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Technical Manual - Section 3 (Safety Hazards)

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SECTION III: CHAPTER 2<br />

PETROLEUM REFINING PROCESSES<br />

A. INTRODUCTION<br />

The petroleum industry began with the successful drilling of<br />

the first commercial oil well in 1859, and the opening of the<br />

first refinery two years later to process the crude into<br />

kerosene. The evolution of petroleum refining from simple<br />

distillation to today's sophisticated processes has created a<br />

need for health and safety management procedures and safe<br />

work practices. To those unfamiliar with the industry,<br />

petroleum refineries may appear to be complex and confusing<br />

places. Refining is the processing of one complex mixture of<br />

hydrocarbons into a number of other complex mixtures of<br />

hydrocarbons. The safe and orderly processing of crude oil<br />

into flammable gases and liquids at high temperatures and<br />

pressures using vessels, equipment, and piping subjected to<br />

stress and corrosion requires considerable knowledge,<br />

control, and expertise.<br />

<strong>Safety</strong> and health professionals, working with process,<br />

chemical, instrumentation, and metallurgical engineers, assure<br />

that potential physical, mechanical, chemical, and health<br />

hazards are recognized and provisions are made for safe<br />

operating practices and appropriate protective measures.<br />

These<br />

A. Introduction. . . . . . . . . . . . . . . . . . . . . . . . III:2-1<br />

B. Overview of the Petroleum Industry. . . . . III:2-2<br />

C. Petroleum Refining Operations . . . . . . . III:2-11<br />

D. Description of Petroleum Refining<br />

Processes and Related Health and<br />

<strong>Safety</strong> Considerations. . . . . . . . . . . . . . III:2-15<br />

E. Other Refinery Operations. . . . . . . . . . . III:2-49<br />

F. Bibliography. . . . . . . . . . . . . . . . . . . . . . III:2-58<br />

Appendix III:2-1. Glossary. . . . . . . . . . . . . .III:2-59<br />

measures may include hard hats, safety glasses and goggles,<br />

safety shoes, hearing protection, respiratory protection, and<br />

protective clothing such as fire resistant clothing where<br />

required. In addition, procedures should be established to<br />

assure compliance with applicable regulations and standards<br />

such as hazard communications, confined space entry, and<br />

process safety management.<br />

This chapter of the technical manual covers the history of<br />

refinery processing, characteristics of crude oil, hydrocarbon<br />

types and chemistry, and major refinery products and<br />

by-products. It presents information on technology as<br />

normally practiced in present operations. It describes the<br />

more common refinery processes and includes relevant safety<br />

and health information. Additional information covers<br />

refinery utilities and miscellaneous supporting activities<br />

related to hydrocarbon processing. Field personnel will learn<br />

what to expect in various facilities regarding typical materials<br />

and process methods, equipment, potential hazards, and<br />

exposures.<br />

The information presented refers to fire prevention, industrial<br />

hygiene, and safe work practices, and is not intended to<br />

provide comprehensive guidelines for protective measures<br />

and/or compliance with regulatory requirements. As some of<br />

the terminology is industry-specific, a glossary is provided as<br />

an appendix. This chapter does not cover petrochemical<br />

processing.<br />

III:2-1

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