Chemical Hygiene Plan - Queensborough Community College ...

Chemical Hygiene Plan - Queensborough Community College ... Chemical Hygiene Plan - Queensborough Community College ...

05.06.2014 Views

death occurs within one hour) to albino rats weighing between 200 and 300 grams each. Information on determining whether or not a chemical meets one of these definitions can be found in MSDSs and other chemical references. As with any particularly hazardous substance, work involving the use of acute toxins should adhere to the Guidelines for Working with Particularly Hazardous Substances. In addition to following the Guidelines for Working with Particularly Hazardous Substances, additional guidelines for working with acute toxins include: • Consider storing highly toxic materials in a locked storage cabinet. • Be aware of any special antidotes that may be required in case of accidental exposure. • Give particular attention to the selection of gloves and other personal protective equipment. • Do not work with highly toxic chemicals outside of a fume hood, glove box or ventilated enclosure. More information on acute toxins, including numerous useful web links, can be found on the OSHA Safety and Health Topics for Hazardous and Toxic Substances webpage. IX. ENGINEERING CONTROLS Engineering controls are considered the first line of defense in the laboratory for the reduction or elimination of the potential exposure to hazardous chemicals. Examples of engineering controls used in laboratories at QCC may include dilution ventilation, local exhaust ventilation, chemical fume hoods, glove boxes, safety shields, and proper storage facilities. The OSHA Laboratory Standard requires that "fume hoods and other protective equipment function properly and that specific measures are taken to ensure proper and adequate performance of such equipment." General laboratory room ventilation is not adequate to provide proper protection against bench top use of hazardous chemicals. Laboratory personnel need to consider available engineering controls to protect themselves against chemical exposures before beginning any new experiment(s) involving the use of hazardous chemicals. The proper functioning and maintenance of fume hoods and other protective equipment used in the laboratory is the responsibility of a variety of service groups. Facilities Management, the EHSO, and other groups service equipment such as fire extinguishers, emergency eyewash and showers, and mechanical ventilation. Periodic inspections and maintenance by these groups ensures the proper functioning and adequate performance of these important pieces of protective equipment. However, it is the responsibility of laboratory personnel to IMMEDIATELY report malfunctioning protective equipment, such as fume hoods or other mechanical problems, to Facilities Management as soon as any malfunctions are discovered. For more information, see Ticket Requests. 57

9.1 Chemical Fume Hoods Fume hoods and other capture devices must be used for operations that might result in the release of toxic chemical vapors, fumes, aerosols, or dusts. Bench top use of chemicals that present an inhalation hazard is not permitted. Fume hoods must be used when conducting new experiments with unknown consequences from reactions or when the potential for a fire exists. Laboratory personnel may want to conduct a dry ice capture test with their fume hoods when using new materials for the first time or whenever substantial changes have been made to an experimental setup in a hood, such as the addition of more apparatus. To obtain optimum performance and achieve the greatest protection when using a fume hood, please adhere to the following: • Before using a fume hood, ensure that the fume hood is working by checking the tell tale (green crepe paper hanging from hood sash) and air monitoring device if the hood is equipped with one. If the EHSO or Facilities Management has posted the hood as being out of service, DO NOT use the fume hood for any reason. • Always work with the fume hood sash as low as possible. Keeping the hood sash lowered improves the performance of the fume hood, acts as a safety shield during experimental procedures and (for VAV hoods) helps to conserve energy. • Keep the fume hood sash closed all of the way whenever the fume hood is not being used to help conserve energy. • For those laboratories equipped with occupancy sensors or where the ventilation rates are controlled by the light switches, when you first enter the lab, wait a few minutes before beginning to work with chemicals in order for the ventilation system to ramp up to occupied settings and higher ventilation rates. • Minimize all materials stored in hoods. Excess and unnecessary storage and clutter results in decreased hood performance and increases the chances of an accident or spill occurring. Do not use hoods as storage cabinets, especially for long term storage of chemicals and hazardous waste. • For optimum performance of the fume hood, keep all materials and equipment at least six (6) inches from the face of the hood and do not block the vents or baffle openings in the back of the hood. • Keep any lab equipment elevated at least one inch off the work surface of the hood to allow for proper airflow. Use bench stands or items such as blocks, metal test tube racks, or other items that will not react with the chemical(s) in use. • When working in a fume hood, keep windows and doors closed within the lab and minimize traffic in front of the hood. Minimize rapid movements while working in the hood, including opening and closing the sash. All of these precautions will help to prevent air currents from forming, which can result in hazardous vapors being pulled out of the hood and into the laboratory personnel’s breathing zone. 58

9.1 <strong>Chemical</strong> Fume Hoods<br />

Fume hoods and other capture devices must be used for operations that might result in the release<br />

of toxic chemical vapors, fumes, aerosols, or dusts. Bench top use of chemicals that present an<br />

inhalation hazard is not permitted. Fume hoods must be used when conducting new experiments<br />

with unknown consequences from reactions or when the potential for a fire exists. Laboratory<br />

personnel may want to conduct a dry ice capture test with their fume hoods when using new<br />

materials for the first time or whenever substantial changes have been made to an experimental<br />

setup in a hood, such as the addition of more apparatus.<br />

To obtain optimum performance and achieve the greatest protection when using a fume hood,<br />

please adhere to the following:<br />

• Before using a fume hood, ensure that the fume hood is working by checking the tell tale<br />

(green crepe paper hanging from hood sash) and air monitoring device if the hood is<br />

equipped with one. If the EHSO or Facilities Management has posted the hood as<br />

being out of service, DO NOT use the fume hood for any reason.<br />

• Always work with the fume hood sash as low as possible. Keeping the hood sash<br />

lowered improves the performance of the fume hood, acts as a safety shield during<br />

experimental procedures and (for VAV hoods) helps to conserve energy.<br />

• Keep the fume hood sash closed all of the way whenever the fume hood is not being used<br />

to help conserve energy.<br />

• For those laboratories equipped with occupancy sensors or where the ventilation rates are<br />

controlled by the light switches, when you first enter the lab, wait a few minutes before<br />

beginning to work with chemicals in order for the ventilation system to ramp up to<br />

occupied settings and higher ventilation rates.<br />

• Minimize all materials stored in hoods. Excess and unnecessary storage and clutter<br />

results in decreased hood performance and increases the chances of an accident or spill<br />

occurring. Do not use hoods as storage cabinets, especially for long term storage of<br />

chemicals and hazardous waste.<br />

• For optimum performance of the fume hood, keep all materials and equipment at least six<br />

(6) inches from the face of the hood and do not block the vents or baffle openings in the<br />

back of the hood.<br />

• Keep any lab equipment elevated at least one inch off the work surface of the hood to<br />

allow for proper airflow. Use bench stands or items such as blocks, metal test tube racks,<br />

or other items that will not react with the chemical(s) in use.<br />

• When working in a fume hood, keep windows and doors closed within the lab and<br />

minimize traffic in front of the hood. Minimize rapid movements while working in the<br />

hood, including opening and closing the sash. All of these precautions will help to<br />

prevent air currents from forming, which can result in hazardous vapors being pulled out<br />

of the hood and into the laboratory personnel’s breathing zone.<br />

58

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