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Vladimir Kozhukharov , NCP-NMP (7fp)

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UCTM<br />

<strong>Vladimir</strong> <strong>Kozhukharov</strong> , <strong>NCP</strong>-<strong>NMP</strong> (<strong>7fp</strong>)<br />

UCTM , LAMAR , 22-24.IV.2009, Ljubljana, Slovenia


OUTLINE<br />

VISION & STRATEGY<br />

INSTITUTIONS INVOLVED<br />

BULGARIA & <strong>NMP</strong> - EC<br />

LAMAR<br />

MULTIPROTECT - project<br />

Acknowledgements<br />

< http://cordis.europa.eu/en/home.htm<br />

< http://www.minedu.government.bg/nsfb/INTER/CME95_12.html<br />

< http://www.government.bg


VISION & STRATEGY<br />

KNOWLEDGE BASED ECONOMY- 2003<br />

EUROPEAN INTEGRATION OF<br />

THE SOCIETY AND INDUSTRY 2007<br />

HIGH IMPACT IS ESPECTED TO OUTCOME FROM THE<br />

DOMESTIC SCIENCE, EDUCATION & INNOVATION SYSTEM.<br />

- THERE IS A NATIONAL CONSENSUS THAT BOTH THE<br />

EDUCATION SYSYEM & THE NATIONAL SCIENTIFIC<br />

BENEFITS HAVE TO BE CHANGED.<br />

- REGARDING THE HIGHER EDUCATION: REQUIREMENTS<br />

TO MEET THE BROAD - SPECTRUM TRAINING FOR NEW<br />

GENERATION SCIENTISTS.SCIENTIFIC SCIENTIFIC INSTITUTIONS (BAS)-<br />

TO GENERATE HIGH QUALITY RESEARCH FOR NEXT TECH<br />

SOCIETY (>N,>E, >G), INCLUDING NANOSCIENCE & TECHN.


BULGARIA<br />

Higher Education & Innovation<br />

Research & Innovation<br />

Business (Industry) and Markets<br />

INSTITUTIONS INVOLVED<br />

• The Parliament > There are several Commissions acting in the field;<br />

• The Bulgarian President > has an active role in science & education policy<br />

promotion; > 1-st National Forum for Science,13-14 May 2005,UNESCO sup.<br />

> 2-nd National Forum for Science,27-29 April 2009, UBS support<br />

• The Bulgarian Government> also plays an important role in innovation policy.<br />

- The Ministry of Education and Science: responsible for shaping-up<br />

policies for the development of science and technology in the country. (NSF)<br />

- The Ministry of Economy: working on innovation strategy and policy<br />

implementation for the business sector. (National Innovation Fund)<br />

- The Ministry of Regional Development: promoting regional innovation.<br />

- The Ministry of Labour & Social Policy: working on the improvement of<br />

hi-tech employment.


MINISTRY OF EDUCATION AND SCIENCE<br />

The Organization with high impact on the<br />

Higher Education, Science and Research Policy issues in BULGARIA<br />

A. Vutsova - ”Main Topics of Bulgarian National Science & Research Policy<br />

Towards ERA” , Report as NC person for 6 Framework Program , (2004)


