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Chemical Hygiene Plan - Queensborough Community College ...

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• Prior approval - Before anyone uses HF they must have prior approval from the P.I. Lab<br />

personnel planning to use HF should be able to answer the following in the affirmative:<br />

o Has read the MSDS for HF<br />

o Has read the HF Use SOP developed by the lab<br />

o Has read the Hydrofluoric acid section in this Lab Safety Manual<br />

o Is aware of the designated area for HF use<br />

o Knows the first aid procedure in case of an HF exposure<br />

o Knows what to do in case of an HF spill<br />

• The following PPE is required for HF use:<br />

o Rubber or plastic apron<br />

o Plastic arm coverings<br />

o Gloves<br />

Incidental use - double glove with heavy nitrile exam gloves and re-glove<br />

if any exposure to the gloves<br />

Extended use – heavy neoprene or butyl over nitrile or silver shield gloves<br />

o Splash goggles in conjunction with a fume hood sash<br />

o Closed toed shoes<br />

o Long pants and a long sleeve shirt with a reasonably high neck<br />

The following are safe practice guidelines when working with HF:<br />

• Never work alone with HF. Have a buddy system.<br />

• Use a plastic tray while working with HF for containment in case of a spill.<br />

• Keep containers of HF closed. HF can etch the glass sash and make it hard to see<br />

through (if the hood sash becomes fogged and hard to see though because of etching,<br />

please contact EHS about installing a polycarbonate sash)<br />

• Material Safety Data Sheet (MSDS) – A MSDS for HF must be available.<br />

• All containers of HF must be clearly labeled.<br />

• The stock HF should be stored in plastic secondary containment and the cabinet should<br />

be labeled. HF should be stored in lower cabinets near the floor.<br />

• Wash gloves off with water before removing them.<br />

Contact your EHS Office for more information.<br />

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