Chemical Hygiene Plan - Queensborough Community College ...

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If you are planning to leave your laboratory or if you know of a research group or students that are planning to leave, there are a few simple steps that can be followed to ensure a smooth transition: • Notify your department chairperson and lab supervisor well in advance of the planned move. • Ensure that all chemical containers are properly labeled. • Properly dispose of any hazardous and chemical waste left in the laboratory. • Ensure that all chemical spills and contamination has been cleaned up. • Review the Lab Move Guide. 10.7 Laboratory Design and Construction To provide the best service during the construction/renovation process for laboratories, it is important to take health and safety considerations into account during the design process, well BEFORE construction begins. If you are planning lab construction or renovation, please contact the Chemical Hygiene Officer and EHSO with the following information: • Contact name, phone number, email • Department, building and room(s) the project will occur in • Expected start date for project • Equipment to be installed, such as fume hoods, biosafety cabinet, other capture devices, eyewash and emergency shower, toxic gas cabinet and monitoring devices. • NOTE: A list of chemicals, including approximate usage (weekly/monthly) and storage quantities will be needed during the process to ensure proper ventilation rates and engineering controls. • If you are planning to vacate your laboratory, please see the Lab Move Guide before you begin your move. All NYC Building and Fire Codes (e.g. Section 2706 of the FDNY Fire Code entitled “Nonproduction Chemical Laboratories”) must be followed for new construction and renovation. Consult with QCC Facilities, Planning, Construction and Management (FPCM) for additional details. XI. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment (PPE) should be considered as the last line of defense in protecting laboratory personnel against chemical hazards. PPE is not a substitute for good engineering or administrative controls or good work practices, but should be used in conjunction with these controls to ensure the safety and health of University employees and students. The OSHA Personal Protective Equipment standard, 29 CFR 1910, Subpart I has the following requirements: • Hazard assessment and equipment selection • Employee training 77
• Record keeping requirements • Guidelines for selecting PPE • Hazard assessment certification More information on PPE can be found in the OSHA Safety and Health topics page on Personal Protective Equipment. 11.1 Laboratory Responsibilities for Personal Protective Equipment Laboratory personnel need to conduct hazard assessments of specific operations occurring in their laboratories to determine what PPE is necessary to carry out the operations safely. PPE must be made available to laboratory workers to reduce exposures to hazardous chemicals in the lab. Proper PPE includes items such as gloves, eye protection, lab coats, face shields, aprons, boots, hearing protection, etc. PPE must be readily available and most equipment is provided at no cost to the employee. When deciding on the appropriate PPE to wear when performing any operations or experiments, a number of factors must be taken into consideration such as: • The chemicals being used, including concentration and quantity. • The hazards the chemicals pose. • The routes of exposure for the chemicals. • The material the PPE is constructed of. • The permeation and degradation rates specific chemicals will have on the material. • The length of time the PPE will be in contact with the chemicals. Careful consideration should be given to the comfort and fit of PPE to ensure that it will be used by laboratory personnel. All personal protective equipment and clothing must be maintained in a sanitary and reliable condition. Only those items that meet NIOSH (National Institute of Occupational Safety and Health) or ANSI standards should be purchased or accepted for use. Please Note: P.I.s, laboratory supervisors, departments, and colleges are free to set policies that establish minimum PPE requirements for personnel working in and entering their laboratories. Check with your EHSO to see if there are any department or college specific requirements for PPE. 11.2 Training for Personal Protective Equipment Laboratory personnel must be trained in the selection, proper use, limitations, care, and maintenance of PPE. Training requirements can be met in a variety of ways including videos, group training sessions, and handouts. Periodic retraining should be offered to both the employees and supervisors as appropriate. Examples of topics to be covered during the training include: 78
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LABORATORY SAFETY AND CHEMICAL HYGI
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TABLE OF CONTENTS Purpose..........
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Visiting Scientists and Other Simil
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Cryogenic Safety...................
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PURPOSE OF THIS MANUAL The main pur
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The OSHA Laboratory Standard requir
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12. Maintain records and make them
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3. Keep the Department Chairperson,
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6. Before an extremely hazardous su
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• Laboratories can use “price t
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shipment of improperly labeled prod
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• Do not smell or taste chemicals
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5.3 Inhalation Inhalation of chemic
Page 27 and 28: Symptoms of skin exposure to chemic
Page 29 and 30: 5.10 Toxic Effects Toxic effects ar
Page 31 and 32: • All chemical containers MUST be
Page 33 and 34: · Peroxidizable materials (aldehyd
Page 35 and 36: 6.4 Transporting Chemicals When tra
Page 37 and 38: liquids not in use should be kept i
Page 39 and 40: 7. An inside storage room meeting a
Page 41 and 42: VII. CHEMICAL HAZARDS Chemicals can
Page 43 and 44: • Metal Picrate Salts • 2,4-Din
Page 45 and 46: 7.5 Dangerous When Wet “Dangerous
Page 47 and 48: ways to remove them if discovered.
