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Please note - Swinburne University of Technology

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~ ~ 7 4 0 Chemistry <strong>of</strong> Surface Coatings<br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Subject description<br />

Purpose and types <strong>of</strong> coatings. Coatings components. Pigment<br />

dispersion and preparation <strong>of</strong> coatings. The structure <strong>of</strong><br />

silicone coatings and their correlation with wetting and<br />

adhesive strength. Application <strong>of</strong> emulsion technology and the<br />

formulation <strong>of</strong> a simple paint using a latex base. Preparation<br />

<strong>of</strong> resins (eg. alkyd resins). Convertible and non-convertible<br />

coatings, anodising, thin films.<br />

~ ~ 7 4 1 Physical Properties <strong>of</strong> Surface<br />

Coatings<br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Subject description<br />

Surface physics including colour reflectivity and surface<br />

hardness. Drying <strong>of</strong> films and the role <strong>of</strong> pigment dispersion to<br />

successful drying. Surface rheology and other characterisation,<br />

including spectroscopy. Measurement and influence <strong>of</strong> critical<br />

pigment volume and humidity. Tactile strength and durability.<br />

sc74z<br />

Corrosion and Protection <strong>of</strong> Metals<br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Subject description<br />

Electrochemical principles <strong>of</strong> corrosion. Thermodynamic<br />

aspects <strong>of</strong> corrosion, Pourbaix diagrams, protective measures.<br />

Kinetics <strong>of</strong> corrosion; electrochemical techniques for<br />

determining corrosion rate, corrosion inhibition, inhibitors,<br />

passivation, anodic and cathodic protection. The subject will<br />

include some practical work on corrosion measurement and<br />

galvanic corrosion.<br />

~ ~ 7 4 3 Food Colloids<br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Subject description<br />

Emulsion theory and colloid rheology as applied to foods.<br />

Common emulsifiers in food and their safety, use, detection<br />

purpose. Wettability <strong>of</strong> non-aqueous materials (eg. fats, flour)<br />

in the presence and absence <strong>of</strong> emulsifiers. Applicability <strong>of</strong><br />

colloid theory to foods.<br />

~ ~ 7 4 4 Chemistry <strong>of</strong> Surfactants<br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Prerequisites: SC717, and SC716 is recommended<br />

Subject description<br />

The origin, manufacture, nature and use <strong>of</strong> surfactants. The<br />

choice <strong>of</strong> cationic, anionic or non-ionic surfactants.<br />

Environmental and safety aspects <strong>of</strong> surfactants and an<br />

introduction to the detection and determination <strong>of</strong><br />

surfactants.<br />

Adsorption at interfaces, wettability and contact angle.<br />

Selection <strong>of</strong> surfactants for particular tasks, eg. the choice <strong>of</strong><br />

emulsifiers and the role <strong>of</strong> the HLB (hydrophobe-lypophobe<br />

balance). An introduction to the stability and rupture <strong>of</strong> thin<br />

films and foams. Applications <strong>of</strong> surfactants (eg. emulsions<br />

and detergency). Solution properties <strong>of</strong> detergents<br />

(introduction) (eg. micellisation, phase diagrams, surface<br />

tension and solubilisation).<br />

sc745<br />

Solution Behaviour <strong>of</strong> Surfactants<br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Prerequisites: SC717, and SC716 and SC744 are<br />

recommended<br />

Subject description<br />

Phase behaviour, diagrams and maps for surfactant systems at<br />

an advanced level. Properties, detection and thermodynamics<br />

<strong>of</strong> surfactant phases such as micelles, liquid crystals and<br />

lamellae.<br />

Preparation <strong>of</strong> soap, tertiary oil recovery and other uses <strong>of</strong><br />

phase maps. Properties, preparation, characterisation and uses<br />

<strong>of</strong> microemulsions.<br />

sc746<br />

Advanced DLVO Theory<br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Prerequisite: SC716<br />

Subject description<br />

DLVO (Deryaguin-Landau-Verwey-Overbeek) theory -<br />

mathematical interpretation <strong>of</strong> colloidal stability based on the<br />

addition <strong>of</strong> attractive dispersion forces and repulsive<br />

electrostatic forces. Interaction between atoms, leading to an<br />

overall generalisation for macroscopic interactions. Derivation<br />

<strong>of</strong> the relationship between charge and potential under<br />

conditions <strong>of</strong> constant charge, constant potential or charge<br />

regulation. Free energy <strong>of</strong> the electrical double layer. The role<br />

<strong>of</strong> DLVO theory to the adsorption <strong>of</strong> small ions. Detailed<br />

derivation <strong>of</strong> the Poisson-Boltzmann equation which relates<br />

charge and potential.<br />

~ ~ 7 4 7 Adsorption from Solution<br />

7.5 credit points<br />

No. <strong>of</strong> hours per week: four hours for five weeks<br />

Prerequisites: SC716 (SC717 is recommended)<br />

Subject description<br />

An ovesew <strong>of</strong> forces involved in adsorption from solution. The<br />

role <strong>of</strong> electrostatics. solvation and chemical terms. Chemical<br />

modelling (site binding).<br />

Uptake onto colloidal materials <strong>of</strong> toxic aqueous pollutants<br />

such as heavy metals, anions, organics and polymers. Industrial<br />

significance <strong>of</strong> adsorption and its implications in waste water<br />

treatment. Practical aspects <strong>of</strong> adsorption phenomena<br />

including experimental design. Adsorption <strong>of</strong> simple<br />

electrolytes.

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