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N2O production in a single stage nitritation/anammox MBBR process

N2O production in a single stage nitritation/anammox MBBR process

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To enable efficient nutrient removal the hydraulic conditions should prevent the buildup<br />

of a lam<strong>in</strong>ar layer and the contact surface between water phase and biofilm should be<br />

as large as possible (Metcalf & Eddy, I. 2003).<br />

2.5 System configurations for nitrogen removal by <strong>anammox</strong><br />

Nitrogen removal by <strong>anammox</strong> can be implemented either as a two <strong>stage</strong> or one <strong>stage</strong><br />

system. 50% of the <strong>in</strong>fluent ammonium is oxidised to nitrite by nitrify<strong>in</strong>g bacteria <strong>in</strong><br />

both cases. In a two <strong>stage</strong> system this conversion takes place <strong>in</strong> a <strong>nitritation</strong> reactor<br />

followed by an <strong>anammox</strong> reactor where the oxidation of ammonium <strong>in</strong>to d<strong>in</strong>itrogen gas<br />

with nitrite takes place. In s<strong>in</strong>gle <strong>stage</strong> technology both <strong>process</strong>es takes place <strong>in</strong> the<br />

same reactor (Abma et al., 2007). S<strong>in</strong>ce the <strong>anammox</strong> <strong>process</strong> was discovered by<br />

different research teams and <strong>in</strong> slightly diverse environments the system configurations<br />

evolved have been given different names but are <strong>in</strong> practice quite similar. Ma<strong>in</strong><br />

differences are reactor configuration and operational mode. Some of the available<br />

<strong>anammox</strong> <strong>process</strong>es are shortly described <strong>in</strong> this chapter.<br />

2.5.1 Sharon/Anammox<br />

A Sharon (s<strong>in</strong>gle reactor system for high rate ammonium removal over nitrite)<br />

reactor followed by an <strong>anammox</strong> reactor is a possible system configuration to achieve<br />

nitrogen removal with <strong>anammox</strong> bacteria. The Sharon <strong>process</strong> is used to nitrify 50% of<br />

the <strong>in</strong>fluent ammonium to nitrite. The effluent from the Sharon reactor is then used as<br />

feed for the <strong>anammox</strong> reactor where nitrite and ammonium is converted to elemental<br />

nitrogen, see Figure 5, (Stowa, 2009).<br />

Figure 5. Sharon/Anammox <strong>process</strong> scheme.<br />

To achieve partial nitrification to only 50% the Sharon reactor is operated <strong>in</strong> a manner<br />

that benefits the ammonium oxidizers, wash<strong>in</strong>g out the nitrite oxidizers from the system<br />

(van Dongen et al., 2001). This is obta<strong>in</strong>ed by operation above 25 ̊C, keep<strong>in</strong>g the sludge<br />

15

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