Chemical Hygiene Plan - Queensborough Community College ...

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Specifications for Chemical Stockrooms................................................................... 36 Flammable Materials Stockrooms............................................................................. 37 Storage Requirements for Specific Hazards of Chemicals........................................ 38 Chemical Hazards........................................................................................................... 40 Explosives................................................................................................................. 40 Flammable and Combustible Liquids........................................................................ 42 Flammable Solids...................................................................................................... 43 Spontaneously Combustible...................................................................................... 43 Dangerous When Wet................................................................................................ 44 Oxidizers/ Organic Peroxides................................................................................... 44 Peroxide Forming Compounds................................................................................. 45 Poisons..................................................................................................................... 46 Corrosives............................................................................................................... 48 Hydrofluoric Acid..................................................................................................... 49 Perchloric Acid......................................................................................................... 51 Particularly Hazardous Substances................................................................................. 51 Establishment of Designated Areas........................................................................... 51 Safe Removal of Contaminated Materials and Waste.............................................. 52 Decontamination Procedures.................................................................................... 52 Guidelines for Working with Particularly Hazardous Substances.......................... 52 Prior Approval.......................................................................................................... 53 Select Carcinogens................................................................................................... 54 Reproductive Toxins................................................................................................ 56 Acute Toxins............................................................................................................ 56 Engineering Controls...................................................................................................... 57 Chemical Fume Hoods.............................................................................................. 58 Perchloric Acid Use................................................................................................... 59 Fume Hood Inspection and Testing Program............................................................ 59 Installation of New Fume Hoods............................................................................. 60 Removal of Existing Fume Hoods........................................................................... 61 Other Capture Devices............................................................................................ 61 Biological Safety Cabinets...................................................................................... 61 Biology Safety Cabinet Certifications....................................................................... 61 Types of Biological Safety Cabinets..........................................................................62 BSC Work Practice and Procedures.......................................................................... 63 BSC Operational Procedures..................................................................................... 64 Use of Ultraviolet Lights in the BSC....................................................................... 65 Glove Boxes.............................................................................................................. 65 Water Protection in the Labs.................................................................................... 67 Administrative Controls................................................................................................. 67 Standard Operating Procedures............................................................................... 68 Procedural Controls.................................................................................................. 69 Housekeeping........................................................................................................... 69 Personal Hygiene...................................................................................................... 70 Eating, Drinking, Applying Cosmetics in the Lab.................................................... 71 Working Alone......................................................................................................... 72 Unattended Operations.............................................................................................. 73 Access to Laboratories.............................................................................................. 74 3
Visiting Scientists and Other Similar Users.............................................................. 74 Pets in Labs................................................................................................................ 75 Chemical Purchasing................................................................................................. 75 Ordering New Equipment.......................................................................................... 75 Work Orders and Ticket Requests............................................................................. 76 Changes in Lab Occupancy....................................................................................... 76 Laboratory Design and Construction......................................................................... 77 Personal Protective Equipment........................................................................................ 77 Laboratory Responsibilities for Personal Protective Equipment............................... 78 Training for Personal Protective Equipment............................................................ 78 Eye Protection.......................................................................................................... 79 Eye Protection Selection............................................................................................ 79 Hand Protection......................................................................................................... 81 Selecting the Proper Gloves....................................................................................... 81 Double Gloving.......................................................................................................... 82 Types of Gloves.........................................................................................................83 Protective Clothing.................................................................................................... 85 Respirators.................................................................................................................85 Hearing Protection.................................................................................................... 87 Foot Protection......................................................................................................... 87 Emergency Preparedness.................................................................................................87 QCC Emergency Response and Recovery Plan....................................................... 88 Emergency Procedures.............................................................................................. 88 Emergency Evacuation Procedures........................................................................... 88 Laboratory Emergency Shutdown Procedures.......................................................... 89 Medical Emergency Procedures............................................................................... 90 First Aid Kits............................................................................................................. 90 Fire and Explosion Emergency Procedures.............................................................. 91 Fire Extinguishers..................................................................................................... 92 Power Outage Procedures......................................................................................... 92 Chemical Spill Procures............................................................................................ 93 Incidental Spills Cleanup Procedures........................................................................ 93 Spill Absorbent Materials.......................................................................................... 94 Spill Kits.................................................................................................................... 95 Major Spills.............................................................................................................. 97 Major Spill Cleanup Procedures.............................................................................. 97 Emergency Eyewash and Showers.......................................................................... 98 Testing and Inspection of Eyewash and Showers..................................................... 98 Installation of New Emergency Eyewash Showers.................................................. 99 Using Emergency Eyewash and Showers................................................................. 99 Phones in Labs..........................................................................................................101 Waste Management...................................................................................................... 101 Hazardous Waste Laws and Regulations..................................................................102 Institutional Compliance with Hazardous Waste Regulations................................. 102 Hazardous Waste Identification................................................................................102 Determining Generator Status.................................................................................. 103 Hazardous Waste Collected and Segregation........................................................... 103 Waste Storage and Transport (Within a Facility)..................................................... .....103 4
Page 1 and 2: LABORATORY SAFETY AND CHEMICAL HYGI
Page 3: TABLE OF CONTENTS Purpose..........
