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Please note - Swinburne University of Technology

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SC748<br />

Water Treatment <strong>Technology</strong><br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Prerequisites: SC716 and SC717 (SC747 is<br />

advised)<br />

Subject description<br />

Implications <strong>of</strong> colloidal chemistry in waste water treatment.<br />

The role <strong>of</strong> adsorption phenomena in waste water treatment.<br />

Biological and non-biological treatment technologies. An<br />

overview <strong>of</strong> common and advanced treatment technologies<br />

including alum flocculation, biochemical treatment, cellular<br />

foam microbial degradation and adsorbing colloid flotation.<br />

Emphasis will be placed on those technologies using colloidal<br />

principles to separate contaminant from clean water.<br />

~ ~ 7 4 9 Polymer Flocculation<br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Prerequisites: SC716 and SC717 (SC747 and<br />

SC752 are advised)<br />

Subject description<br />

Types <strong>of</strong> flocculants - natural, synthetic and metal ions vs<br />

polymers. Flocculants in solution and adsorption <strong>of</strong> polymers.<br />

Bridging model, floc formation and floc strucfure. The role <strong>of</strong><br />

DLVO theory. Selective flocculation, sensitisatlon and protective<br />

action. General principles <strong>of</strong> water treatment. Flocculation <strong>of</strong><br />

4 clays, pigments, etc. Analytical methods for determining low<br />

concentration <strong>of</strong> flocculants. Effect <strong>of</strong> pH on flocs and floc<br />

building.<br />

n<br />

ID<br />

m<br />

'0.<br />

2<br />

SC75o<br />

Detergency<br />

(D 7.5 credit points<br />

2.<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

2<br />

a<br />

Prerequisites: SC744 and SC717 (SC716 is advised)<br />

0)<br />

2<br />

CT<br />

Subject description<br />

0 Detergent action and the role <strong>of</strong> contact angle, adhesion,<br />

. cohesion, micellisation and emulsification. Methods <strong>of</strong> analysis<br />

ID<br />

2 ranging from cloud point determination and two-phase<br />

titrations to infra-red and NMR analysis. Detergent<br />

biodegradability.<br />

Detergent formulation for specific needs, eg. s<strong>of</strong>teners,<br />

conditioners. Specific examples <strong>of</strong> interest, eg. removal <strong>of</strong><br />

lanolin from wool and the formulation <strong>of</strong> haw shampoos.<br />

~ ~ 7 5 1 Emulsion <strong>Technology</strong><br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Prerequisites: SC744, SC716 and SC717<br />

Subject description<br />

Common methods for obtaining emulsions and their<br />

subsequent use. Emulsion polymerisation and the properties <strong>of</strong><br />

polymer latices.<br />

The theory <strong>of</strong> ernulsion stability. Long range (DLVO) and short<br />

range (Gibb's-Marangoni) stability. Surface chemical factors<br />

and the application <strong>of</strong> the DLVO theory. Surface elasticity and<br />

surface viscosity. The role <strong>of</strong> macromolecules as emulsion<br />

stabilisers. Stabilisation by finely divided solids and the<br />

properties <strong>of</strong> thin films (eg. rupture). Breakdown <strong>of</strong> emulsions<br />

(thermodynamics). Applications to cosmetics, food, bitumen,<br />

wax, etc.<br />

scm<br />

Polymer Stabilisation <strong>Technology</strong><br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Prerequisite: SC716<br />

Subject description<br />

Equilibrium thermodynamics <strong>of</strong> solutions <strong>of</strong> large<br />

macromolecules and configurational statistics <strong>of</strong> polymers.<br />

Forces <strong>of</strong> steric repulsion. Volume restriction and mixing<br />

models. Calculation <strong>of</strong> free enemies. Steric stabilisation. steric<br />

flocculation depletion stabilisation and depletion floccuiation.<br />

Orientation <strong>of</strong> adsorbed layers.<br />

Experimental methods for measuring the thickness <strong>of</strong> an<br />

adsorbed layer. Implications <strong>of</strong> the adsorbed layer in particle<br />

stability. Desiqn <strong>of</strong> copolvmers and selection <strong>of</strong> various<br />

structural components. ~pplication to the dispersion <strong>of</strong><br />

pigments in various media and to polymer flocculation.<br />

~ ~ 7 5 3 Thin Films and Foams<br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Prerequisites: SC716, SC717 (SC744 and SC751<br />

are advised)<br />

Subject description<br />

The properties, stability and rupture <strong>of</strong> foams. Disjoining<br />

pressure, calculation <strong>of</strong> electrostatics. VOW and steric<br />

components <strong>of</strong> disjoining pressure. instability and rupture <strong>of</strong><br />

thin films (advanced).<br />

Evidence pertaining to short range hydration and hydrophobic<br />

forces, based on experimental studies and statistical<br />

mechanical treatments <strong>of</strong> fluids at interfaces. Application <strong>of</strong><br />

flotation emulsions and the stability <strong>of</strong> froths and foams.<br />

~ ~ 7 5 4 Light Scattering and Concentrated<br />

Dispersions<br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Prerequisites: SC716 and SC717 (SC718 and<br />

SC719 are advised)<br />

Subject description<br />

Radial distribution function (g(r)) - relationship between g(r)<br />

and S(Q) (Q is the scattering vector) - potential <strong>of</strong> mean force<br />

and its link to g(r). Measurement <strong>of</strong> g(r) through the scattering<br />

<strong>of</strong> radiation and its angular variation -determination <strong>of</strong> S(Q)<br />

using theoretical models, link between S(Q) and osmotic<br />

compressibility.<br />

Photon correlation spectroscopy, small angle neutron scattering<br />

and low angle X-ray diffraction. Concept <strong>of</strong> the scattering<br />

density parameter, particle form factor P(Q) and the structure<br />

factor S(Q). Application to microemulsions, latices and pigment<br />

dispersions.

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