
Extraction Technologies for Medicinal and Aromatic ... - Capacity4Dev Extraction Technologies for Medicinal and Aromatic ... - Capacity4Dev
1 AN OVERVIEW OF EXTRACTION TECHNIQUES FOR MEDICINAL AND AROMATIC PLANTS confectionery food products, soft drinks, distilled alcoholic beverages (hard drinks) and insecticides. The world production and consumption of essential oils and perfumes are increasing very fast. Production technology is an essential element to improve the overall yield and quality of essential oil. The traditional technologies pertaining to essential oil processing are of great significance and are still being used in many parts of the globe. Water distillation, water and steam distillation, steam distillation, cohobation, maceration and enfleurage are the most traditional and commonly used methods. Maceration is adaptable when oil yield from distillation is poor. Distillation methods are good for powdered almonds, rose petals and rose blossoms, whereas solvent extraction is suitable for expensive, delicate and thermally unstable materials like jasmine, tuberose, and hyacinth. Water distillation is the most favored method of production of citronella oil from plant material. 1.3.5.1 Sources of Natural Essential Oils Plant organs containing natural essential oils are illustrated in Figure 3. Essential oils are generally derived from one or more plant parts, such as fl owers (e.g. rose, jasmine, carnation, clove, mimosa, rosemary, lavander), leaves (e.g. mint, Ocimum spp., lemongrass, jamrosa), leaves and stems (e.g. geranium, patchouli, petitgrain, verbena, cinnamon), bark (e.g. cinnamon, cassia, canella), wood (e.g. cedar, sandal, pine), roots (e.g. angelica, sassafras, vetiver, saussurea, valerian), seeds (e.g fennel, coriander, caraway, dill, nutmeg), fruits (bergamot, orange, lemon, juniper), rhizomes (e.g. ginger, calamus, curcuma, orris) and gums or oleoresin exudations (e.g. balsam of Peru, balsam of Tolu, storax, myrrh, benzoin). Specialized plant structures that produce and store essential oils are shown in Figure 4. Depending upon the plant family, essential oils may occur in specialized secretary structures such as glandular hairs (Labiatae, Verbenaceace, Geraniaceae), modifi ed parenchymal cells (Piperaceae), resin canals (conifers), oil tubes called vittae (Umbelliferae), lysigenous cavities (Rutaceae), schizogenous passages (Myrtaceae, Graminae, Compositae) or gum canals (Cistacae, Burseraceae). It is well known that when a geranium leaf is lightly touched, an odor is emitted because the long stalked oil glands are fragile. Similarly, the application of slight pressure on a peppermint leaf will rupture the oil gland and release oil. In contrast, pine needles and eucalyptus leaves do not release their oils until the epidermis of the leaf is broken. Hence, the types of structures in which oil is contained differ depending on the plant type and are plant-family specifi c. Unfortunately, not enough is known even today about these oil secretary structures to carefully categorize them. From the practical standpoint, they can be categorized into superfi cial and subcutaneous oils. Based on the currently available information, it may be inferred that oils of the Labiatae, Verbenaceae and Geraniaceae families are the only superfi cial oils known; consequently, the others are considered subcutaneous oils. 36
EXTRACTION TECHNOLOGIES FOR MEDICINAL AND AROMATIC PLANTS During handling, some flowers continue to produce aroma while other quickly loose their odor. Flowers collected at different times may also give different perfumery values. Regarding the rose, half-open flowers with plump anthers give higher oil yield than fully opened flowers with shrivelled anthers. Humidity, wind, rain and surface temperature also affect the oil yield considerably. Harvesting schedule affects both quantity and quality of the oil. 1.3.5.2 Essential Oil Constituents Major constituents of essential oils are shown in Figure 5, from which it is clear that most essential oils consist of hydrocarbons, esters, terpenes, lactones, phenols, aldehydes, acids, alcohols, ketones, and esters. Among these, the oxygenated compounds (alcohols, esters, aldehydes, ketones, lactones, phenols) are the principal odor source. They are more stable against oxidizing and resinifying influences than other constituents. On the other hand, unsaturated constituents like monoterpenes and sesquiterpenes have the tendency to oxidize or resinify in the presence of air and light. The knowledge of individual constituents and their physical characteristics, such as boiling point, thermal stability and vapor-pressure-temperature relationship, is of paramount importance in technology development of oxygenated compounds. 