MINISTRY OF EDUCATION AND SCIENCE<br />

BULGARIA - Scientific Research & Innovation<br />

National Scientific Programs in<br />

accordance to EC research priorities<br />

-Information Society – communications and computing,<br />

digital content and intelligent interfaces, e-services for citizens<br />

and business i.e.in all ICT aspects.<br />

-Genomics – stem cell research, plant genomics,<br />

bioinformatics, proteonics etc.<br />

-Nanotechnologies & New Materials – nanomaterials,<br />

ultrathin layers, multilayers nanosystems, nanobio-, mol. design<br />

-Bulgarian Society – Part of Europe - Effective participation<br />

in the European administration area, catch-up of differences in<br />

regional economic development<br />

- Ecology & Agriculture


MINISTRY OF EDUCATION AND SCIENCE<br />

www.nsfb.net<br />

BG local FP7 network (viko@uctm.edu)<br />

SME<br />

OTH<br />

HES<br />

ROR<br />

<strong>NCP</strong><br />

IND<br />

<strong>NCP</strong><br />

HES<br />

<strong>NCP</strong><br />

UNI<br />

EC/FP7<br />

HES<br />

IND<br />

<strong>NCP</strong><br />

IND<br />

OTH<br />

HES<br />

ROR<br />

IND<br />

FP7 National Contact<br />

Points for Bulgaria<br />

<strong>NCP</strong> – <strong>NMP</strong><br />

EUROPEAN<br />

<strong>NCP</strong> – <strong>NMP</strong><br />

Project Network<br />

HES<br />

<strong>NCP</strong><br />

IND<br />

IND<br />

OTH<br />

COOREERS<br />

<strong>NMP</strong>-<strong>NCP</strong> coordination action<br />

EUROPEAN <strong>NCP</strong> contacts exists


4-th Framework Program (1994- 1995).<br />

5-th FW Program (1998 - 2002).<br />

6-th FW Program (2002 - 2006) AREA 3 “NT & NS, knowledgebased<br />

multifunctional materials and new production process& devices”<br />

7-th FW Program (2006 - 2013) AREA 4 “Nanotechnologies,<br />

materials and production ” ; European Networking Events<br />

27 to 31, avenue du Général Leclerc - 94710 Maisons-Alfort Cedex - France on<br />

2nd June 2009 (09.00-19.00h)>Environment & Energy, RE: European stakeholders<br />

> http://www.vdivde-it.de/netwoeking-event-europoles<br />

2- 5 June 2009,EuroNanoForum2009 in Prague; > http://euronanoforum2009.eu<br />

11-15 May 2009, AHEMA 2009 Frankfurt am Main; >http://www.achema.de<br />

Info Days “GO” proposals > BREYDEL building (avenue Auderghem 45,<br />

Brussels) : FP7-<strong>NMP</strong>-2009- LARGE-3: 11 May 2009 ;FP7-<strong>NMP</strong>-2009-SMALL-3:<br />

4-th <strong>NMP</strong> call in July 2009 !<br />

13 May 2009; FP7-<strong>NMP</strong>-2009- SME-3 : 14 May 2009


BULGARIA<br />

& <strong>NMP</strong><br />

4-th Framework Program (1994- 1995).<br />

5-th FW Program (1998 - 2002).<br />

COST Action 523 < EUROPEAN COMMISSION ><br />

FOCUS on fields of activities: Synthesis & Processing > fundamental /mechanical<br />

/magnetic,electrical & optical / Characterization ; Application; Modeling <br />

Working Groups are established and few NoE and Integrated Projects have been deposited 2002.<br />

6-th FW Program (2002 - 2006) AREA 3 “NT & NS, knowledgebased<br />

multifunctional materials and new production process& devices”<br />

IP > MULTIPROTECT http://multiprotect.org/<br />

7-th FW Program (2006 - 2013) AREA 4 “Nanotechnologies,<br />

materials and production ” ; 4-th <strong>NMP</strong> call in July 2009


BULGARIA & <strong>NMP</strong><br />

4. Nanotechnologies, materials and production (<strong>NMP</strong>)<br />

NATIONAL PROJECTS :<br />

COST Action 523 - NoE (1998 - 2002) > EC support<br />

COSENT initiative , (2002/5) > UNESCO-ROSTE support<br />

NATIONAL CENTER of NANOTECHNOLOGY - BAS<br />

- NATIONAL WORKSHOPS on NS & NT, 2000 - 2008 , Sofia<br />

e.g. > 10th National Workshop Nanoscience & Nanotechnology,<br />

Nanotechnologies – Medicine – Society, November 27-28, 2008, Sofia, Bulgaria<br />

The main R&D activities: Theory, Modeling & Simulations,<br />

Nanoparticles & Composites, Thin films and Quantum dots,<br />

Nano-bio-materials and Medical appl., Micro and Nano- Eng..<br />

Dr. Ivanka Tsakovska, Centre of Biomedical Engineering at BAS ;<br />

- computational toxicology and nanotoxicology, Quantitative structure-activity<br />

relationships (QSARs) modelling for regulatory use.