Page 7 and 8: Cryogenic Safety...................
Page 9 and 10: PURPOSE OF THIS MANUAL The main pur
Page 11 and 12: The OSHA Laboratory Standard requir
Page 13 and 14: 12. Maintain records and make them
Page 15 and 16: 3. Keep the Department Chairperson,
Page 17 and 18: 6. Before an extremely hazardous su
Page 19 and 20: • Laboratories can use “price t
Page 21 and 22: shipment of improperly labeled prod
Page 23 and 24: • Do not smell or taste chemicals
Page 25 and 26: 5.3 Inhalation Inhalation of chemic
Page 27 and 28: Symptoms of skin exposure to chemic
Page 29 and 30: 5.10 Toxic Effects Toxic effects ar
Page 31 and 32: • All chemical containers MUST be
Page 33 and 34: · Peroxidizable materials (aldehyd
Page 35 and 36: 6.4 Transporting Chemicals When tra
Page 37 and 38: liquids not in use should be kept i
Page 39 and 40: 7. An inside storage room meeting a
Page 41 and 42: VII. CHEMICAL HAZARDS Chemicals can
Page 43 and 44: • Metal Picrate Salts • 2,4-Din
Page 45 and 46: 7.5 Dangerous When Wet “Dangerous
Page 47 and 48: ways to remove them if discovered.
Page 49 and 50: 1(800) 222-1222. If possible, bring
Page 51 and 52: • Prior approval - Before anyone
Page 53 and 54: everyone in the laboratory is aware
Page 55 and 56:
particularly hazardous substances
Page 57 and 58:
8.7 Reproductive Toxins The OSHA La
Page 59 and 60:
9.1 Chemical Fume Hoods Fume hoods
Page 61 and 62:
inspected, and initials of the insp
Page 63 and 64:
9.4 Biological Safety Cabinet Certi
Page 65 and 66:
• Plan and prepare for your work
Page 67 and 68:
The topic of glove boxes can be con
Page 69 and 70:
10.1 Standard Operating Procedures
Page 71 and 72:
paper, boxes, plastics, etc.) withi
Page 73 and 74:
10.6 Working Alone In Appendix A of
Page 75 and 76:
• The nature of the experiment in
Page 77 and 78:
Additionally, as with installation
Page 79 and 80:
• Record keeping requirements •
Page 81 and 82:
Prescription Safety Eyewear OSHA re
Page 83 and 84:
different glove types. Different ma
Page 85 and 86:
• Natural Rubber Latex*** - Resis
Page 87 and 88:
The use of all types of respiratory
Page 89 and 90:
your College’s Emergency Procedur
Page 91 and 92:
• Check all pressure, temperature
Page 93 and 94:
If you have been trained and it is
Page 95 and 96:
4) Try to prevent spilled chemicals
Page 97 and 98:
their use. Colleges and departments
Page 99 and 100:
Once outside, notify emergency resp
Page 101 and 102:
5) Keep flushing for at least 15 mi
Page 103 and 104:
3. The New York City Rules and Regu
Page 105 and 106:
6. Selection of Hazardous Waste Con
Page 107 and 108:
XV. PESTICIDES A pesticide is defin
Page 109 and 110:
16.1 Institutional Biosafety Commit
Page 111 and 112:
the College’s IACUC must ensure t
Page 113 and 114:
• Materials derived from animals
Page 115 and 116:
the same regulations and laws; and
Page 117 and 118:
problems and compliance issues, and
