N2O production in a single stage nitritation/anammox MBBR process
N2O production in a single stage nitritation/anammox MBBR process
N2O production in a single stage nitritation/anammox MBBR process
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2.3.4 Mov<strong>in</strong>g bed reactor<br />
Another way to design a compact biofilm <strong>process</strong> is to use a suspended <strong>in</strong>ert carrier that<br />
moves freely with<strong>in</strong> the reactor. The first carrier materials were small polyethylene<br />
(density 0.95 g/cm 3 ) cyl<strong>in</strong>ders with a cross <strong>in</strong> side provid<strong>in</strong>g the microorganisms with a<br />
protected surface to grow on. The carriers are kept <strong>in</strong> motion by aeration or mechanical<br />
stirr<strong>in</strong>g, a sieve <strong>in</strong> the outlet keeps the mov<strong>in</strong>g carriers <strong>in</strong> the reactor. The reactor does<br />
not clog and there is no need for backwash<strong>in</strong>g or biomass recycl<strong>in</strong>g. (Ødegaard et al.,<br />
1994). Different shapes and sizes of the carrier material provides an effective specific<br />
area rang<strong>in</strong>g from 220 -1200 m 2 /m 3 (AnoxKaldnes, 2009). Biofilm thickness depends on<br />
carrier design and hydraulic conditions <strong>in</strong> the reactor. If a stagnant lam<strong>in</strong>ar layer is<br />
formed around the carrier material this will <strong>in</strong>crease the diffusional resistance that is<br />
limit<strong>in</strong>g <strong>in</strong> biofilm <strong>process</strong>es. The mov<strong>in</strong>g bed technology can also be comb<strong>in</strong>ed with the<br />
activated sludge <strong>process</strong> result<strong>in</strong>g <strong>in</strong> higher removal rates and more compact systems.<br />
2.3.5 Rotat<strong>in</strong>g disc<br />
Rotat<strong>in</strong>g filters are constituted of flat discs often made out of plastic, 2-3 meters <strong>in</strong><br />
diameter mounted <strong>in</strong> rows on a horizontal shaft. The filter medium that is semisubmerged<br />
is alternately rotated through the water phase at right angles to the flow.<br />
The filters are 10-20 mm thick, spaced about 20 mm apart and have an active surface<br />
area of about 150-200 m 2 /m 3 (Gray N, 2004). Rotation of the filter discs keeps the<br />
biofilm oxygenated and the motion creates an efficient contact between the water phase<br />
and biofilm. Revolution speed of the filter is controll<strong>in</strong>g the biofilm thickness (Henze et<br />
al., 1997).<br />
2.4 Biofilm k<strong>in</strong>etics<br />
The k<strong>in</strong>etics of substrate conversion <strong>in</strong> a biofilm reactor is dependent of the reactor<br />
configuration that decides the biofilm structure and of available nutrients <strong>in</strong> the<br />
wastewater. Substrates <strong>in</strong> the water bulk phase are converted to biomass, energy and<br />
end products through cellular metabolism <strong>in</strong> the bacteria. The mass balance for an<br />
<strong>in</strong>f<strong>in</strong>itely small section of the biofilm is described by:<br />
(2.4.1)<br />
(2.4.2)<br />
where: Q is the volumetric flow, (dimension L -3 ∙T -1 ), C is the concentration, (dimension<br />
M∙L -3 ), r describes the biological growth rate, (dimension M∙L -3 ∙ T -1 ) and V is the reactor<br />
volume, (dimension L -3 ), (Warfv<strong>in</strong>ge, 2008).<br />
The substrate conversion rate <strong>in</strong> a biofilm reactor is dependent on three ma<strong>in</strong><br />
mechanisms, the diffusion resistance of substrates from the well mixed water bulk phase<br />
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