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Thermochemistry Webquest worksheet - Quia

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ThermoChemistry (Energy) WebQuest<br />

Name _________________________________________ Period _______<br />

Part 1 – Vocabulary http://www.learnchem.net/glossary/<br />

Define the following terms:<br />

1. Kinetic energy –<br />

2. Potential energy –<br />

3. Endothermic –<br />

4. Exothermic –<br />

5. Activation energy –<br />

6. Calorie –<br />

7. Enthalpy -<br />

8. Entropy-<br />

9. Specific Heat Capacity-<br />

10. Free Energy -<br />

11. Hess’s Law –<br />

12. Heat of Fusion-<br />

13. Heat of Vaporization-<br />

14. Heat of Solution-<br />

15. Thermochemical Equation-


ThermoChemistry (Energy) WebQuest<br />

Name _________________________________________ Period _______<br />

Part 2 - Reaction Rates<br />

http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/activa2.swf<br />

Listen to the introduction.<br />

Play & Listen to the Exothermic & Endothermic Reaction animation.<br />

Draw an exothermic & endothermic energy profile<br />

Label: axes, reactants, products, activation energy, activated complex, heat of<br />

reaction<br />

Exothermic<br />

Endothermic<br />

Part 3- Hess’s Law Problems<br />

http://www.youtube.com/watch?v=_NLAgSnqNOE<br />

Watch and Listen to the Hess’s Law Demonstration.<br />

What is the total enthalpy change of the example problem done in the demo?<br />

____________<br />

http://employees.oneonta.edu/viningwj/sims/hess_law_s.html<br />

Click on the Description Button and read the description.<br />

Click and drag the reactions down until the Net Reaction appears as shown below.<br />

Fill in the reactions and H° values below.<br />

Reaction 1:<br />

H°=<br />

Reaction 2:<br />

Reaction 3:<br />

H°=<br />

H°=<br />

Net Reaction: 2SnCl 2 (s) + TiBr 2 (s) + 2Cl 2 (g) SnBr 2 (s) + SnCl 4 (l) +TiCl 4 (l) H° Net =<br />

<br />

Change the reactions by clearing and reversing them until the Net Reactions<br />

equals the one shown below. Fill in the reactions and H° values below.


ThermoChemistry (Energy) WebQuest<br />

Name _________________________________________ Period _______<br />

Reaction 1:<br />

Reaction 2:<br />

Reaction 3:<br />

H°=<br />

H°=<br />

H°=<br />

Net Reaction: SnCl 2 (s) + TiBr 2 (s) + Cl 2 (g) SnBr 2 (s) + TiCl 4 (l) H° Net =<br />

Part 4- Specific Heat<br />

http://hyperphysics.phy-astr.gsu.edu/hbase/thermo/spht.html#c1<br />

Write the formula that can be used to calculate the heat energy being absorbed or<br />

released in a system.<br />

<br />

Describe each part of the equation<br />

Heat gained or lost = Mass x Change in Temperature x Specific Heat<br />

Mass –<br />

Change in temperature -<br />

Specific Heat –<br />

http://employees.oneonta.edu/viningwj/sims/specific_heat_s.html<br />

Click on the Description Button and read the description.<br />

Choose a material from the drop down box. Choose either 5 or 10 grams of your<br />

material. Move the slider to determine how long the material will be heated.<br />

Click HEAT<br />

Fill in the data below and calculate the specific heat of your material.<br />

Initial temp = Final Temp = T =<br />

Mass of Block =<br />

Heat Added to Block =<br />

(show all work)<br />

Specific Heat =


ThermoChemistry (Energy) WebQuest<br />

Name _________________________________________ Period _______<br />

Part 5- Some more Specific Heat Problems<br />

http://www.sciencebugz.com/chemistry/chprbspheat.htm<br />

Show set up for the 3 problems. Calculate the answer and check it.<br />

1. Problem #1<br />

2. Problem #2<br />

3. Problem #3<br />

Part 6 – Mixed Review<br />

calculations done.<br />

Answer the following questions. Show all equations used and<br />

1. Use the thermochemical equations shown below to determine the enthalpy for the reaction:<br />

CH 4 (g) + 2O 2 (g) CO 2 (g) + 2H 2 O(l)<br />

CO 2 (g) C(s) + O 2 (g)<br />

H 2 (g) + ½O 2 (g) H 2 O(l)<br />

CH 4 (g) C(s) + 2H 2 (g)<br />

H=590.2KJ<br />

H=-428.7KJ<br />

H=112.2KJ<br />

2. How much energy must be absorbed by 20.0 g of water to increase its temperature from 283.0°C to<br />

303.0°C?<br />

3. How much heat, in kJ, is given off when 85.0 grams of Pb cools from 225.0°C to 10.0°C?<br />

(Cp of lead = 0.129 J/g°C.)<br />

4. Use the thermochemical equations shown below to determine the enthalpy for the reaction:<br />

COCl 2 (g) + H 2 O(l) CH 2 Cl 2 (l) + O 2 (g)<br />

½H 2 (g) + ½Cl 2 (g) HCl(g)<br />

H 2 O(g) + Cl 2 (g) 2HCl(g) + ½O 2 (g)<br />

CH 2 Cl 2 (l) + H 2 (g) + 3/2O 2 (g) COCl 2 (g) + 2H 2 O(l)<br />

H=-46KJ<br />

H=-21KJ<br />

H=-80.5KJ

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