Page 119 and 120:
from any given amperage, the table
Page 121 and 122:
extension cords, see the Consumer P
Page 123 and 124:
"reset" buttons. They are found on
Page 125 and 126:
properly replaced before use. Movin
Page 127 and 128:
22.4.1 Handling Compressed Gas Cyli
Page 129 and 130:
materials for connections; toxic an
Page 131 and 132:
Therefore, when counting an “equa
Page 133 and 134:
• If toxic, flammable, or otherwi
Page 135 and 136:
22.9 Centrifuges Some general safet
Page 137 and 138:
significant thrust may be experienc
Page 139 and 140:
frozen to the underlying skin, cold
Page 141 and 142:
• Allow the system to cool and th
Page 143 and 144:
• Cover the tubing with cloth and
Page 145 and 146:
• Apparatus, equipment, or chemic
Page 147 and 148:
• Seat height—be sure lab chair
Page 149 and 150:
someone else in your department or
Page 151 and 152:
23.3 Cylinders • Before moving to
Page 153 and 154:
EHS roles/responsibilities: • Pro
Page 155 and 156:
and that there are no dents or hole
Page 157 and 158:
• The contents of the Laboratory
Page 159 and 160:
Training Manuals and Booklets P.I.s
Page 161 and 162:
• Where airborne exposure monitor
Page 163 and 164:
than one year's employment must be
Page 165 and 166:
APPENDIX B: SITE MAP 164
Page 167 and 168:
APPENDIX D: OSHA TOXIC SUBSTANCES L
Page 169 and 170:
APPENDIX F: SAMPLE LAB INSPECTION F
Page 171 and 172:
APPENDIX G: CHEMICAL COMPATIBILITY
Page 173 and 174:
peroxide, Nitric acid, Sodium perox
Page 175 and 176:
Sodium peroxide Sulfides Sulfuric a
Page 177 and 178:
APPENDIX I: FDNY REGULATIONS GOVERN
Page 179 and 180:
41 and the total quantity, excludin
Page 181 and 182:
Dimethyl sulfoxide 1 Natural rubber
Page 183 and 184:
Pump oil Butyl rubber Silane based
Page 185 and 186:
APPENDIX L: HOW TO UNDERSTAND MATER
Page 187 and 188:
Percent Volatile by Volume: Describ
Page 189 and 190:
Stability: Unstable indicates that
Page 191 and 192:
APPENDIX M: HAZARDS OF FUNCTIONAL G
Page 193 and 194:
Examples: Butane Cyclohexene Cyclop
Page 195 and 196:
• Azides of nonmetals, such as th
Page 197 and 198:
• The routes of exposure are inha
Page 199 and 200:
• Many of the common solvents can
Page 201 and 202:
ORGANIC PEROXIDES • Compounds con
Page 203 and 204:
• High doses may produce somnolen
Page 205 and 206:
APPENDIX O:LASER REGISTRATION FORM
Page 207 and 208:
APPENDIX Q : APPENDIX OF REFERENCE
Page 209 and 210:
Biological Effects and Exposure Cri
Page 211 and 212:
Dental X-Ray Protection, National C
Page 213 and 214:
Gibson, David E., Printmaking, Occu
Page 215 and 216:
Laboratory Decontamination and Carc
Page 217 and 218:
Natural Background Radiation In The
Page 219 and 220:
Public Radiation Exposure from Nucl
Page 221 and 222:
Materials, The School of the Art In
Page 223 and 224:
Video Display Terminals, Bell Labor
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