Physical Chemistry 3: — Chemical Kinetics — - Christian-Albrechts ...
Physical Chemistry 3: — Chemical Kinetics — - Christian-Albrechts ... Physical Chemistry 3: — Chemical Kinetics — - Christian-Albrechts ...
4.7 NMR spectroscopy 87 4.7 NMR spectroscopy • line coalescence • good for interconversion of two conformers (“isomerization”) I Figure 4.15:
4.8 Relaxation methods 88 4.8 Relaxation methods • application to fast reactions in the liquid phase (Eigen) • -jump, -jump, -jump, . . . : (1) ⇒ displacement from equilibrium (2) ⇒ measurements of relaxation into new equilibrium state by transient absorption spectroscopy, conductivity, . . .
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4.8 Relaxation methods 88<br />
4.8 Relaxation methods<br />
• application to fast reactions in the liquid phase (Eigen)<br />
• -jump, -jump, -jump, . . . :<br />
(1) ⇒ displacement from equilibrium<br />
(2) ⇒ measurements of relaxation into new equilibrium state by transient absorption<br />
spectroscopy, conductivity, . . .
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