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N2O production in a single stage nitritation/anammox MBBR process

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10<br />

8<br />

DO concentration, pH & temperature<br />

35<br />

28<br />

DO (mg/l), pH<br />

6<br />

4<br />

2<br />

21<br />

14<br />

7<br />

Temp °C<br />

DO (mg/l)<br />

pH<br />

Temperature (°C)<br />

0<br />

0<br />

06/07/09<br />

26/07/09<br />

15/08/09<br />

04/09/09<br />

24/09/09<br />

Date<br />

14/10/09<br />

03/11/09<br />

23/11/09<br />

13/12/09<br />

350<br />

Concentrations of <strong>in</strong>fluent and effluent total <strong>in</strong>organic nitrogen<br />

Total <strong>in</strong>organic nitrogen (mg/l)<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

0<br />

Σ TIN <strong>in</strong> (mg/l)<br />

Σ TIN out (mg/l)<br />

06/07/09<br />

26/07/09<br />

15/08/09<br />

04/09/09<br />

24/09/09<br />

Date<br />

14/10/09<br />

03/11/09<br />

23/11/09<br />

13/12/09<br />

Removal rate (gN/m²d)<br />

1.8<br />

1.6<br />

1.4<br />

1.2<br />

1.0<br />

0.8<br />

0.6<br />

0.4<br />

0.2<br />

0.0<br />

Removal rate (gN/m²d) & % reduction of <strong>in</strong>comm<strong>in</strong>g nitrogen<br />

90<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

% reduction<br />

Removal rate<br />

(gN/m2d)<br />

% reduction<br />

06/07/09<br />

26/07/09<br />

15/08/09<br />

04/09/09<br />

24/09/09<br />

Date<br />

14/10/09<br />

03/11/09<br />

23/11/09<br />

13/12/09<br />

Figure 13. Reactor operation and <strong>process</strong> performance dur<strong>in</strong>g the period 09/07/09-15/12/09.<br />

Top graph illustrates concentration of DO dur<strong>in</strong>g aeration, pH and temperature. The second graph<br />

shows total concentration of <strong>in</strong>organic nitrogen <strong>in</strong> <strong>in</strong>fluent feed and effluent water. The third<br />

shows the removal rate gN/m 2 d and the reduced nitrogen <strong>in</strong> %.<br />

Figure 14 shows the <strong>process</strong> performance dur<strong>in</strong>g different operation modes. Green<br />

series are represent<strong>in</strong>g measurements done at <strong>in</strong>termittent aeration dur<strong>in</strong>g the period<br />

090918-090927. Blue series are represent<strong>in</strong>g measurements at cont<strong>in</strong>uous operation,<br />

DO ~1.5 mg/l dur<strong>in</strong>g the period 091006-091010. Orange series are represent<strong>in</strong>g<br />

measurement at cont<strong>in</strong>uous operation, DO ~1mg/l dur<strong>in</strong>g the period 091013-091016.<br />

32

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