UCTM<br />

BULGARIA & <strong>NMP</strong> (UCTM<br />

UCTM)<br />

- EDUCATION & TRAINING<br />

-2 New syllabuses for education in NS&T- MSc.<br />

- 8 > Ph.D. Students in the field<br />

- RESEARCH & DEVELOPMENT<br />

- 25 > Publications and Reports (10/15)<br />

- 7 > National Conferences<br />

- 9 > International Conferences<br />

- 18 > Projects (National- 15, International- 2 &<br />

EC(6fp)-1<br />

IP > MULTIPROTECT >http://multiprotect.org/<br />

UCTM > Above 16 events: National and International:<br />

- Nanostructured Materials for Advanced Technological Applications –1-13 June<br />

2008, Sozopol, Bulgaria , 4 NATO ASI.<br />

- Condensed Matter Physics, Conference of Balkan Countries, 26-28 May 2008,<br />

MUGLA UNIVERSITY, Mugla – Turkey .<br />

- E-MRS 2008 Autumn Meeting, 15 -19 September 2008, Warsaw, Poland , etc.


BOTTOM-UP<br />

SYNTHESIS<br />

TOP - DOWN<br />

PROCESSING<br />

The tiny<br />

revolution


*** NANO-SAFETY ***<br />

22-24.IV.2009, Ljubljana, Slovenia


The mission of<br />

To develop, identify and investigate of advanced materials and<br />

technology, including nanotechnology, in the strategic areas of<br />

EDUCATION, RESEARCH and APPLICATION . The main<br />

goal is to meet the needs of a future society, science and industry<br />

through activities as follows:<br />

www.lamar.hit.bg<br />

• - innovative education in frontier of the science<br />

• - international and interdisciplinary collaboration<br />

• - partnerships for a mutual progress<br />

• - research on a high level of expert competence<br />

• - application activities to the industry<br />

i.e. target focused on the MATERIALS with new effects for<br />

the future components, devices and systems.


CHARACTERISTICS > 1 - 7<br />

LAMAR-activities<br />

PHYSICAL<br />

CHEMICAL<br />

SYNTHESIS<br />

-Nanotoxicology<br />

-NanoSience &<br />

Society, etc.<br />

4.1.3: Health, Safety and<br />

Environmental Impacts<br />

VALIDATION<br />

\ EXPERT SYSTEMS<br />

PROPERTIES<br />

MODELING<br />

PERFORMANCE<br />

NANO<br />

STRUCTURE<br />

MATERIALS<br />

-super fine<br />

-nano level<br />

- Micro & macro<br />

-Ageing Tests<br />

-Exploatation<br />

and etc. tests


Shock wave<br />

P<br />

(atm)<br />

High pressure<br />

Solvothermal<br />

Hydrothermal<br />

Fusion<br />

C V D Gasflame Ion<br />

Electron<br />

Sputtering<br />

V. Evaporation<br />

Sol-Gel + Spray<br />

Solid State Reactions<br />

LASER<br />

PLASMA<br />

ENVIRONMENTAL<br />

1 atm.<br />

ATTRACTIVE<br />

0 1 2 3 x 1000 t , °C<br />

Deposition of thin-films and characterization/tests aspects are actual at present.


- NMR (NQR), ESR, MÖS<br />

- OESp, ICP-AES, AASp, UV-VIS,<br />

IR Sp, Raman Sp, X-Ray Sp<br />

- XRD, ED, ND, SAXS, SANS<br />

- SIMS, RBackScSp<br />

(METALLOGRAPHIC)<br />

- XPS, UPS, TEM, SEM, EDX,<br />

LEED, AFM, STM, POSITRONSp, etc.


-T.EXPANSION, CONDUCTIVITY etc.<br />

-E. CONDUCTIVITY, TRANSPORT<br />

BEHAVIOUR, DIELECTRIC etc.<br />

-ELASTICITY, ADHESION,CRACK<br />

PROPAGATION etc.<br />

- SURFACE TENSION &<br />

CAPILLARITY, TPB etc.


