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N2O production in a single stage nitritation/anammox MBBR process

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Chapter 4<br />

4. Results<br />

4.1 Process performance<br />

Variations <strong>in</strong> nitrogen concentration of the <strong>in</strong>fluent medium, flow rate, temperature and<br />

pH are shown <strong>in</strong> Table 7 and Figure 13. Variations <strong>in</strong> nitrogen concentration shown <strong>in</strong><br />

Figure 13 are the sum of <strong>in</strong>fluent nitrogen compounds accounted for <strong>in</strong> Table 7. The<br />

figure also shows variations <strong>in</strong> oxygen concentrations dur<strong>in</strong>g aeration.<br />

Table 7. Characteristics of <strong>in</strong>fluent feed, flow rates, temperature and pH dur<strong>in</strong>g the operation<br />

period 09/07/09-15/12/09.<br />

Nitrogen mg/l<br />

NH 4-N NO 2-N NO 3-N Q l/h T °C pH<br />

264.5 ± 24.5 19.7 ±12.4 3.6 ±2.1 0.48 ±0.06 30.0 ±0.8 7.3-7.8<br />

Changes of nitrogen concentrations <strong>in</strong> the effluent water are shown together with %<br />

nitrogen reduction and the total nitrogen removal <strong>in</strong> Table 8 and Figure 13. The Effluent<br />

nitrogen illustrated <strong>in</strong> Figure 13 is the sum of effluent nitrogen compounds seen <strong>in</strong> Table<br />

8.<br />

Table 8. Average concentrations of <strong>in</strong>organic nitrogen <strong>in</strong> effluent water, reduction rates and<br />

removal rates dur<strong>in</strong>g the operation period 09/07/09-15/12/09.<br />

Nitrogen mg/l<br />

NH 4-N NO 2-N NO 3-N<br />

Reduction % Removal gN/m 2 d<br />

82.4 ±44.0 6.3 ±1.7 32.3 ±9.5 58 ±13 1.1 ±0.2<br />

On the 28 th of September the operation mode was changed to cont<strong>in</strong>uous aeration,<br />

aim<strong>in</strong>g at a DO level of ~1.5 mg/l. It took around one week to get a stable performance<br />

at the desired oxygen level. For measurements at even lower oxygenation the oxygen<br />

concentration was further decreased to ~1.0 mg/l.<br />

31

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