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LIMITATIONS OF GAUGE INVARIANCE

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LENGTH <strong>GAUGE</strong><br />

There is a gauge transformation that replaces the vector potential for<br />

the applied field by the scalar potential for quasistatic electric field.<br />

(Maria Göppert-Mayer, 1931)<br />

1 ˆ<br />

2<br />

H p V r<br />

r E t<br />

2<br />

This is a convenient gauge because both the Coulomb and the external<br />

fields are represented by scalar potentials that can simply be added.<br />

It is the foundation for the tunneling theory of strong-field ionization.<br />

(Keldysh, Nikishov & Ritus, PPT, ADK)<br />

Starting with a 1952 paper by Lamb, the length gauge has been<br />

regarded by many people in the AMO community as the “correct gauge”<br />

for the expression of atomic and molecular problems.<br />

22

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