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Solubility of Nitrous Oxide in Amine Aqueous Solutions - Scientific ...

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Figure 5. Comparison between calculated and experimental literature solubility data <strong>of</strong> N 2 O <strong>in</strong><br />

aqueous MEA solutions.<br />

Experimental solubilities <strong>of</strong> N 2 O <strong>in</strong> DEA + H 2 O are shown <strong>in</strong> Figure 6. There is a satisfactory<br />

agreement between experimental and correlation data at all temperatures and concentrations. The<br />

results <strong>of</strong> calculations, us<strong>in</strong>g equation 7, <strong>of</strong> the present work (solid l<strong>in</strong>es), Tsai et al [10] (dotted<br />

l<strong>in</strong>es), and Wang et al. [17] (broken l<strong>in</strong>es) correlations when applied to experimental data <strong>of</strong> Little et<br />

al [24] are shown <strong>in</strong> Figure 7. The correlation <strong>of</strong> Wang et al [17] shows very poor predictions at lowtemperature<br />

(15, 20, 25, and 30 °C) solubility data. On the other hand, results obta<strong>in</strong>ed by Tsai et al<br />

[10] correlation deviate from experimental values when the temperature is <strong>in</strong>creased above 45 o C.<br />

However, the calculated Henry's constant values us<strong>in</strong>g equation 7 are consistent with most <strong>of</strong> the<br />

data <strong>of</strong> Little et al [24] at all temperatures and concentrations <strong>of</strong> DEA.<br />

10

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