1.3.5.3 Methods of Producing Essential Oils Methods for producing essential oils from plant materials are summarized in Figure 6. Regarding hydrodistillation, the essential oils industry has developed terminology to distinguish three types: water distillation; water and steam distillation; and direct steam distillation. Originally introduced by Von Rechenberg, these terms have become established in the essential oil industry. All three methods are subject to the same theoretical considerations which deal with distillation of two-phase systems. The differences lie mainly in the methods of handling the material. Some volatile oils cannot be distilled without decomposition and thus are usually obtained by expression (lemon oil, orange oil) or by other mechanical means. In certain countries, the general method for obtaining citrus oil involves puncturing the oil glands by rolling the fruit over a trough lined with sharp projections that are long enough to penetrate the epidermis and pierce the oil glands located within outer portion of the peel (ecuelle method). A pressing action on the fruit removes the oil from the glands, and a fi ne spray of water washes the oil from the mashed peel while the juice is extracted through a central tube that cores the fruit. The resulting oil-water emulsion is separated by centrifugation. A variation of this process is to remove the peel from the fruit before the oil is extracted. Often, the volatile oil content of fresh plant parts (flower petals) is so small that oil removal is not commercially feasible by the aforementioned 37
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1 AN OVERVIEW OF EXTRACTION TECHNIQUES FOR MEDICINAL AND AROMATIC PLANTS<br />
confectionery food products, soft drinks, distilled alcoholic beverages (hard<br />
drinks) <strong>and</strong> insecticides. The world production <strong>and</strong> consumption of essential<br />
oils <strong>and</strong> perfumes are increasing very fast. Production technology is an essential<br />
element to improve the overall yield <strong>and</strong> quality of essential oil. The<br />
traditional technologies pertaining to essential oil processing are of great significance<br />
<strong>and</strong> are still being used in many parts of the globe. Water distillation,<br />
water <strong>and</strong> steam distillation, steam distillation, cohobation, maceration <strong>and</strong><br />
enfleurage are the most traditional <strong>and</strong> commonly used methods. Maceration<br />
is adaptable when oil yield from distillation is poor. Distillation methods are<br />
good <strong>for</strong> powdered almonds, rose petals <strong>and</strong> rose blossoms, whereas solvent<br />
extraction is suitable <strong>for</strong> expensive, delicate <strong>and</strong> thermally unstable materials<br />
like jasmine, tuberose, <strong>and</strong> hyacinth. Water distillation is the most favored<br />
method of production of citronella oil from plant material.<br />
1.3.5.1 Sources of Natural Essential Oils<br />
Plant organs containing natural essential oils are illustrated in<br />
Figure 3. Essential oils are generally derived from one or more plant parts,<br />
such as fl owers (e.g. rose, jasmine, carnation, clove, mimosa, rosemary,<br />
lav<strong>and</strong>er), leaves (e.g. mint, Ocimum spp., lemongrass, jamrosa), leaves <strong>and</strong><br />
stems (e.g. geranium, patchouli, petitgrain, verbena, cinnamon), bark (e.g.<br />
cinnamon, cassia, canella), wood (e.g. cedar, s<strong>and</strong>al, pine), roots (e.g. angelica,<br />
sassafras, vetiver, saussurea, valerian), seeds (e.g fennel, cori<strong>and</strong>er,<br />
caraway, dill, nutmeg), fruits (bergamot, orange, lemon, juniper), rhizomes<br />
(e.g. ginger, calamus, curcuma, orris) <strong>and</strong> gums or oleoresin exudations<br />
(e.g. balsam of Peru, balsam of Tolu, storax, myrrh, benzoin).<br />
Specialized plant structures that produce <strong>and</strong> store essential<br />
oils are shown in Figure 4. Depending upon the plant family, essential<br />
oils may occur in specialized secretary structures such as gl<strong>and</strong>ular hairs<br />
(Labiatae, Verbenaceace, Geraniaceae), modifi ed parenchymal cells (Piperaceae),<br />
resin canals (conifers), oil tubes called vittae (Umbelliferae), lysigenous<br />
cavities (Rutaceae), schizogenous passages (Myrtaceae, Graminae,<br />
Compositae) or gum canals (Cistacae, Burseraceae). It is well known that<br />
when a geranium leaf is lightly touched, an odor is emitted because the long<br />
stalked oil gl<strong>and</strong>s are fragile. Similarly, the application of slight pressure<br />
on a peppermint leaf will rupture the oil gl<strong>and</strong> <strong>and</strong> release oil. In contrast,<br />
pine needles <strong>and</strong> eucalyptus leaves do not release their oils until the epidermis<br />
of the leaf is broken. Hence, the types of structures in which oil is<br />
contained differ depending on the plant type <strong>and</strong> are plant-family specifi c.<br />
Un<strong>for</strong>tunately, not enough is known even today about these oil secretary<br />
structures to carefully categorize them. From the practical st<strong>and</strong>point, they<br />
can be categorized into superfi cial <strong>and</strong> subcutaneous oils. Based on the<br />
currently available in<strong>for</strong>mation, it may be inferred that oils of the Labiatae,<br />
Verbenaceae <strong>and</strong> Geraniaceae families are the only superfi cial oils known;<br />
consequently, the others are considered subcutaneous oils.<br />
36