Page 49 and 50: 1(800) 222-1222. If possible, bring
Page 51 and 52: • Prior approval - Before anyone
Page 53 and 54: everyone in the laboratory is aware
Page 55 and 56: particularly hazardous substances
Page 57 and 58: 8.7 Reproductive Toxins The OSHA La
Page 59 and 60: 9.1 Chemical Fume Hoods Fume hoods
Page 61 and 62: inspected, and initials of the insp
Page 63 and 64: 9.4 Biological Safety Cabinet Certi
Page 65 and 66: • Plan and prepare for your work
Page 67 and 68: The topic of glove boxes can be con
Page 69 and 70: 10.1 Standard Operating Procedures
Page 71 and 72: paper, boxes, plastics, etc.) withi
Page 73 and 74: 10.6 Working Alone In Appendix A of
Page 75 and 76: • The nature of the experiment in
Page 77: Additionally, as with installation
Page 81 and 82: Prescription Safety Eyewear OSHA re
Page 83 and 84: different glove types. Different ma
Page 85 and 86: • Natural Rubber Latex*** - Resis
Page 87 and 88: The use of all types of respiratory
Page 89 and 90: your College’s Emergency Procedur
Page 91 and 92: • Check all pressure, temperature
Page 93 and 94: If you have been trained and it is
Page 95 and 96: 4) Try to prevent spilled chemicals
Page 97 and 98: their use. Colleges and departments
Page 99 and 100: Once outside, notify emergency resp
Page 101 and 102: 5) Keep flushing for at least 15 mi
Page 103 and 104: 3. The New York City Rules and Regu
Page 105 and 106: 6. Selection of Hazardous Waste Con
Page 107 and 108: XV. PESTICIDES A pesticide is defin
Page 109 and 110: 16.1 Institutional Biosafety Commit
Page 111 and 112: the College’s IACUC must ensure t
Page 113 and 114: • Materials derived from animals
Page 115 and 116: the same regulations and laws; and
Page 117 and 118: problems and compliance issues, and
Page 119 and 120: from any given amperage, the table
Page 121 and 122: extension cords, see the Consumer P
Page 123 and 124: "reset" buttons. They are found on
Page 125 and 126: properly replaced before use. Movin
Page 127 and 128: 22.4.1 Handling Compressed Gas Cyli
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materials for connections; toxic an
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Therefore, when counting an “equa
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• If toxic, flammable, or otherwi
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22.9 Centrifuges Some general safet
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significant thrust may be experienc
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frozen to the underlying skin, cold
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• Allow the system to cool and th
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• Cover the tubing with cloth and
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• Apparatus, equipment, or chemic
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• Seat height—be sure lab chair
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someone else in your department or
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23.3 Cylinders • Before moving to
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EHS roles/responsibilities: • Pro
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and that there are no dents or hole
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• The contents of the Laboratory
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Training Manuals and Booklets P.I.s
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• Where airborne exposure monitor
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than one year's employment must be
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APPENDIX B: SITE MAP 164
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APPENDIX D: OSHA TOXIC SUBSTANCES L
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APPENDIX F: SAMPLE LAB INSPECTION F
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APPENDIX G: CHEMICAL COMPATIBILITY
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peroxide, Nitric acid, Sodium perox
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Sodium peroxide Sulfides Sulfuric a
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APPENDIX I: FDNY REGULATIONS GOVERN
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41 and the total quantity, excludin
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Dimethyl sulfoxide 1 Natural rubber
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Pump oil Butyl rubber Silane based
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APPENDIX L: HOW TO UNDERSTAND MATER
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Percent Volatile by Volume: Describ
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Stability: Unstable indicates that
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APPENDIX M: HAZARDS OF FUNCTIONAL G
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Examples: Butane Cyclohexene Cyclop
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• Azides of nonmetals, such as th
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• The routes of exposure are inha
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• Many of the common solvents can
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ORGANIC PEROXIDES • Compounds con
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• High doses may produce somnolen
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APPENDIX O:LASER REGISTRATION FORM
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APPENDIX Q : APPENDIX OF REFERENCE
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Biological Effects and Exposure Cri
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Dental X-Ray Protection, National C
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Gibson, David E., Printmaking, Occu
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Laboratory Decontamination and Carc
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Natural Background Radiation In The
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Public Radiation Exposure from Nucl
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Materials, The School of the Art In
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Video Display Terminals, Bell Labor
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