- Ageing under various atmospheres,<br />

temperatures and current loads<br />

(influence of the water vapour)<br />

- short (performance) and<br />

- long term (durability) tests<br />

-Thermodynamics and kinetics<br />

of evaporation,phase phormation &etc


Atmosphere corrosion test procedures<br />

Thermodynamical tests of<br />

nanocomposites stability<br />

Physical- Chemical characterization<br />

( Phase and Structure analysis )<br />

Corrosion tests at special conditions<br />

(high temperature corrosion tests)<br />

Potenciodynamic method application<br />

EIS - measurements<br />

Electrochemical noise


<strong>NMP</strong>3- SSA FP6- 510314 - ANVOC<br />

Application of Nanotechnologies<br />

for Separation and Recovery of Volatile Organic Compounds<br />

SES6-CT-2003-502612<br />

REAL - SOFC<br />

̌AREA 3--3<br />

--NT&NS, Knowledge based multifunctional<br />

materials and new production processes and devices<br />

<strong>NMP</strong>3-CT-2005-011783<br />

MULTIPROTECT<br />

SES 6-2004-510435<br />

ENFUGEN http://www.enfugen.net/


Advanced Environmentally Friendly<br />

Multifunctional Corrosion Protection by<br />

Nanotechnology<br />

<strong>NMP</strong>3-CT-2005-011783


INM<br />

EURICE<br />

IPA<br />

EADS<br />

LLI<br />

FEM<br />

ELAS<br />

TNO<br />

TUS<br />

UNIMAN<br />

SEI<br />

BUH<br />

ICF<br />

INASMET<br />

ICV<br />

UCTM<br />

ISQ<br />

AVEIRO<br />

NCSR<br />

HAI<br />

GENTACASTI<br />

CRF<br />

UDINE<br />

CSM<br />

PLALAM<br />

CROMOSPHER<br />

IIM<br />

SHL/IAI<br />

ALUBIN<br />

ISRAEL


<strong>NMP</strong>3-CT-2005-011783<br />

MULTIPROTECT<br />

STRUCTURE , INTEGRATION & WP Leaders<br />

PARTNERS 1 - 31<br />

IP- MULTIPROTECT<br />

UCTM<br />

INM & EURICE<br />

GENTA&TIPO<br />

INM<br />

IPA & IIM<br />

EADS<br />

CASTI<br />

UDINE &<br />

EURUCE<br />

Supported by the European Commission under the 6 th Framework Programme


Atmosphere corrosion test procedures<br />

Thermodynamical tests of<br />

nanocomposites stability<br />

Physical- Chemical characterization<br />

( Phase and Structure analysis )<br />

Corrosion tests at special conditions<br />

(high temperature corrosion tests)<br />

Potenciodynamic method application<br />

EIS - measurements<br />

Electrochemical noise


APPLICATION


COLABORATION<br />

INSTITUTE OF ORGANIC<br />

CATALYSIS AND<br />

INSTITUTE OF HIGH<br />

ELECTROCHEMISTRY<br />

TEMPERATURE<br />

ELECTROCHEMISTRY<br />

FLORIDA STATE<br />

UNIVERSITY<br />

INTERCONTINENTAL<br />

BORESKOV<br />

INSTITUTE OF<br />

CATALYSIS<br />

ESOF 2004 – Stockholm , Sweden<br />

ESOF-2006<br />

– Munich , Germany<br />

ESOF-2008<br />

– Barcelona , Spain<br />

ESOF-2010<br />

– Torino , Italy<br />

DALIAN<br />

MARITIME<br />

UNIVERSITY<br />

TOHOKU<br />

UNIVERSITY<br />

UNIVERSITY<br />

OF TSUKUBA<br />

DOHA<br />

UNIVERSITY


The support from the Government of Republic<br />

SLOVENIJA regarding International<br />

Conference on NANO-SAFETY is greatly<br />

acknowledged.<br />

www.lamar.hit.bg<br />

UCTM & UJI UCTM & UJI 28<br />

UCTM, Sofia, Bulgaria

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