Physical Chemistry 3: — Chemical Kinetics — - Christian-Albrechts ...
Physical Chemistry 3: — Chemical Kinetics — - Christian-Albrechts ... Physical Chemistry 3: — Chemical Kinetics — - Christian-Albrechts ...
8.2 Lindemann mechanism 181 I Deficiencies of the Lindemann model: I Figure 8.8: • Activation energies: In particular: 0 ∞ (8.28) ∞ ≈ 0 (8.29) 0 ≈ 0 − ( − 15) (8.30)
8.3 Generalized Lindemann-Hinshelwood mechanism 182 8.3 Generalized Lindemann-Hinshelwood mechanism 8.3.1 Master equation I Figure 8.9: Strong collision model. I Figure 8.10: Generalized Lindemann-Hinshelwood weak collision model.
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8.2 Lindemann mechanism 181<br />
I<br />
Deficiencies of the Lindemann model:<br />
I Figure 8.8:<br />
• Activation energies:<br />
In particular:<br />
0 ∞ (8.28)<br />
∞ ≈ 0 (8.29)<br />
0 ≈ 0 − ( − 15) (8.30)
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