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SRC Users' Meeting - Synchrotron Radiation Center - University of ...

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spatially resolved chemistry <strong>of</strong> the ZDDPdet film was found to be short-chain calcium<br />

phosphate throughout.<br />

Fiducial marks allowed for<br />

the re-location <strong>of</strong> the same<br />

areas with an imaging<br />

nanoindenter. This allowed<br />

the nanoscale mechanical<br />

properties, <strong>of</strong> selected<br />

antiwear pads, to be<br />

measured on the same length scale. The indentation modulus <strong>of</strong> the ZDDP antiwear pads<br />

were found to be heterogeneous, ~120 GPa at the center and ~90 GPa at the edges. The<br />

ZDDPdet antiwear pads were found to be more uniform and have a similar indentation<br />

modulus <strong>of</strong> ~90 GPa. A theory explaining this measured similarity, which is based on the<br />

probing depths <strong>of</strong> all techniques used, sheds new insight into the structure and<br />

mechanical response <strong>of</strong> ZDDP antiwear films.

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