Strychnos 1990 - 2004 - Crops for the Future

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Author Title Year Source title Reference Hosagoudar, V. B. and S. Shiburaj Meliola gamsii sp nov (ascomycetes, meliolales) from Kerala, India 2002 Nova Hedwigia 74(3-4): 411-413 Abstract The new species Meliola gamsii is described from the host plant Strychnos mix-vomica from Kerala, I n d i a . Author Title Year Source title Reference Khumalo, L. W., L. Majoko, J. S. Read and I. Ncube Characterisation of some underutilised vegetable oils and their evaluation as starti 2002 Industrial Crops and Products 16(3): 237-244 Abstract Oils were extracted from the inner skin of Strychnos madagascariensis fruit shell, Trichelia emetica seed and Ximenia caffra seed. Gas chromatography analysis of methyl esters of the glycerides of these oils was used to determine the fatty acid profiles of the oils. S. madagascariensis and X. caffra oils were found to contain high oleic acid levels, 68 and 59% respectively, while T emetica oil was found to contain 53% palmitic acid. Pancreatic lipase digestion was used to perform structural analyses on the triglycerides of oils. Oleic acid was found to be concentrated at the 2-position of the triglycerides of the X caffra and T emetica oils. The three oils were evaluated for use as starting materials in lipase-catalysed production of cocoa butter equivalents using transesterification reactions. A 1,3-specific lipase from Rhizomucor miehei was used to incorporate stearic acid and palmitic acid into the 1- and 3-positions of the triglycerides. The products of the transesterifications in the case of X caffra and S. niadagascariensis compare well with those produced using lipasecatalysed transesterifications of other oils. (C) 2002 Elsevier Science B.V. All rights reserved.
Author Title Year Source title Reference Abstract Lansiaux, A., C. Bailly, C. Houssier, P. Colson, M. C. De Pauw-Gillet, M. Frederi Apoptosis of hl-60 leukemia cells induced by the bisindole alkaloids sungucine an 2002 Planta Medica 68(7): 591-595 - Author Title Year Source title Reference Abstract Lynch, S. M., S. K. Bur and A. Padwa Intramolecular amidofuran cycloadditions across an indole pi-bond: An efficient a 2002 Organic Letters 4(26): 4643-4646 - Author Title Year Source title Reference Martin, S. F. Evolution of the vinylogous mannich reaction as a key construction for alkaloid sy 2002 Accounts of Chemical Research 35(10): 895-904 Abstract The vinylogous Mannich reaction is rapidly emerging as an important process for the construction of derivatives of delta-aminocarbonyl compounds. Because the iminium and dienol components employed in this addition may be either acyclic or cyclic, a wide variety of adducts may be quickly assembled. These intermediates may then in turn be converted into a broad array of alkaloids and substituted nitrogen heterocycles. We have developed a number of variations of this reaction and have applied some of them to the concise syntheses of a number of structurally diverse and complex alkaloid natural products. Many of these results are presented in a historical context in this Account.
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